铝钢复合材料兼具钢良好的力学性能和铝的耐腐蚀、高导热性、密度低等特点，可以满足许多特殊使用要求。铝钢界面若生成金属间化合物，会破坏铝钢基体间的冶金结合，严重影响材料的使用性能。因此，抑制铝钢界面金属间化合物的生长是开发铝钢复合材料的关键。对铝钢金属间化合物的生长及其抑制机理进行了较为系统的综述，介绍了铝钢界面常见的金属间化合物生成相的种类、晶体结构，从热力学与动力学角度对金属间化合物的生成机理及形成顺序进行了阐述。此外，对比总结了不同合金元素对铝钢金属间化合物形成的影响规律，着重分析了Si元素对铝钢金属间化合物生长的抑制机理。
Al-steel clad material has been widely used due to its excellent performance both with good mechani-cal property of steel and corrosion resistance,high thermal conductivity,low density of Al.The metallurgical bonding between the Al and the steel will be damaged when the intermetallic compound generated in the interface.It seriously deteriorates the performance of the material.So it′s important to inhibit the growth of the intermetallic compound for develop the Al-steel clad material.This paper summarizes the formation and inhibition mechanism of Fe-Al intermetal-lic compound.Introduce the type and crystal structure of the most common Fe-Al intermetallic compound phases.Dis-cuss the mechanism and the subsequence on the formation of the intermetallic compound from the aspects of thermody-namics and dynamics.Then compare the effect of different alloy element on the formation of the Fe-Al intermetallic compound.Especially,the inhibition mechanism of Si on the formation of Fe-Al intermetallic compound is emphatically considered.
参考文献
| [1] | 沓名 宗春;ラソウド．マノジュ;菰田 頼忠;籠原 幸彦.低炭素鋼とアルミニウム合金のロール圧接継手の接合機構に関する研究[J].溶接学会論文集,20031(1):101-108. |
| [2] | 祖国胤;王磊;王威;于九明.退火对轧制包覆碳钢/铝夹层带材组织与性能的影响[J].东北大学学报（自然科学版）,2009(8):1127-1130,1134. |
| [3] | 王谦;冷雪松;杨天豪;闫久春.Al-Fe金属间化合物对复合板界面结合的影响[J].中国有色金属学报（英文版）,2014(1):279-284. |
| [4] | 陈鑫;李龙;周德敬.铝（4A60）-钢（08Al）复合带材界面化合物形成及结合性能[J].中国有色金属学报,2015(5):1176-1184. |
| [5] | 王平;谢佩佩.钢-铝轧制复合界面化合物的抑制机理[J].中国有色金属学报,2010(z1):284-288. |
| [6] | 宋群玲;孙勇;范启印.钢-铝轧制复合材料界面生成化合物的热力学计算及分析[J].热加工工艺,2012(10):114-116,120. |
| [7] | 祝汉良;郭景杰;贾均.硅对压铸模与铝合金相互作用的影响[J].特种铸造及有色合金,1998(6):22-25. |
| [8] | A. Bouayad;Ch. Gerometta;A. Belkebir.Kinetic interactions between solid iron and molten aluminium[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20031/2(1/2):53-61. |
| [9] | Sasaki T;Yakou T.Features of intermetallic compounds in aluminized steels formed using aluminum foil[J].Surface & Coatings Technology,20066(6):2131-2139. |
| [10] | Su CW;Lee JW;Wang CS;Chao CG;Liu TF.The effect of hot-dipped aluminum coatings on Fe-8Al-30Mn-0.8C alloy[J].Surface & Coatings Technology,20089(9):1847-1852. |
| [11] | 张都清;刘光明;赵国群;管延锦.T91钢热浸镀铝及其在水蒸汽中的循环氧化行为[J].中南大学学报（自然科学版）,2009(4):956-962. |
| [12] | Emel Taban;Jerry E. Gould;John C. Lippold.Characterization of 6061-T6 aluminum alloy to AISI 1018 steel interfaces during joining and thermo-mechanical conditioning[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20107/8(7/8):1704-1708. |
| [13] | 岳宗洪;张小磊;侯发臣.铝-钢复合板结合界面研究[J].材料开发与应用,2011(1):34-37. |
| [14] | 吴铭方;司乃潮;王敬;王凤江.铁/铝扩散偶界面反应层生长机理分析[J].焊接学报,2011(5):29-32. |
| [15] | H. Springer;A. Kostka;E.J. Payton.On the formation and growth of intermetallic phases during interdiffusion between low-carbon steel and aluminum alloys[J].Acta materialia,20114(4):1586-1600. |
| [16] | Olexandr Grydin;Gregory Gerstein;Florian Nuernberger;Mirko Schaper;Valentyn Danchenko.Twin-roll casting of aluminum-steel clad strips[J].Journal of manufacturing processes,20134(4):501-507. |
| [17] | O. Ikeda;I. Ohnuma;R. Kainuma.Phase equilibria and stability of ordered BCC phases in the Fe-rich portion of the Fe-Al system[J].Intermetallics,20019(9):755-761. |
| [18] | S. Hirose;T. Itoh;M. Makita.Defect structure of deformed Fe_2Al_5 intermetallic compound[J].Intermetallics,20037(7):633-642. |
| [19] | GUILLAUME PASCHE;CECILE HEBERT;AICHA HESSLER-WYSER.Time-Resolved X-Ray Microtomography Observation of Intermetallic Formation Between Solid Fe and Liquid Al[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,20139(9):4119-4123. |
| [20] | Saito K.;Hiraga K.;Sugiyama K..Al13M4-type structures and atomic models of their twins[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20000(0):279-282. |
