以固体粒子替代表面活性剂稳定的Pickering乳液，不仅可以赋予乳液许多特殊的性能（电磁和温度感应性能等），还可消除由添加表面活性剂所带来的副作用（过敏性和毒性等），这使得Pickering乳液可以应用到对表面活性物质具有很大限制的生物材料领域。系统综述了常见Pickering乳液用固体粒子，以及为了获得不同类型的乳液而对固体粒子进行表面改性的主要方法，着重归纳了表面改性前亲水性羟基磷灰石（HAp）和改性后疏水性HAp作为颗粒乳化剂稳定的Pickering乳液的类型及其进一步合成的产物。
Pickering emulsion is stabilized by solid particles instead of surfactant,which can not only adj ust the special properties of emulsion (electromagnetic and temperature sensitive performance),but also avoid the side effects of surfactant (irritability and toxicity).Accordingly,Pickering emulsions can be applied to the field of biological mate-rials which have great limitations on surfactant.This paper summarized the solid particles widely used in common Pickering emulsion,and some methods used for surface modification of solid particles in order to obtain different types of emulsion.The emulsion types and further synthetic products of Pickering emulsion stabilized by using hydroxyapa-tite (HAp)as particle emulsifier before and after surface modification are concluded.
参考文献
| [1] | Vignati E.;Piazza R.;Lockhart TP..Pickering emulsions: Interfacial tension, colloidal layer morphology, and trapped-particle motion[J].Langmuir: The ACS Journal of Surfaces and Colloids,200317(17):6650-6656. |
| [2] | Sowmitri Tarimala;Lenore L.Dai.Structure of Microparticles in Solid-Stabilized Emulsions[J].Langmuir: The ACS Journal of Surfaces and Colloids,20049(9):3492-3494. |
| [3] | Binks BP.;Lumsdon SO..Catastrophic phase inversion of water-in-oil emulsions stabilized by hydrophobic silica[J].Langmuir: The ACS Journal of Surfaces and Colloids,20006(6):2539-2547. |
| [4] | Frelichowska, J.;Bolzinger, M.-A.;Chevalier, Y..Effects of solid particle content on properties of o/w Pickering emulsions[J].Journal of Colloid and Interface Science,20102(2):348-356. |
| [5] | Wang, J;Liu, GP;Wang, LY;Li, CF;Xu, JA;Sun, DJ.Synergistic stabilization of emulsions by poly(oxypropylene)diamine and Laponite particles[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,20102/3(2/3):117-124. |
| [6] | Xiaona Li;Chunli Zhu;Yanze Wei.Fabrication of macroporous foam and microspheres of polystyrene by Pickering emulsion polymerization[J].Colloid and polymer science,20141(1):115-122. |
| [7] | Bernard P. Binks;Jhdnny A. Rodrigues.Enhanced Stabilization of Emulsions Due to Surfactant-Induced Nanoparticle Flocculation[J].Langmuir: The ACS Journal of Surfaces and Colloids,200714(14):7436-7439. |
| [8] | Chevalier, Y.;Bolzinger, M.-A..Emulsions stabilized with solid nanoparticles: Pickering emulsions[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2013:23-34. |
| [9] | Frelichowska J;Bolzinger MA;Valour JP;Mouaziz H;Pelletier J;Chevalier Y.Pickering w/o emulsions: drug release and topical delivery.[J].International Journal of Pharmaceutics,20091/2(1/2):7-15. |
| [10] | Kruglyakov, PM;Nushtayeva, AV.Phase inversion in emulsions stabilised by solid particles[J].Advances in Colloid and Interface Science,20040(0):151-158. |
