C/C-SiC复合材料具有高比强度、高比模量、高热导率、低热膨胀系数和优异的高温抗氧化性能等特点,是新一代的耐高温陶瓷基复合材料,已经被广泛地用作热结构和热防护材料、制动材料以及空间光学系统零部件等。近年来,随着高超声速飞行器和返回式航天运输工具的快速发展,飞行器面临着更多的有高热流、高压气流以及高速粒子冲蚀的环境,这对C/C-SiC复合材料的高温防护技术提出了更高的要求。C/C-SiC复合材料高温防护的研究主要集中在纤维涂层改性、基体改性和高温防护涂层等3个方面,综合近几年国内外的研究报道,从上述3个方面综述了C/C-SiC复合材料高温防护技术的研究进展,总结了各种高温防护技术的制备方法,比较了3种高温防护技术的特点,最后对C/C-SiC复合材料高温防护技术的发展趋势提出了一些见解。
The C/C-SiC composites as a new generation of the high-temperature resistant ceramic matrix com-posite material has delivered improved performance in several applications such as thermal structure and thermal pro-tection systems,advanced friction systems and space optical systems,because of its high specific strength,high mo-dulus,low thermal expansion coefficient and high-temperature oxidation resistance.However,the oxidation and abla-tion resistance of C/C-SiC composites need to be improved to satisfy the demands for the new generation of hypersonic vehicles and reusable space transportation vehicles operated in the extreme environment with high heat flux,high pres-sure airflow and high speed erosion of particles.For C/C-SiC composites,research mainly focus on three methods in-cluding coating modification of carbon fibers,matrix modification and high-temperature protective surface coating.Ac-cording to both internal and external research reports in recent years,new progresses in high-temperature protection of C/C-SiC composites are described in detail.Preparation methods of coating modification of carbon fibers,matrix modi-fication and high-temperature protective surface coating are concluded,while the characteristics of three high-tempera-ture resistance methods are compared.Finally,several opinions of trends in development of high-temperature protec-tion of C/C-SiC composites are put forward.
参考文献
[1] | Hussam Abu El-Hija;Walter Krenkel;Stefan Hugel.Development of C/C-SiC Brake Pads for High-Performance Elevators[J].International journal of applied ceramic technology,20052(2):105-113. |
[2] | 张立同;成来飞;徐永东.新型碳化硅陶瓷基复合材料的研究进展[J].航空制造技术,2003(1):24-32. |
[3] | 李翠云;李辅安.碳/碳复合材料的应用研究进展[J].化工新型材料,2006(3):18-20. |
[4] | 赵建国;李克智;李贺军;孙国栋;王闯.炭/炭复合材料热膨胀性能的研究[J].材料热处理学报,2006(6):1-4. |
[5] | Hermann Hald.Operational limits for reusable space transportation systems due to physical boundaries of C/SiC materials[J].Aerospace science and technology,20037(7):551-559. |
[6] | Walter Krenkel;Bernhard Heidenreich;Ralph Renz.C/C-SiC composites for advanced friction systems[J].Advanced Engineering Materials,20027(7):427-436. |
[7] | Krenkel W;Berndt F.C/C-SiC composites for space applications and advanced friction systems[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20051/2(1/2):177-181. |
[8] | 盛文彦;曾令可;王慧;刘平安;程小苏.陶瓷纤维涂层改性技术[J].陶瓷,2004(4):22-24. |
[9] | Liu, Shanhua;Zhang, Litong;Yin, Xiaowei;Liu, Yongsheng;Cheng, Laifei;Li, Hui;Zhao, Chunnian;Guan, Kang.The comparison of microstructure and oxidation behaviors of (SiC-C)/PyC/SiC and C/PyCHT/SiC composites in air[J].Science and Engineering of Composite Materials,20154(4):417-423. |
[10] | Naslain R.;Guette A.;Rebillat F.;Pailler R.;Langlais F.;Bourrat X..Boron-bearing species in ceramic matrix composites for long-term aerospace applications[J].International Journal of Quantum Chemistry,20042(2):449-456. |
