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卟啉是一类特殊的大环共轭芳香化合物,在不同条件下能通过非共价键相互作用形成不同形式的聚集体.综述了国内外学者对卟啉化合物聚集行为的研究,详细介绍了不同类型的卟啉分子在不同条件下所形成的聚集体,重点介绍了卟啉所形成聚集体的结构以及影响卟啉聚集体形成的主要因素,并对卟啉聚集体的研究前景进行了展望.

Porphyrin is a special kind of conjugate aromatic macrocyclic compounds.It can form different types of aggregates under different conditions through non-covalent bond interaction.The aggregate behaviors of porphyrin compounds are reviewed.Different aggregates formed by different porphyrins under different conditions are introduced in detail.The aggregation structure and the corresponding effect factors are emphatically discussed.In addition,the prospect of porphyrin aggregation is forecasted.

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