| [11] | Hua, Y.;Zhang, S.;Zhu, Y.;Chu, Y.;Chen, J..Hydrophilic polymer foams with well-defined open-cell structure prepared from pickering high internal phase emulsions[J].Journal of Polymer Science, Part A. Polymer Chemistry,201310(10):2181-2187. |
| [12] | Frelichowska, J;Bolzinger, MA;Chevalier, Y.Pickering emulsions with bare silica[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,20091/3(1/3):70-74. |
| [13] | Wei, Z.;Wang, C.;Liu, H.;Zou, S.;Tong, Z..Facile fabrication of biocompatible PLGA drug-carrying microspheres by O/W pickering emulsions[J].Colloids and Surfaces, B. Biointerfaces,2012:97-105. |
| [14] | Whitby, C.P.;Fornasiero, D.;Ralston, J..Structure of oil-in-water emulsions stabilised by silica and hydrophobised titania particles[J].Journal of Colloid and Interface Science,20101(1):205-209. |
| [15] | Cui, ZG;Shi, KZ;Cui, YZ;Binks, BP.Double phase inversion of emulsions stabilized by a mixture of CaCO3 nanoparticles and sodium dodecyl sulphate[J].Colloids and Surfaces. A, Physicochemical and Engineering Aspects,20081/2(1/2):67-74. |
| [16] | Zhou, J.;Qiao, X.;Binks, B.P.;Sun, K.;Bai, M.;Li, Y.;Liu, Y..Magnetic pickering emulsions stabilized by Fe_3O_4 nanoparticles[J].Langmuir: The ACS Journal of Surfaces and Colloids,20117(7):3308-3316. |
| [17] | Kim SH;Yi GR;Kim KH;Yang SM.Photocurable pickering emulsion for colloidal particles with structural complexity[J].Langmuir: The ACS Journal of Surfaces and Colloids,20086(6):2365-2371. |
| [18] | Tsuji S;Kawaguchi H.Thermosensitive pickering emulsion stabilized by poly(N-isopropylacrylamide)-carrying particles[J].Langmuir: The ACS Journal of Surfaces and Colloids,20087(7):3300-3305. |
| [19] | Rayner, M;Timgren, A;Sjoeoe, M;Dejmek, P..Quinoa starch granules: a candidate for stabilising food-grade Pickering emulsions.[J].Journal of the Science of Food and Agriculture,20129(9):1841-1847. |
| [20] | Liu, H.;Wang, C.;Zou, S.;Wei, Z.;Tong, Z..Simple, reversible emulsion system switched by pH on the basis of chitosan without any hydrophobic modification[J].Langmuir: The ACS Journal of Surfaces and Colloids,201230(30):11017-11024. |
| [21] | Li, ZF;Ngai, T.Macroporous Polymer from Core-Shell Particle-Stabilized Pickering Emulsions[J].Langmuir: The ACS Journal of Surfaces and Colloids,20107(7):5088-5092. |
| [22] | 廖建国;王学江;左奕;张利;文季秋;李玉宝.硅烷偶联剂对纳米羟基磷灰石表面改性的研究[J].无机材料学报,2008(1):145-149. |
| [23] | 罗庆平;刘桂香;杨世源;尹光福;郑昌琼.磷酸单酯偶联剂改性羟基磷灰石/高密度聚乙烯复合人工骨材料的制备和性能[J].复合材料学报,2006(1):80-84. |
| [24] | 毋伟;贾梦秋;陈建峰;邵磊;初广文.硅烷偶联剂对溶胶凝胶法纳米二氧化硅复合材料制备及应用的影响[J].复合材料学报,2004(2):70-75. |
| [25] | 杜高翔.纳米沉淀二氧化硅的硅烷偶联剂原位表面改性[J].功能材料,2008(12):2072-2074,2078. |
| [26] | Wang X;Song G;Lou T.Fabrication and characterization of nano-composite scaffold of PLLA/silane modified hydroxyapatite.[J].Medical engineering and physics,20104(4):391-397. |
| [27] | Li J;Stover HDH.Doubly pH-Responsive Pickering Emulsion[J].Langmuir: The ACS Journal of Surfaces and Colloids,200823(23):13237-13240. |