[11] | Jia, Yan;Li, Kezhi;Xue, Lizhen;Ren, Junjie;Zhang, Shouyang;Zhang, Xinmeng.Microstructure and mechanical properties of carbon fiber reinforced multilayered (PyC-SiC)(n) matrix composites[J].Materials & design,2015Dec.5(Dec.5):55-60. |
[12] | 赵彦伟;孙文婷;李军平;刘宏瑞;张国兵.C/C-SiC复合材料的反应熔渗法制备与微观组织[J].宇航材料工艺,2013(2):64-69. |
[13] | 范晓孟;殷小玮;张立同;成来飞.液硅渗透法制备Ti3SiC2改性C/C-SiC复合材料[J].复合材料学报,2012(1):104-110. |
[14] | 刘建功;殷小玮;成来飞;张立同;王琴.液硅渗透法制备Si-B-C改性C/C-SiC复合材料[J].复合材料学报,2012(6):78-82. |
[15] | 童长青;成来飞;殷小玮;刘永胜;张立同;鲁波.C/SiC-SiB4复合材料的制备及氧化行为[J].功能材料,2008(12):1982-1984,1988. |
[16] | 樊乾国;崔红;闫联生;张强;孟祥利;杨星.浆料浸渍法制备C/C-SiC-ZrB2超高温复合材料及其烧蚀性能研究[J].无机材料学报,2013(9):1014-1018. |
[17] | Solntsev, S. S..Erosion-Resistant Thermostatic Coatings Based on the Composition (SiO2-B2O3 )-SiB4[J].Glass and ceramics,20155/6(5/6):175-179. |
[18] | Fengming Shi;Xiaowei Yin;Xiaomeng Fan.A new route to fabricate SiB_4 modified C/SiC composites[J].Journal of the European Ceramic Society,20109(9):1955-1962. |
[19] | Yonggang Tong;Shuxin Bai;Hong Zhang.C/C-SiC composite prepared by Si-10Zr alloyed melt infiltration[J].CERAMICS INTERNATIONAL,20124(4):3301-3307. |
[20] | Singh M.;Behrendt DR..REACTIVE MELT INFILTRATION OF SILICON-MOLYBDENUM ALLOYS INTO MICROPOROUS CARBON PREFORMS[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,19952(2):193-200. |
[21] | M. Esfehanian;J. Gunster;F. Moztarzadeh.Development of a high temperature C_f/XSi_2-SiC (X = Mo, Ti) composite via reactive melt infiltration[J].Journal of the European Ceramic Society,20072/3(2/3):1229-1235. |
[22] | 李娜;肖鹏;李专;刘逸众.C/C-SiC-Cu3Si复合材料的氧化行为[J].中国有色金属学报,2012(11):3054-3058. |
[23] | 曾燮榕;李贺军;杨峥.碳/碳复合材料表面MoSi2-SiC复相陶瓷涂层及其抗氧化机制[J].硅酸盐学报,1999(1):8-15. |
[24] | Yiguang Wang;Xiaojuan Zhu;Litong Zhang.C/C-SiC-ZrC composites fabricated by reactive melt infiltration with Si_(0.87)Zr_(0.13) alloy[J].CERAMICS INTERNATIONAL,20125(5):4337-4343. |
[25] | Zhaoqian Li;Hejun Li;Shouyang Zhang;Jie Wang;Wei Li;Fengjiao Sun.Effect of reaction melt infiltration temperature on the ablation properties of 2D C/C-SiC-ZrC composites[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2012may(may):12-19. |
[26] | Zhaoqian Li;Hejun Li;Shouyang Zhang.Microstructures and ablation properties of C/C-SiC-ZrC composites prepared using C/C skeletons with various densities[J].CERAMICS INTERNATIONAL,20137(7):8173-8181. |
[27] | 田玲;范雪骐;陈来;吴市;张家宝;任慕苏;孙晋良.C/C-B-SiC复合材料的烧蚀性能研究[J].固体火箭技术,2007(3):256-259. |
[28] | 杨星;崔红;闫联生;孟祥利;张强.陶瓷前驱体配比对C/C-ZrC-SiC复合材料烧蚀性能的影响[J].材料导报,2015(2):52-56. |
[29] | Jing Xie;Kezhi Li;Hejun Li.Ablation behavior and mechanism of C/C-ZrC-SiC composites under an oxyacetylene torch at 3000 °C[J].CERAMICS INTERNATIONAL,20134(4):4171-4178. |
[30] | 杨星;崔红;闫联生;孟祥利;张强;樊乾国.ZrC改性C/C-SiC复合材料的烧蚀性能研究[J].化工新型材料,2014(11):169-171. |
[31] | 孟祥利;田蔚;崔红;闫联生;杨星;张强;赵景鹏.C/C-SiC-ZrB2多元炭陶复合材料烧蚀性能[J].固体火箭技术,2014(1):107-112. |
[32] | 孟祥利;崔红;闫联生;张强;宋麦丽;朱阳.基体改性C/C-HfC-HfB2-SiC复合材料抗烧蚀性能研究[J].中国材料进展,2013(11):655-658. |
[33] | Jing Xie;Kezhi Li;Hejun Li.Cyclic ablation behavior of C/C-ZrC-SiC composites under oxyacetylene torch[J].CERAMICS INTERNATIONAL,20144(4):5165-5171. |
[34] | He-jun Li;Xi-yuan Yao;Yu-lei Zhang;Ke-zhi Li;Ling-jun Guo;Lei Liu.Effect of heat flux on ablation behaviour and mechanism of C/C-ZrB_2-SiC composite under oxyacetylene torch flame[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2013Sep.(Sep.):265-270. |
