石墨烯具有良好的电子传导性、巨大的表面积、稳定的化学和机械稳定性等,在分子氧催化还原(ORR)反应中可以有效地改进催化剂的催化活性,是过渡金属大环催化剂新的基底材料.对石墨烯支持的非贵金属氮杂环复合材料在ORR催化反应中的应用以及影响催化O2活性的因素进行了讨论.重点讨论了卟啉和酞菁中心金属核,Co和Fe,以及卟啉和酞菁作为N的前驱体对ORR电催化活性的影响,并展望了非贵金属氧还原催化剂在燃料电池中的研究发展方向.
参考文献
| [1] | Mani, Veerappan;Devasenathipathy, Rajkumar;Chen, Shen-Ming;Gu, Jiun-An;Huang, Sheng-Tung.Synthesis and characterization of graphene-cobalt phthalocyanines and graphene-iron phthalocyanine composites and their enzymatic fuel cell application[J].Renewable energy,2015Feb.(Feb.):867-874. |
| [2] | Kruusenberg, I.;Mondal, J.;Matisen, L.;Sammelselg, V.;Tammeveski, K..Oxygen reduction on graphene-supported MN_4 macrocycles in alkaline media[J].Electrochemistry communications,2013:18-22. |
| [3] | Zhang, Shiming;Zhang, Heyou;Hua, Xing;Chen, Shengli.Tailoring molecular architectures of Fe phthalocyanine on nanocarbon supports for high oxygen reduction performance[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201518(18):10013-10019. |
| [4] | Lili Cui;Tao Pu;Ying Liu;Xingquan He.Layer-by-layer construction of graphene/cobalt phthalocyanine composite film on activated GCE for application as a nitrite sensor[J].Electrochimica Acta,2013:559-564. |
| [5] | Joel N. Lekitima;Kenneth I. Ozoemena;Charl J. Jafta.High-performance aqueous asymmetric electrochemical capacitors based on graphene oxide/cobalt(II)-tetrapyrazinoporphyrazine hybrids[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,20138(8):2821-2826. |
| [6] | Ingrid Ponce;J. Francisco Suva;Ruben Onate.Enhancement of the Catalytic Activity of Fe Phthalocyanine for the Reduction of O2 Anchored to Au(111) via Conjugated Self-Assembled Monolayers of Aromatic Thiols As Compared to Cu Phthalocyanine[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201229(29):15329-15341. |
| [7] | Stephen Nyoni;Tebello Nyokong.Development of Graphene/CdSe Quantum Dots-Co Phthalocyanine Nanocomposite for Oxygen Reduction Reaction[J].Electroanalysis,201410(10):2261-2272. |
| [8] | Xia Gao;Jingfang Wang;Zhao Ma;Jianshan Ye.Iron tetrasulfophthalocyanine functionalized graphene nanosheets for oxygen reduction reaction in alkaline media[J].Electrochimica Acta,2014:543-550. |
| [9] | Cheng, Mu-Jeng;Head-Gordon, Martin;Bell, Alexis T..How to Chemically Tailor Metal-Porphyrin-Like Active Sites on Carbon Nanotubes and Graphene for Minimal Overpotential in the Electrochemical Oxygen Evolution and Oxygen Reduction Reactions[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201451(51):29482-29491. |
| [10] | Jahan, M.;Bao, Q.;Loh, K.P..Electrocatalytically active graphene-porphyrin MOF composite for oxygen reduction reaction[J].Journal of the American Chemical Society,201215(15):6707-6713. |
| [11] | Jiang, Liqing;Cui, Lili;He, Xingquan.Cobalt-porphyrin noncovalently functionalized graphene as nonprecious-metal electrocatalyst for oxygen reduction reaction in an alkaline medium[J].Journal of solid state electrochemistry,20152(2):497-506. |
| [12] | Han Yin;Chenzhen Zhang;Fei Liu;Yanglong Hou.Hybrid of Iron Nitride and Nitrogen-Doped Graphene Aerogel as Synergistic Catalyst for Oxygen Reduction Reaction[J].Advanced functional materials,201420(20):2930-2937. |
| [13] | Chenzhen Zhang;Rui Hao;Han Yin.Iron phthalocyanine and nitrogen-doped graphene composite as a novel non-precious catalyst for the oxygen reduction reaction[J].Nanoscale,201223(23):7326-7329. |
| [14] | Xiaochun Zhou;Changpeng Liu;Jianhui Liao;Tianhong Lu;Wei Xing.Platinum-macrocycle co-catalysts for electro-oxidation of formic acid[J].Journal of Power Sources,20082(2):481-488. |
| [15] | Yuanyuan Jiang;Yizhong Lu;Xiangyu Lv.Enhanced Catalytic Performance of Pt-Free Iron Phthalocyanine by Graphene Support for Effcient Oxygen Reduction Reaction[J].ACS catalysis,20136(6):1263-1271. |
| [16] | Lili Cui;Guojun Lv;Zhiyu Dou;Xingquan He.Fabrication of iron phthalocyanine/graphene micro/nanocomposite by solvothermally assisted π-π assembling method and its application for oxygen reduction reaction[J].Electrochimica Acta,2013:272-278. |
| [17] | Ying Liu;Yan-Ying Wu;Guo-Jun Lv;Tao Pu;Xing-Quan He;Li-Li Cui.Iron(II) phthalocyanine covalently functionalized graphene as a highly efficient non-precious-metal catalyst for the oxygen reduction reaction in alkaline media[J].Electrochimica Acta,2013:269-278. |
| [18] | Guojun Lv;Lili Cui;Yanying Wu.A novel cobalt tetranitrophthalocyanine/graphene composite assembled by an in situ solvothermal synthesis method as a highly efficient electrocatalyst for the oxygen reduction reaction in alkaline medium[J].Physical chemistry chemical physics: PCCP,201331(31):13093-13100. |
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