三维石墨烯具有独特的三维多孔结构，不仅增加了与电解液的接触面积，同时为固定在其表面的活性物质提供了快速的电子传输通道，有效地提高了超级电容器的电化学性能，使其被认为是最有前景的超级电容器电极材料。综述了目前获得多孔结构、大比表面积、优异导电性和良好力学性能的三维石墨烯的方法，并简述了其复合材料在超级电容器领域的应用现状。
The porous structure of three-dimensional graphene not only improves the contact area with the electrolyte but also provides a fast electron transport channels for the active materials anchored on it,therefore the electrochemical performance of the su-percapacitors can be effectively enhanced,which makes them to be the promising materials for supercapacitors.This review summari-zes the preparation methods of the three-dimensional graphene with a porous structure,large specific surface area,good electrical conductivity and excellent mechanical properties.In addition,the application status of the three-dimensional graphene composites in supercapacitors is described.
参考文献
| [1] | Balandin AA;Ghosh S;Bao WZ;Calizo I;Teweldebrhan D;Miao F;Lau CN.Superior thermal conductivity of single-layer graphene[J].Nano letters,20083(3):902-907. |
| [2] | Changgu Lee;Xiaoding Wei;Jeffrey W. Kysar;James Hone.Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene[J].Science,20085887(5887):385-388. |
| [3] | Li D;Muller MB;Gilje S;Kaner RB;Wallace GG.Processable aqueous dispersions of graphene nanosheets[J].Nature nanotechnology,20082(2):101-105. |
| [4] | Reina A;Jia XT;Ho J;Nezich D;Son HB;Bulovic V;Dresselhaus MS;Kong J.Large Area, Few-Layer Graphene Films on Arbitrary Substrates by Chemical Vapor Deposition[J].Nano letters,20091(1):30-35. |
| [5] | Zongping Chen;Wencai Ren;Libo Gao.Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition[J].Nature materials,20116(6):424-428. |
| [6] | Ji, H.;Zhang, L.;Pettes, M.T.;Li, H.;Chen, S.;Shi, L.;Piner, R.;Ruoff, R.S..Ultrathin graphite foam: A three-dimensional conductive network for battery electrodes[J].Nano letters,20125(5):2446-2451. |
| [7] | 周国珺;叶志凯;石微微;刘吉洋;奚凤娜.三维（3D）石墨烯及其复合材料的应用[J].化学进展,2014(6):950-960. |
| [8] | Hong Yan Yue;Shuo Huang;Jian Chang;Chaejeong Heo;Fei Yao;Subash Adhikari;Fethullah Gunes;Li Chun Liu;Tae Hoon Lee;Eung Seok Oh;Bing Li;Jian Jiao Zhang;Ta Quang Huy;Nguyen Van Luan;Young Hee Lee.ZnO Nanowire Arrays on 3D Hierachical Graphene Foam: Biomarker Detection of Parkinson's Disease[J].ACS nano,20142(2):1639-1646. |
| [9] | Mi Zhou;Tianquan Lin;Fuqiang Huang;Yajuan Thong;Zhou Wang;Yufeng Tang;Hui Bi;Dongyun Wan;Jianhua Lin.Highly Conductive Porous Graphene/Ceramic Composites for Heat Transfer and Thermal Energy Storage[J].Advanced functional materials,201318(18):2263-2269. |
| [10] | Matthias Mecklenburg;Arnim Schuchard;Yogendra Kumar Mishra;Soeren Kaps;Rainer Adelung;Andriy Lotnyk;Lorenz Kienle;Karl Schulte.Aerographite: Ultra Lightweight, Flexible Nanowall, Carbon Microtube Material with Outstanding Mechanical Performance[J].Advanced Materials,201226(26):3486-3490. |
| [11] | Ji Chen;Kaixuan Sheng;Peihui Luo;Chun Li;Caoquan Shi.Graphene Hydrogels Deposited in Nickel Foams for High-Rate Electrochemical Capacitors[J].Advanced Materials,201233(33):4569-4573. |
| [12] | Bong Gill Choi;MinHo Yang;Won Hi Hong;Jang Wook Choi;Yun Suk Huh.3D Macroporous Graphene Frameworks for Supercapacitors with High Energy and Power Densities[J].ACS nano,20125(5):4020-4028. |
| [13] | Xia, X.;Tu, J.;Mai, Y.;Chen, R.;Wang, X.;Gu, C.;Zhao, X..Graphene sheet/porous NiO hybrid film for supercapacitor applications[J].Chemistry: A European journal,201139(39):10898-10905. |
| [14] | Xu, Y.;Sheng, K.;Li, C.;Shi, G..Self-assembled graphene hydrogel via a one-step hydrothermal process[J].ACS nano,20107(7):4324-4330. |
| [15] | Bai, H;Li, C;Wang, XL;Shi, GQ.A pH-sensitive graphene oxide composite hydrogel[J].Chemical communications,201014(14):2376-2378. |
| [16] | Maher F. El-Kady;Veronica Strong;Sergey Dubin;Richard B. Kaner.Laser Scribing of High-Performance and Flexible Graphene-Based Electrochemical Capacitors[J].Science,2012Mar.16 TN.6074(Mar.16 TN.6074):1326-1330. |
