微波辅助合成了取代席夫碱铜金属卟啉.实验结果表明,取代苯甲醛与四(对氨基苯基)铜金属卟啉的缩合反应速率和产率与芳香醛取代基的种类有关,含吸电子基团的芳香醛大于含给电子基团的芳香醛,且随吸电子性的增强而增加,随给电子性的增强而减少.水杨醛席夫碱铜金属卟啉侧链可与铜离子在碱性条件下形成铜配合物,其催化氧化环己烷的转化率达到了7.68％,环己酮的选择性达到了60.87％.
参考文献
| [1] | Hayashi H,Lightcap I V,Tsujimoto M,et al.Electron Transfer Cascade by Organic/Inorganic Ternary Composites of Porphyrin,Zinc Oxide Nanoparticles,and Reduced Graphene Oxide on a Tin Oxide Electrode that Exhibits Efficient Photocurrent Generation[J].J Am Chem Soc,2011,133 (20):7684-7687.,2011. |
| [2] | Wang Y,Cohen B,Jicsinszky L,et al.Femtosecond to Second Studies of a Water-Soluble Porphyrin Derivative in Chemical and Biological Nanocavities[J].Langmuir,2012,28 (9):4363-4372.,2012. |
| [3] | Bonomo L,Lehaire M L,Solari E,et al.The First Crystalline Calcium Porphyrin and Tetrakis tert-butylphenyl) porphyrinato Calcium(Ⅱ):Its Synthesis,Structure,and Binding Properties Towards Alkali and Alkaline Earth Metal Salts[J].Angew Chem,2001,113(4):793-796.,2001. |
| [4] | 王荣民,裴菲,何玉凤,谢云涛,宋鹏飞.低聚壳聚糖负载金属卟啉配合物的制备及生物活性研究[J].化学研究与应用,2012(02):278-281. |
| [5] | 于克贵,周成合,李东红.卟啉类抗癌药物研究新进展[J].化学研究与应用,2007(12):1296-1303. |
| [6] | Zhou C Y,Chan P W,Che C M.Gold (Ⅲ) Porphyrin-Catalyzed Cycloisomerization of Allenones[J].Org Leu,2006,8 (2):325-328.,2006. |
| [7] | Hasobe T,Fukuzumi S,Kamat P V.Organized Assemblies of Single Wall Carbon Nanotubes and Porphyrin for Photochemical Solar Cells:Charge Injection from Excited Porphyrin into Single-Walled Carbon Nanotubes[J].J Phys Chem B,2006,110:25477-25484.,2006. |
| [8] | McCratea A,Carloneb M,Nielsena M,et al.Anaerobic Photocleavage of Supereoiled DNA by a Ruthenium(Ⅱ) Substituted Fluorinated Porphyrin[J].Inorg Chem Commun,2010,13(4):537-539.,2010. |
| [9] | Yella Aswani,Lee Hsuan-Wei,Tsao Hoi Nok,et al.Porphyrin-Sensitized Solar Cells with Cobalt(Ⅱ/Ⅲ) Based Redox Electrolyte Exceed 12 Percent Efficiency[J].Science,2011,334:6294534.,2011. |
| [10] | Roy S,George C B,Ratner M A.Catalysis by a Zinc-Porphyrin-Based Metal-Organic Framework:From Theory to Computational Design[J].J Phys Chem C,2012,116(44):23494-23502.,2012. |
| [11] | Wu A S,Kiaei M Aguirre N,et al.Iron Porphyrin Treatment Extends Survival in a Transgenic Animal Model of Amyotrophic Lateral Sclerosis[J].J Neurochem,2003,85:142-150.,2003. |
| [12] | McGarrigle E M,Gilheany D G.Chromium and Manganese-salen Promoted Epoxidation of Alkenes[J].Chem Rev,2005,105(5):1563-1602.,2005. |
| [13] | 冯辉霞,高晓红,陈娜丽,段玲玲,张娟,李汉峰.钴-席夫碱-壳聚糖/凹凸棒土对苯乙烯环氧化的催化性能[J].应用化学,2014(02):159-164. |
| [14] | Kumar S,Dhar D N,Saxena P N,Kanpur I I T.Applications of Metal Complexes of Schiff Bases-A Review[J].J Sci Ind Res,2009,68:181-187.,2009. |
| [15] | Prakash A,Adhikari D.Application of Schiff Bases and Their Metal Complexes-A Review[J].Int J Chem Tech Res,2011,3:1891-1896.,2011. |
| [16] | 谢复新,刘远芳,董华泽,马文.一个新希夫碱的合成、晶体结构及抑菌活性[J].中国药物化学杂志,2002(05):279-280. |
| [17] | Callaway W B,Veauthier J M,Sessler J L.Schiff-base Porphyrin and Expanded Porphyrin Analogs[J].J Porphyr Phthalocya,2004,8:1-25.,2004. |
| [18] | Wu Yahong,Chen Lin,Yu Jian,et al.Synthesis and Spectroscopic Characterization of meso-Tetra (Schiff-base substituted phenyl) porphyrins and Their Zinc Complexes[J].Dyes Pigm,2013,97:423-428.,2013. |
| [19] | 陈林,佟珊玲,吴雅红,余坚,阎雁.meso-四[（4-苯乙烯氨基）苯基]卟啉合成及其波谱特点[J].应用化学,2013(03):290-294. |
| [20] | 苏建玲,赵文军,张富昌,高利柱,高林.新型Salen-卟啉金属配合物催化剂的研究[J].应用化工,2007(04):390-393. |
| [21] | LUO Guotian,ZHENG Shengwei,XU Qingbing.Synthesis,Optical and Thermal Properties of Novel Schiff Base Complexes Containing Porphyin Copper(Ⅱ) and Zinc (Ⅱ)[J].Chem J Chinese Univ,2008,29(7):1307-1311 (in Chinese).罗国添,郑生伟,徐庆兵.新型卟啉-席夫碱铜(Ⅱ)/锌(Ⅱ)配合物的合成与光热性能[J].高等学校化学学报,2008,29(7):1307-1311.,2008. |
| [22] | 罗国添,郑生伟,徐庆兵.新型卟啉-席夫碱铜（Ⅱ）/锌（Ⅱ）配合物的合成与光热性能[J].高等学校化学学报,2008(07):1307-1311. |
| [23] | Imaoka T,Horiguchi H,Yamamoto K.Metal Assembly in Novel Dendrimers with Porphyrin Cores[J].J Am Chem Soc,2003,125:340-341.,2003. |
| [24] | Imaoka T,Tanaka R,Arimoto S,et al.Probing Stepwise Complexation in Phenylazomethine Dendrimers by a MetalloPorphyrin Core[J].J Am Chem Soc,2005,127:13896-13905.,2005. |
| [25] | 井淑波,王国甲.环己烷催化氧化研究进展[J].精细石油化工,2004(02):52-57. |
| [26] | ZHANG Yicheng,DAI Weili,WU Guangjun,et al.Cyclohexane Oxidation:Small Organic Molecules as Catalysts[J].Chinese J Catal,2014,35:279-285 (in Chinese).张义成,戴卫理,武光军,等.环己烷氧化反应:有机小分子的催化作用[J].催化学报,2014,35:279-285.,2014. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%