[35] | Naslain RR.;Bourrat X.;Bertrand S.;Heurtevent F.;Dupel P. Lamouroux F.;Pailler R..Synthesis of highly tailored ceramic matrix composites by pressure-pulsed CVI[J].Solid state ionics,2001Special Issue SI(Special Issue SI):541-548. |
[36] | M. Genet;L. Martin;E. Baranger.Computational prediction of the lifetime of self-healing CMC structures[J].Composites, Part A. Applied science and manufacturing,20122(2):294-303. |
[37] | F. Lamouroux;S. Bertrand.Oxidation-resistant carbon-fiber-reinforced ceramic-matrix composites[J].Composites science and technology,19997(7):1073-1085. |
[38] | Liu, YS;Zhang, LT;Cheng, LF;Yang, XGLWB;Zhang, WH;Xu, YD;Zeng, QF.Preparation and oxidation resistance of 2D C/SiC composites modified by partial boron carbide self-sealing matrix[J].Materials Science and Engineering. A, Structural Materials: Properties, Microstructure and Processing,20081/2(1/2):430-436. |
[39] | 李思维;张立同;刘永胜;成来飞;冯祖德;栾新刚;张伟华;杨文彬.CVI B-C基体改性2D C/SiC在低温湿氧中的自愈合行为[J].无机材料学报,2010(11):1199-1203. |
[40] | 王玲玲;张玲;嵇阿琳;崔红;闫联生.CVD-SiC涂层的C/C-SiC复合材料的抗烧蚀性能[J].宇航材料工艺,2013(2):78-82. |
[41] | 左新章;张立同;刘永胜;成来飞;龚慧灵.Si-B-C陶瓷涂敷2D C/SiC复合材料的抗氧化性能[J].复合材料学报,2013(3):100-106. |
[42] | YAN Zhi-qiao;XIONG Xiang;XIAO Peng;CHEN Feng;ZHANG Hong-bo;HUANG Bai-yun.Oxidation behavior of oxidation protective coatings for C/C-SiC composites at 1 500 ℃[J].中国有色金属学会会刊(英文版),2009(01):61-64. |
[43] | P. D. Sarkisov;N. V. Popovich;L. A. Orlova.COATINGS--BARRIER COATINGS FOR TYPE C/SiC CERAMIC-MATRIX COMPOSITES (REVIEW)[J].Glass and ceramics,20089/10(9/10):366-371. |
[44] | Zhang, Yu-Lei;Fei, Tian;Zeng, Wen-Ying;Yang, Bo-Xing;Li, He-Jun;Li, Ke-Zhi.Microstructure and oxidation behavior of C/C-ZrB2-SiC composites coated with SiC coating at high temperature[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2015Nov.(Nov.):421-427. |
[45] | Zhuang, Lei;Fu, Qian-gang;Zhang, Jia-ping;Guo, Yong-an;Li, He-jun;Shan, Yu-cai.Effect of pre-oxidation treatment on the bonding strength and thermal shock resistance of SiC coating for C/C-ZrC-SiC composites[J].CERAMICS INTERNATIONAL,20155 Pt.B(5 Pt.B):6956-6964. |
[46] | Chr. Argirusis;T. Damjanovic;G. Borchardt.Yttrium silicate coating system for oxidation protection of C/C-Si-SiC composites: Electrophoretic deposition and oxygen self-diffusion measurements[J].Journal of the European Ceramic Society,20072/3(2/3):1303-1306. |
[47] | Yan ZQ;Xiong X;Xiao P;Chen F;Zhang HB;Huang BY.Si-Mo-SiO2 oxidation protective coatings prepared by slurry painting for C/C-SiC composites[J].Surface & Coatings Technology,200819(19):4734-4740. |
[48] | J. Schulte-Fischedick;J. Schmidt;R. Tamme;U. Kroener;J. Arnold;B. Zeiffer.Oxidation behaviour of C/C-SiC coated with SiC-B_4C-SiC-cordierite oxidation protection system[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20041/2(1/2):428-434. |
[49] | Yan Zhi-Qiao;Xiong Xiang;Xiao Peng.A multilayer coating of dense SiC alternated with porous Si-Mo for the oxidation protection of carbon/carbon silicon carbide composites[J].Carbon: An International Journal Sponsored by the American Carbon Society,20081(1):149-153. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%