镁合金具有低密度、高比强度、易回收利用等优点,在电子、汽车、航空航天等领域得到了广泛的应用。但是镁合金强度低、变形加工困难等缺点成为阻碍其大规模应用的主要问题。长周期堆垛有序(LPSO)结构增强镁合金具有较高的强度和较好的塑性,引起了人们的广泛关注。列举了镁合金中5种长周期结构类型及其研究进展,分析了常见的4种长周期结构制备方法的特点,阐述了5种长周期结构特征及其表征方法,分析了长周期结构的强化机制,指出了今后的研究方向。
Magnesium alloy has the advantages of low density,high specific strength,easy recycling and so on. It has been widely used in the fields of electronics,automobile and aerospace.However,it has become a major prob-lem in the large scale application of magnesium alloys because of its low strength,its difficulty of deformation proces-sing and so on.The long period stacking ordered(LPSO)structure reinforced magnesium alloy has aroused wide atten-tion because of its better strength and plasticity.Five types of LPSO structure and their research progress in mag-nesium alloys are listed.The preparation methods of the LPSO structure are analyzed.Five types of LPSO structures and the corresponding characterization methods are described.The strengthening mechanism of LPSO structure is ana-lyzed and the future research direction is pointed out.
参考文献
[1] | 杨媛;李加强;宋宏宝;刘鹏成.镁合金的应用及其成形技术研究现状[J].热加工工艺,2013(8):24-27. |
[2] | 刘庆.镁合金塑性变形机理研究进展[J].金属学报,2010(11):1458-1472. |
[3] | Luo ZP.;Zhang SQ..High-resolution electron microscopy on the X-Mg12ZnY phase in a high strength Mg-Zn-Zr-Y magnesium alloy[J].Journal of Materials Science Letters,20009(9):813-815. |
[4] | Yoshihito Kawamura;Kentaro Hayashi;Akihisa Inoue.Rapidly Solidified Powder Metallurgy Mg_(97)Zn_1Y_2 Alloys with Excellent Tensile Yield Strength above 600 MPa[J].Materials transactions,20017(7):1172-1176. |
[5] | E. Abe;Y. Kawamura;K. Hayashi.Long-period ordered structure in a high-strength nanocrystalline Mg-1 at percent Zn-2 at percent Y alloy studied by atomic-resolution Z-contrast STEM[J].Acta materialia,200215(15):3845-3857. |
[6] | T. Itoi;T. Seimiya;Y. Kawamura;M. Hirohashi.Long period stacking structures observed in Mg_(97)Zn_1Y_2 alloy[J].Scripta materialia,20042(2):107-111. |
[7] | M. Matsuda;S. Ii;Y. Kawamura.Variation of long-period stacking order structures in rapidly solidified Mg_(97)Zn_1Y_2 alloy[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20051/2(1/2):269-274. |
[8] | Akihisa Inoue;Mitsuhide Matsushita;Yoshihito Kawamura.Novel Hexagonal Structure of Ultra-High Strength Magnesium-Based Alloys[J].Materials transactions,20023(3):580-584. |
[9] | Kenji Amiya;Tetsu Ohsuna;Akihisa Inoue.Long-Period Hexagonal Structures in Melt-Spun Mg{sub}97Ln{sub}2Zn{sub}1 (Ln=Lanthanide Metal) Alloys[J].Materials transactions,200310(10):2151-2156. |
[10] | M. Matsuda;S. Ii;Y. Kawamura;Y. Ikuhara;M. Nishida.Interaction between long period stacking order phase and deformation twin in rapidly solidified Mg_(97)Zn_1Y_2 alloy[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20041/2(1/2):447-452. |
[11] | Michiaki Yamasaki;Minami Sasaki;Masahiko Nishijima.Formation of 14H long period stacking ordered structure and profuse stacking faults in Mg-Zn-Gd alloys during isothermal aging at high temperature[J].Acta materialia,200720(20):6798-6805. |
[12] | R.G. Li;D.Q. Fang;J. An.Comparative studies on the microstructure evolution and fracture behavior between hot-rolled and as-cast Mg_(96)ZnY_3 alloys[J].Materials Characterization,20096(6):470-475. |
[13] | Y.M. Zhu;A.J. Morton;J.F. Nie.The 18R and 14H long-period stacking ordered structures in Mg-Y-Zn alloys[J].Acta materialia,20108(8):2936-2947. |
[14] | 唐平英;吴萌萌;唐壁玉;王继伟;彭立明;丁文江.Mg97Y2Zn1合金中18R型长周期有序相的微观结构[J].中国有色金属学报(英文版),2011(4):801-806. |
[15] | 刘欢;薛烽;白晶.长周期堆垛有序结构强化Mg-Zn-Y合金的组织与性能[J].东南大学学报(自然科学版),2012(3):478-482. |
[16] | D. Egusa;E. Abe.The structure of long period stacking/order Mg-Zn-RE phases with extended non-stoichiometry ranges[J].Acta materialia,20121(1):166-178. |