| [28] | Binks BP;Rodrigues JA;Frith WJ.Synergistic interaction in emulsions stabilized by a mixture of silica nanoparticles and cationic surfactant[J].Langmuir: The ACS Journal of Surfaces and Colloids,20077(7):3626-3636. |
| [29] | Binks BP;Desforges A;Duff DG.Synergistic stabilization of emulsions by a mixture of surface-active nanoparticles and surfactant[J].Langmuir: The ACS Journal of Surfaces and Colloids,200726(26):1098-1106. |
| [30] | Binks BP;Whitby CP.Nanoparticle silica-stabilised oil-in-water emulsions: improving emulsion stability[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,20051/3(1/3):105-115. |
| [31] | Akay G;Birch MA;Bokhari MA.Microcellular polyHIPE polymer supports osteoblast growth and bone formation in vitro.[J].Biomaterials,200418(18):3991-4000. |
| [32] | 曾亮 .纳米羟基磷灰石表面改性及其增强PCL复合材料性能研究[D].湘潭大学,2010. |
| [33] | Choi HW;Lee HJ;Kim KJ;Kim HM;Lee SC.Surface modification of hydroxyapatite nanocrystals by grafting polymers containing phosphonic acid groups[J].Journal of Colloid and Interface Science,20061(1):277-281. |
| [34] | 宋晓峰;凌风光;陈学思.纳米羟基磷灰石表面接枝聚合左旋丙交酯[J].高分子学报,2013(1):95-101. |
| [35] | Dajana Milovac;Gloria Gallego Ferrer;Marica Ivankovic;Hrvoje Ivankovic.PCL-coated hydroxyapatite scaffold derived from cuttlefish bone: Morphology, mechanical properties and bioactivity[J].Materials science & engineering, C. Materials for Biogical applications,2014:437-445. |
| [36] | Hong Jae Lee;Hyung Woo Choi;Kyung Ja Kim.Modification of Hydroxyapatite Nanosurfaces for Enhanced Colloidal Stability and Improved Interfacial Adhesion in Nanocomposites[J].Chemistry of Materials: A Publication of the American Chemistry Society,200621(21):5111-5118. |
| [37] | Xueyu Qiu;Zhongkui Hong;Junli Hu;Li Chen;Xuesi Chen;Xiabin Jing.Hydroxyapatite Surface Modified by L-Lactic Acid and Its Subsequent Grafting Polymerization of L-Lactide[J].Biomacromolecules,20053(3):1193-1199. |
| [38] | Hong ZK;Zhang PB;He CL;Qiu XY;Liu AX;Chen L;Chen XS;Jing XB.Nano-composite of poly(L-lactide) and surface grafted hydroxyapatite: Mechanical properties and biocompatibility[J].Biomaterials,200532(32):6296-6304. |
| [39] | Binks BP.;Lumsdon SO..Influence of particle wettability on the type and stability of surfactant-free emulsions[J].Langmuir: The ACS Journal of Surfaces and Colloids,200023(23):8622-8631. |
| [40] | Stiller S.;Gers-Barlag H.;Lergenmueller M.;Pflucker F.;Schulz J. Wittern KP.;Daniels R..Investigation of the stability in emulsions stabilized with different surface modified titanium dioxides[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,20042/3(2/3):261-267. |
| [41] | Menner A;Verdejo R;Shaffer M;Bismarck A.Particle-stabilized surfactant-free medium internal phase emulsions as templates for porous nanocomposite materials: Poly-pickering-foams[J].Langmuir: The ACS Journal of Surfaces and Colloids,20075(5):2398-2403. |
| [42] | Fujii, Syuji;Okada, Masahiro;Sawa, Hidekatsu;Furuzono, Tsutomu;Nakamura, Yoshinobu.Hydroxyapatite Nanoparticles as Particulate Emulsifier: Fabrication of Hydroxyapatite-Coated Biodegradable Microspheres[J].Langmuir,200917(17):9759-9766. |