| [17] | Zhiqiong Niu;Jun Chen;Huey Hoon Hng;Jan Ma;Xiaodong Chen.A Leavening Strategy to Prepare Reduced Graphene Oxide Foams[J].Advanced Materials,201230(30):4144-4150. |
| [18] | Haiyan Sun;Zhen Xu;Chao Gao.Multifunctional, Ultra-Flyweight, Synergistically Assembled Carbon Aerogels[J].Advanced Materials,201318(18):2554-2560. |
| [19] | Xiaochen Dong;Xuewan Wang;Jing Wang.Synthesis of a MnO2-graphene foam hybrid with controlled MnO2 particle shape and its use as a supercapacitor electrode[J].Carbon: An International Journal Sponsored by the American Carbon Society,201213(13):4865-4870. |
| [20] | Peng, L.;Peng, X.;Liu, B.;Wu, C.;Xie, Y.;Yu, G..Ultrathin two-dimensional MnO_2/graphene hybrid nanostructures for high-performance, flexible planar supercapacitors[J].Nano letters,20135(5):2151-2157. |
| [21] | He, Y.;Chen, W.;Li, X.;Zhang, Z.;Fu, J.;Zhao, C.;Xie, E..Freestanding three-dimensional graphene/Mno_2 composite networks as ultralight and flexible supercapacitor electrodes[J].ACS nano,20131(1):174-182. |
| [22] | El-Kady, Maher F.;Ihns, Melanie;Li, Mengping;Hwang, Jee Youn;Mousavi, Mir F.;Chaney, Lindsay;Lech, Andrew T.;Kaner, Richard B..Engineering three-dimensional hybrid supercapacitors and microsupercapacitors for high-performance integrated energy storage[J].Proceedings of the National Academy of Sciences of the United States of America,201514(14):4233-4238. |
| [23] | Wang, Chundong;Xu, Junling;Yuen, Muk-Fung;Zhang, Jie;Li, Yangyang;Chen, Xianfeng;Zhang, Wenjun.Hierarchical Composite Electrodes of Nickel Oxide Nanoflake 3D Graphene for High-Performance Pseudocapacitors[J].Advanced functional materials,201440(40):6372-6380. |
| [24] | Jing, Mingjun;Wang, Chiwei;Hou, Hongshuai;Wu, Zhibin;Zhu, Yirong;Yang, Yingchang;Jia, Xinnan;Zhang, Yan;Ji, Xiaobo.Ultrafine nickel oxide quantum dots enbedded with few-layer exfoliative graphene for an asymmetric supercapacitor: Enhanced capacitances by alternating voltage[J].Journal of Power Sources,2015Dec.1(Dec.1):241-248. |
| [25] | Dong, X.-C.;Xu, H.;Wang, X.-W.;Huang, Y.-X.;Chan-Park, M.B.;Zhang, H.;Wang, L.-H.;Huang, W.;Chen, P..3D graphene-cobalt oxide electrode for high-performance supercapacitor and enzymeless glucose detection[J].ACS nano,20124(4):3206-3213. |
| [26] | Weijia Zhou;Xiehong Cao;Zhiyuan Zeng;Wenhui Shi;Yuanyuan Zhu;Qingyu Yan;Hong Liu;Jiyang Wang;Hua Zhang.One-step synthesis of Ni_3S_2 nanorod@Ni(OH)_2 nanosheet core-shell nanostructures on a three-dimensional graphene network for high-performance supercapacitors[J].Energy & environmental science: EES,20137(7):2216-2221. |
| [27] | Shen, Laifa;Wang, Jie;Xu, Guiyin;Li, Hongsen;Dou, Hui;Zhang, Xiaogang.NiCo2S4 Nanosheets Grown on Nitrogen-Doped Carbon Foams as an Advanced Electrode for Supercapacitors[J].Advanced energy materials,20153(3):1. |
| [28] | Wu, Q.;Xu, Y.;Yao, Z.;Liu, A.;Shi, G..Supercapacitors based on flexible graphene/polyaniline nanofiber composite films[J].ACS nano,20104(4):1963-1970. |
| [29] | Xu, J.;Wang, K.;Zu, S.-Z.;Han, B.-H.;Wei, Z..Hierarchical nanocomposites of polyaniline nanowire arrays on graphene oxide sheets with synergistic effect for energy storage[J].ACS nano,20109(9):5019-5026. |
| [30] | Moussa, Mahmoud;El-Kady, Maher F.;Wang, Hao;Michimore, Andrew;Zhou, Qinqin;Xu, Jian;Majeswki, Peter;Ma, Jun.High-performance supercapacitors using graphene/polyaniline composites deposited on kitchen sponge[J].Nanotechnology,20157(7) |
| [31] | Wang, Shiyong;Ma, Li;Gan, Mengyu;Fu, Shenna;Dai, Wenqin;Zhou, Tao;Sun, Xiaowu;Wang, Huihui;Wang, Huining.Free-standing 3D graphene/polyaniline composite film electrodes for high-performance supercapacitors[J].Journal of Power Sources,2015Dec.20(Dec.20):347-355. |
| [32] | Cao, Jianyun;Wang, Yaming;Chen, Junchen;Li, Xiaohong;Walsh, Frank C.;Ouyang, Jia-Hu;Jia, Dechang;Zhou, Yu.Three-dimensional graphene oxide/polypyrrole composite electrodes fabricated by one-step electrodeposition for high performance supercapacitors[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201527(27):14445-14457. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%