[17] | O?orbe, E.;Garcés, G.;Pérez, P.;Adeva, P..Effect of the LPSO volume fraction on the microstructure and mechanical properties of Mg-Y _(2X) -Zn _X alloys[J].Journal of Materials Science,20122(2):1085-1093. |
[18] | J. Grobner;A. Kozlov;X.Y. Fang.Phase equilibria and transformations in ternary Mg-rich Mg-Y-Zn alloys[J].Acta materialia,201217(17):5948-5962. |
[19] | 刘欢;薛烽;白晶;周健;孙扬善.含长周期堆垛有序结构Mg94Zn2Y4挤压态合金的显微组织与力学性能[J].中国有色金属学报(英文版),2013(12):3598-3603. |
[20] | 刘欢;薛烽;白晶;周健;孙扬善.高温退火对铸态和挤压态Mg97Y2Zn1合金中长周期堆垛有序结构形态的影响[J].金属学报,2013(10):1255-1263. |
[21] | Zhao,X.;Shi,L.-L.;Xu,J..Biodegradable Mg-Zn-Y alloys with long-period stacking ordered structure: Optimization for mechanical properties[J].Journal of the mechanical behavior of biomedical materials,2013:181-190. |
[22] | Yongbo XU;Daokui XU;Xiaohong SHAO;En-hou HAN.Guinier-Preston Zone, Quasicrystal and Long-period Stacking Ordered Structure in Mg-based Alloys, A Review[J].金属学报(英文版),2013(3):217-231. |
[23] | M. Tane;Y. Nagai;H. Kimizuka.Elastic properties of an Mg-Zn-Y alloy single crystal with a long-period stacking-ordered structure[J].Acta materialia,201317(17):6338-6351. |
[24] | Liu, H.;Xue, F.;Bai, J.;Sun, Y..Effect of heat treatments on the microstructure and mechanical properties of an extruded Mg_(95.5)Y_3Zn_(1.5) alloy[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2013:261-267. |
[25] | Dandan Wang;Wenbo Zhang;Ximei Zong;Kaibo Nie;Chunxiang Xu;Jinshan Zhang.Abundant long period stacking ordered structure induced by Ni addition into Mg-Gd-Zn alloy[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2014:355-358. |
[26] | Kim, Jin-Kyung;Sandloebes, Stefanie;Raabe, Dierk.On the room temperature deformation mechanisms of a Mg-Y-Zn alloy with long-period-stacking-ordered structures[J].Acta materialia,2015:414-423. |
[27] | H. Liu;F. Xue;J. Bai;J. Zhou.Microstructure and Mechanical Properties of a Mg_(94)Y_4Ni_2 Alloy with Long Period Stacking Ordered Structure[J].Journal of Materials Engineering and Performance,201311(11):3500-3506. |
[28] | Makoto Matsuura;Kazuya Konno;Mitsuhiko Yoshida.Precipitates with Peculiar Morphology Consisting of a Disk-Shaped Amorphous Core Sandwiched between 14H-Typed Long Period Stacking Order Crystals in a Melt-Quenched Mg_(98)Cu_1Y_1 Alloy[J].Materials transactions,20064(4):1264-1267. |
[29] | Yoshihlto Kawamura;Takayuki Kasahara;Shogo Izumi.Elevated temperature Mg_(97)Y_2Cu_1 alloy with long period ordered structure[J].Scripta materialia,20065(5):453-456. |
[30] | X. Hui;W. Dong;G.L. Chen.Formation, microstructure and properties of long-period order structure reinforced Mg-based bulk metallic glass composites[J].Acta materialia,20073(3):907-920. |
[31] | T. Itoi;K. Takahashi;H. Moriyama.A high-strength Mg-Ni-Y alloy sheet with a long-period ordered phase prepared by hot-rolling[J].Scripta materialia,200810(10):1155-1158. |
[32] | Yasumasa Chino;Mamoru Mabuchi;Shigehiro Hagiwara.Novel equilibrium two phase Mg alloy with the long-period ordered structure[J].Scripta materialia,20047(7):711-714. |
[33] | 刘静远;张振忠;华旻;马立群;沈晓冬.快速凝固Mg-Zn-Y合金薄带的制备及凝固组织特征[J].铸造技术,2006(3):258-262. |
[34] | 郑水云;徐春杰;张忠明;郭学锋;孟令楠.快速凝固Mg94.6Zn4.8Y0.6镁合金薄带的组织与性能[J].铸造技术,2006(1):39-42. |
[35] | 王红梅;王宇飞.镁合金中的LPSO结构[J].材料导报,2010(z1):467-472. |
[36] | 付建强;孙威;谢中柱;刘林林;张泽.合金元素对铸态镁合金中长周期堆垛结构的形成与特征的影响[J].金属学报,2008(4):428-432. |
[37] | Mitsuhiro Matsuda;Shinji Ando;Minoru Nishida.Dislocation Structure in Rapidly Solidified Mg_(97)Zn_1Y_2 Alloy with Long Period Stacking Order Phase[J].Materials transactions,20052(2):361-364. |
[38] | 蒋毅;唐壁玉.溶偏析对Mg-Y-Zn合金层错能的影响[J].广西大学学报(自然科学版),2011(6):887-891. |
[39] | K. Hagihara;A. Kinoshita;Y. Sugino;M. Yamasaki;Y. Kawamura;H.Y. Yasuda;Y. Umakoshi.Effect of long-period stacking ordered phase on mechanical properties of Mg97Zn1Y2 extruded alloy[J].Acta materialia,201019(19):6282-6293. |
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