近年来,离子液体以其独特的优势成为催化体系研究的热点。离子液体具有良好的溶解性、较低的挥发性、可设计性和可重复使用性等特点,作为反应催化剂和溶剂,其相比于传统溶剂展现出更好的选择性和反应速率。综述了离子液体作为反应催化剂、反应溶剂、共催化剂或活性催化剂、负载型离子液体等在催化体系中的应用研究进展,并展望了离子液体在催化中的发展前景。
In recent years,ionic liquid has been a hot research topic in catalytic systems for its unique advanta-ges,such as good solubility,low volatility,readily tunable catalytic activities and good recyclability.As a reaction catalyst and solvents,it shows better selectivity and reaction rate than the traditional solvents.The application ad-vances of ionic liquid as reaction catalyst,reaction solvent,co-catalyst or active catalyst,supported ionic liquid and so on in catalytic systems are reviewed.The perspectives on catalytic processes with assistance of ionic liquids are also provided.
参考文献
[1] | Welton Thomas.Room-Temperature lonic Liquids.Solvents for Synthesis and Catalysis[J].Chemical Reviews,19998(8):2071-2083. |
[2] | Marsh KN;Boxall JA;Lichtenthaler R.Room temperature ionic liquids and their mixtures - a review[J].Fluid Phase Equilibria,20041(1):93-98. |
[3] | Zhao H.Innovative applications of ionic liquids as "greem" engineering liquids[J].Chemical Engineering Communications,200611(11):1660-1677. |
[4] | Davis JH.Task-specific ionic liquids[J].Chemistry Letters,20049(9):1072-1077. |
[5] | Martyn J. Earle;Kenneth R. Seddon.Ionic liquids. Green solvents for the future[J].Pure and Applied Chemistry,20007(7):1391-1398. |
[6] | 陈慧;戴立益;单永奎;何鸣元.新型离子液体体系催化苯与1-己烯的烷基化反应[J].应用化学,2003(9):829-832. |
[7] | 陈敏;张春燕;袁新华;张燕;刘华;程晓农.[Emim]Cl-AlCl3离子液体催化蒽与草酰氯的Friedel-Crafts酰基化反应[J].化学试剂,2007(10):628-630,632. |
[8] | Tom Welton.Ionic liquids in catalysis[J].Coordination chemistry reviews,200421/24(21/24):2459-2477. |
[9] | Susheel J.Nara;R.Harjani;Manikrao M.Salunkhe.Friedel-crafts sulfonylation in 1-butyl-3-methylimidazolium chloroaluminate ionic liquids[J].The Journal of Organic Chemistry,200125(25):8616-8620. |
[10] | 路军;李迎迎;杨玲;白银娟;田敏.芳香醛与硫代巴比妥酸的缩合反应研究[J].有机化学,2003(9):958-960. |
[11] | 胡燚;李恒;康晖;韦萍.离子液体中缩合反应研究进展[J].化学试剂,2006(6):341-344,374. |
[12] | B. Ellis;W. Keim;P. Wasserscheid.Linear dimerisation of but-1-ene in biphasic mode using buffered chloroaluminate ionic liquid solvents[J].Chemical communications,19994(4):337-338. |
[13] | Yves Chauvin;Sandra Einloft;Helene Olivier.Catalytic Dimerization of Propene by Nickel-Phosphine Complexes in 1-Butyl-3-methylimidazolium Chloride/AlEt_xCl_(3-x) (x = 0, 1) Ionic Liquids[J].Industrial & Engineering Chemistry Research,19954(4):1149-1155. |
[14] | P.Wasserscheid;M.Eichmann.Selective dimerisation of 1-butene in biphasic mode using buffered chloroaluminate ionic liquid solvnets-design and application of a continuosu loop reactor[J].Catalysis Today,20012/4(2/4):309-316. |
[15] | 杨昕;戴立益;单永奎;何鸣元.离子液体体系中1-丁烯二聚反应的研究[J].催化学报,2003(12):895-899. |
[16] | 杨宏训;黄妙良;韩鹏;姜奇伟;吴子豹;吴季怀.染料敏化太阳能电池研究进展[J].材料导报,2006(9):120-123,127. |
[17] | 孙珊珊 .适用于锂离子电池的新型离子液体电解液的研究[D].哈尔滨工业大学,2009. |
