以吸附等温线、动力学和热力学等方法研究了金属-有机骨架对苯二甲酸酯-铝[MIL-53(Al),MIL:Materials of Institut Lavoisier]对水中邻硝基苯酚、苯酚和邻苯二酚的吸附行为.MIL-53 (Al)对上述酚类化合物的吸附符合准二级吸附动力学模型,且包含表面吸附和孔内扩散两个过程.吸附热力学结果表明,MIL-53(Al)对酚类化合物的吸附是自发的,且为吸热和熵增加过程.在40℃条件下,MIL-53 (Al)对邻硝基苯酚、苯酚和邻苯二酚的吸附量分别为78.6、30.5和16.5 mg/g.
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