| [43] | Fujii, S.;Okada, M.;Nishimura, T.;Maeda, H.;Sugimoto, T.;Hamasaki, H.;Furuzono, T.;Nakamura, Y..Hydroxyapatite-armored poly(ε-caprolactone) microspheres and hydroxyapatite microcapsules fabricated via a Pickering emulsion route[J].Journal of Colloid and Interface Science,2012:1-8. |
| [44] | Okada, M.;Maeda, H.;Fujii, S.;Nakamura, Y.;Furuzono, T..Formation of pickering emulsions stabilized via interaction between nanoparticles dispersed in aqueous phase and polymer end groups dissolved in oil phase[J].Langmuir: The ACS Journal of Surfaces and Colloids,201225(25):9405-9412. |
| [45] | Michele Iafisco;Barbara Palazzo;Tomoko Ito;Makoto Otsuka;Mamoru Senna;Jose Manuel Delgado-Lopez;Jaime Gomez-Morales;Anna Tampieri;Maria Prat;Lia Rimondini.Preparation of core-shell poly(L-lactic) acid-nanocrystalline apatite hollow microspheres for bone repairing applications[J].Journal of Materials Science. Materials in Medicine,201211(11):2659-2669. |
| [46] | Shinto, H.;Hirata, T.;Fukasawa, T.;Fujii, S.;Maeda, H.;Okada, M.;Nakamura, Y.;Furuzono, T..Effect of interfacial serum proteins on melanoma cell adhesion to biodegradable poly(l-lactic acid) microspheres coated with hydroxyapatite[J].Colloids and Surfaces, B. Biointerfaces,2013:8-15. |
| [47] | Maeda, H.;Okada, M.;Fujii, S.;Nakamura, Y.;Furuzono, T..Pickering-type water-in-oil-in-water multiple emulsions toward multihollow nanocomposite microspheres[J].Langmuir: The ACS Journal of Surfaces and Colloids,201017(17):13727-13731. |
| [48] | Fujii, S.;Miyanari, Y.;Nishimura, T.;Yokoyama, Y.;Hamasaki, S.;Okada, M.;Furuzono, T.;Matsuda, S.;Takamori, H.;Nakamura, Y..In vitro degradation of hydroxyapatite nanoparticle-coated biodegradable microspheres[J].Polymer Degradation and Stability,20131(1):377-386. |
| [49] | Tanaka H.;Kandori K.;Ishikawa T.;Yasukawa A..MODIFICATION OF CALCIUM HYDROXYAPATITE USING ALKYL PHOSPHATES[J].Langmuir: The ACS Journal of Surfaces and Colloids,19974(4):821-826. |
| [50] | Michele Iafisco;Monica Sandri;Silvia Panseri.Magnetic Bioactive and Biodegradable Hollow Fe-Doped Hydroxyapatite Coated Poly(L-lactic) Acid Micro-nanospheres[J].Chemistry of Materials: A Publication of the American Chemistry Society,201313(13):2610-2617. |
| [51] | Borum-Nicholas L.;Wilson OC..Surface modification of hydroxyapatite. Part I. Dodecyl alcohol[J].Biomaterials,200321(21):3671-3679. |
| [52] | Wilson OC;Hull JR.Surface modification of nanophase hydroxyapatite with chitosan[J].Materials science & engineering, C. Biomimetic and supramolecular systems,20083(3):434-437. |
| [53] | 魏俊超;马丽莉;戴延凤;陈义旺;章培标;崔毅;陈学思.改性羟基磷灰石/聚乳酸纳米复合材料的结晶行为[J].高等学校化学学报,2011(11):2674-2679. |
| [54] | Hong Z;Zhang P;Liu A;Chen L;Chen X;Jing X.Composites of poly(lactide-co-glycolide) and the surface modified carbonated hydroxyapatite nanoparticles.[J].Journal of biomedical materials research, Part A,20073(3):515-522. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%