离子液体@TiO2纳米复合材料的制备及其光催化性能

应用化学, 2016, 33(4): 459-465. doi: 10.11944/j.issn.1000-0518.2016.04.150269

离子液体@TiO2纳米复合材料的制备及其光催化性能

于宗龙 ^1, , 贾春晓 ^2, , 路鑫 ^3, , 韩海港 ^4, , 辛炳炜 ^5,

1.德州学院,山东高校配位化学与功能材料重点实验室山东德州,253023

2.德州学院,山东高校配位化学与功能材料重点实验室山东德州,253023

3.德州学院,山东高校配位化学与功能材料重点实验室山东德州,253023

4.德州学院,山东高校配位化学与功能材料重点实验室山东德州,253023

5.德州学院,山东高校配位化学与功能材料重点实验室山东德州,253023

基金项目: the Natural Science Foundation of Shandong Province(ZR2015EM022) 国家大学生创新创业训练计划项目(201410448029) the Natural Science Foundation of Shandong Province Combination Research Projects(ZR2013EML003) 山东省自然科学基金(ZR2015EM022) 德州学院2013年度实验技术立项项目 Supported by the National Training Programs of Innovation and Entrepreneurship for Undergraduates(201410448029) 山东省自然科学基金高校、科研单位联合专项资助项目(ZR2013EML003) Research Projects of Solar Energy of Dezhou University(SYJS-B13003)

关键词：离子液体TiO2纳米复合材料 , 光催化剂 , 甲基橙

Synthesis of Ionic Liquid@TiO2 Nanocomposites and Their Photocatalytic Performance

Keywords： IL@TiO2 nanocomposites , photo-catalyst , methyl orange

利用-Si-O-共价键将离子液体嫁接在纳米TiO2表面,制备离子液体@TiO2纳米复合材料,并利用红外光谱、差热分析、元素分析等技术手段进行了分析.光催化性能研究表明,在紫外光照射60 min后,[C8 tespim] Br@TiO2([C8tespim]:N-3-(3-三乙氧基硅烷基丙基)4,5-二氢咪唑)复合材料能够将甲基橙100％脱色,明显优于TiO2 P25的光催化降解性能.同时发现其光催化性能与阴离子类型有密切关系,活性顺序为[C8tespim] Br@TiO2＜[C8tespim] PF6@TiO2＜[C8tespim] Tf2N@TiO2.

参考文献

[1]	Zhang XT;Jin M;Liu ZY;Nishimoto S;Saito H;Murakami T;Fujishima A.Preparation and photocatalytic wettability conversion of TiO2-based superhydrophobic surfaces[J].Langmuir: The ACS Journal of Surfaces and Colloids,200623(23):9477-9479.
[2]	Jutz, F.;Andanson, J.-M.;Baiker, A..Ionic liquids and dense carbon dioxide: A beneficial biphasic system for catalysis[J].Chemical Reviews,20112(2):322-353.
[3]	Bingwei Xin;Jingcheng Hao.Reversibly switchable wettability[J].Chemical Society Reviews,20102(2):769-782.
[4]	Qian Ye;Tingting Gao;Fei Wan.Grafting poly(ionic liquid) brushes for anti-bacterial and anti-biofouling applications[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201226(26):13123-13131.
[5]	常睿;李春喜;孟洪;陆颖舟.光催化法与生物法结合降解咪唑类离子液体[J].环境工程学报,2011(9):1950-1954.
[6]	Yongai Zhai;Yu Gao;Fengqi Liu.Synthesis of nanostructured TiO_2 particles in room temperature ionic liquid and its photocatalytic performance[J].Materials Letters,200728(28):5056-5058.
[7]	Yongai Zhai;Qing Zhang;Fengqi Liu;Ge Gao.Synthesis of nanostructure rutile TiO_2 in a carboxyl-containing ionic liquid[J].Materials Letters,200830(30):4563-4565.
[8]	Hideaki Itoh;Kensuke Naka;Yoshiki Chujo.Synthesis of Gold Nanoparticles Modified with Ionic Liquid Based on the Imidazolium Cation[J].Journal of the American Chemical Society,200410(10):3026-3027.
[9]	Tetsuo Nishida;Yasutaka Tashiro;Masashi Yamamoto.Physical and electrochemical properties of 1-alkyl-3-methylimidazolium tetrafluoroborate for electrolyte[J].Journal of Fluorine Chemistry,20032(2):135-141.
[10]	D. Neela Priya;Jayant M. Modak;Ashok M. Raichur.LbL Fabricated Poly(Styrene Sulfonate)/TiO2 Multilayer Thin Films for Environmental Applications[J].ACS applied materials & interfaces,200911(11):2684-2693.

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