[18] | Michel Armand;Frank Endres;Douglas R. MacFarlane.Ionic-liquid materials for the electrochemical challenges of the future[J].Nature materials,20098(8):621-629. |
[19] | G.-T. Kim;S.S. Jeong;M.-Z. Xue;A. Balducci;M. Winter;S. Passerini;F. Alessandrini;G.B. Appetecchi.Development of ionic liquid-based lithium battery prototypes[J].Journal of Power Sources,2012Feb.1(Feb.1):239-246. |
[20] | Sara T.Parker;Jason D.Slinker;Michael S.Lowry;Marshall P.Cox;Stefan Bernhard;George G.Malliaras.Improved Turn-on Times of Iridium Electroluminescent Devices by Use of Ionic Liquids[J].Chemistry of Materials,200512(12):3187-3190. |
[21] | Jeff Xin Wu;Brandon Beck;Rex X.Ren.Catalytic Rosenmund-von Braun reaction in halide-based ionic liquids[J].Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry,20023(3):387-389. |
[22] | 顾彦龙;彭家建;乔琨;杨宏洲;石峰;邓友全.室温离子液体及其在催化和有机合成中的应用[J].化学进展,2003(3):222-241. |
[23] | Silvina Guernik;Adi Wolfson;Moti Herskowitz;Noam Greenspoon;Shimona Geresh.A novel system consisting of Rh-DuPHOS and ionic liquid for asymmetric hydrogenations[J].Chemical communications,200122(22):2314-2315. |
[24] | Mehnert CP.Supported ionic liquid phases[J].Chemistry: A European journal,20041(1):50-56. |
[25] | Mao LF;Li FW;Peng HH;Xia CG.Immobilized ionic liquid/zinc chloride: Heterogeneous catalyst for synthesis of cyclic carbonates from carbon dioxide and epoxides[J].Journal of molecular catalysis, A. Chemical,20061/2(1/2):265-269. |
[26] | 朴玲钰;付晓;杨雅立;陶国宏;寇元.离子液体的酸性测定及其催化的二苯醚/十二烯烷基化反应[J].催化学报,2004(1):44-48. |
[27] | 乔煙;邓友全.超强酸性室温离子液体反应介质中烷烃羰化研究[J].化学学报,2002(8):1520-1523. |
[28] | Calo V.;Giannoccaro P.;Nacci A.;Monopoli A..Pd-benzothiazole carbene catalysed carbonylation of aryl halides in ionic liquids[J].Journal of Organometallic Chemistry,20021/2(1/2):152-157. |
[29] | Feng Shi;Jiajian Peng;Youquan Deng.Highly efficient ionic liquid-mediated palladium complex catalyst system for the oxidative carbonylation of amines[J].Journal of Catalysis,20032(2):372-375. |
[30] | Roberta Bernini;Antonietta Coratti;Giancarlo Fabrizi;Antonella Goggiamani.CH_3ReO_3/H_2O_2 in room temperature ionic liquids:an homogeneous recyclable catalytic system for the Baeyer-Villiger reaction[J].Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry,200350(50):8991-8994. |
[31] | 裴文;沈忱;莫峻;许孝良.离子液体中用Heck反应合成2-取代萘烯丙醇化合物[J].有机化学,2007(5):653-655. |
[32] | 顾彦龙;杨宏洲;邓友全.室温离子液体中双环戊二烯加氢以及金刚烷合成[J].石油化工,2002(5):345-348. |
[33] | Vallette H;Pican S;Boudou C;Levillain J;Plaquevent JC;Gaumont AC.Palladium catalyzed C-P cross-coupling reactions in ionic liquids[J].Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry,200629(29):5191-5193. |
[34] | 张婧;刘月明;李宁宁;吴海虹;李晓红;谢伟;赵忠林;吴鹏;何鸣元.季铵盐功能化的钛硅分子筛催化丙烯氧化酯化合成碳酸丙烯酯[J].催化学报,2008(7):589-591. |
[35] | 沈加春;郭建平;孙艳美;唐斌艳;陈小花;尹笃林.SBA-15固载离子液体功能化脯氨酸的制备及其催化Knoevenagel缩合反应[J].催化学报,2010(7):827-832. |
[36] | 郝翊彤;颜文超;李珂.NaY分子筛负载型离子液体在催化裂化汽油脱硫中的应用[J].石油化工高等学校学报,2013(4):27-30,56. |
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