| [21] | Li YJ.;Wang J.;Holly X..X-ray diffraction and TEM analysis of Fe-Al alloy layer in coating of new hot dip aluminised steel[J].Materials Science and Technology: MST: A publication of the Institute of Metals,20035(5):657-660. |
| [22] | Kobayashi S.;Yakou T..Control of intermetallic compound layers at interface between steel and aluminum by diffusion-treatment[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20021/2(1/2):44-53. |
| [23] | Bouche K.;Coulet A.;Barbier F..Intermetallic compound layer growth between solid iron and molten aluminium[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,19981/2(1/2):167-175. |
| [24] | 沈物灵;李金山;高鹏;王川云;唐斌;寇宏超.镀锌30CrMnSi锌铁扩散层生长动力学[J].材料热处理学报,2014(z2):171-174. |
| [25] | M. J. RATHOD;M. KUTSUNA.Joining of Aluminum Alloy 5052 and Low-Carbon Steel by Laser Roll Welding[J].Welding Journal,20041(1):(16-S)-(26-S)-0. |
| [26] | Masanori Kajihara.Quantitative Evaluation of Interdiffusion in Fe_2Al_5 during Reactive Diffusion in the Binary Fe-Al System[J].Materials transactions,20066(6):1480-1484. |
| [27] | Vikas Jindal;V.C. Srivastava;Arpan Das.Reactive diffusion in the roll bonded iron-aluminum system[J].Materials Letters,200613/14(13/14):1758-1761. |
| [28] | D. Naoi;M. Kajihara.Growth behavior of Fe_2Al_5 during reactive diffusion between Fe and Al at solid-state temperatures[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20071/2(1/2):375-382. |
| [29] | 尹付成;赵满秀;刘永雄;韩炜;李智.Si对铁铝固-液扩散反应中间化合物生长动力学的影响[J].中国有色金属学报（英文版）,2013(2):556-561. |
| [30] | M. Yousaf;Iqbal, M. Ajmal.Variables affecting growth and morphology of the intermetallic layer (Fe_2Al_5)[J].Materials Characterization,20115(5):517-525. |
| [31] | Sung-Ha Hwang;Jin-Hwa Song;Yong-Suk Kim.Effects of carbon content of carbon steel on its dissolution into a molten aluminum alloy[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20051/2(1/2):437-443. |
| [32] | Awan, GH;Ul Hasan, F.The morphology of coating/substrate interface in hot-dip-aluminized steels[J].Materials Science and Engineering. A, Structural Materials: Properties, Microstructure and Processing,20081/2(1/2):157-165. |
| [33] | Teng-Shih Shih;Shu-Hao Tu.Interaction of steel with pure Al, Al-7Si and A356 alloys[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20070(0):349-356. |
| [34] | M.V.Akdeniz;A.O.Mekhrabov.The effect of substitutional impurities on the evolution of Fe-Al diffusion layer[J].Acta materialia,19984(4):1185-1192. |
| [35] | Sun Kyu Kim.Hot-Dip Aluminizing with Silicon and Magnesium Addition I. Effect on Intemiertallic Layer Thickness[J].Journal of Korean Institute of Metal and Materials,201311(11):795-799. |
| [36] | J.K. Jain;S.P. Gupota.Intermetallic compound formation in the Zr-Al-Si ternary system[J].Materials Characterization,20022(2):139-148. |
| [37] | ElMahallawy NA;Taha MA;Shady MA;ElSissi AR;Attia AN;Reif W.Analysis of coating layer formed on steel strips during aluminising by hot dipping in Al-Si baths[J].Materials Science and Technology: MST: A publication of the Institute of Metals,199710(10):832-840. |
| [38] | Sungmin KANG;Kwangsik HAN;Kwangwon KIM.Formation Behavior of an Intermetallic Compound Layer during the Hot Dip Aluminizing of Cast Iron[J].ISIJ International,20127(7):1342-1347. |
| [39] | 韩炜;尹付成;苏旭平;王建华;徐琛.硅对Fe/Al固态扩散反应中Fe2 Al5生长动力学的影响[J].材料热处理学报,2010(6):28-32. |
| [40] | 高超;高明;王平.硅对钢/铝轧制复合界面化合物抑制效应的研究靠[J].沈阳师范大学学报（自然科学版）,2010(2):185-188. |
| [41] | Yong Du;Julius Clemens Schuster;Zi-Kui Liu.A thermodynamic description of the Al-Fe-Si system over the whole composition and temperature ranges via a hybrid approach of CALPHAD and key experiments[J].Intermetallics,20084(4):554-570. |
| [42] | Wei-Jen Cheng;Chaur-Jeng Wang.Observation of high-temperature phase transformation in the Si-modified aluminide coating on mild steel using EBSD[J].Materials Characterization,20104(4):467-473. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%