欢迎登录材料期刊网

材料期刊网

高级检索

铁矿石烧结是目前一个重要的二(口恶)英(PCDD/Fs)产生工业源,烧结过程二(口恶)英的生成机理复杂,主要由前驱体化合物经有机化合反应生成和碳、氢、氧和氯等元素通过“从头合成”生成,其中以“从头合成”为主,二(口恶)英在烧结机上不仅在干燥带中产生,而且在燃烧带和烧结带的排烟道中也产生.烧结过程二(口恶)英的减排主要方法分为源头控制、过程与操作控制以及末端治理3种,源头控制是烧结过程抑制二(口恶)英产生的最佳选择,现行工艺往往选择末端治理.烧结烟气成分复杂,单一的二(口恶)英减排技术减排幅度未必奏效,而且投资比较大.针对烧结工序的技术特点和烧结烟气的特征,烧结污染物协同减排是烧结工序节能减排的最佳途径,如烧结烟气循环不但可以减少二(口恶)英产生,还可以同时减少NOx和粉尘量的排放,这是今后烧结协同减排发展的一个方向.

参考文献

[1] Heidelore F .Thermal Formation of PCDD/PCDF:A Survey[J].Environmental Engineering Science,1998,15(1):49.,1998.
[2] Berg M,Birnbaum L,Denison M,et al .The 2005 World Health Organization Reevaluation of Human and Mammalian Toxic Equivalency Factors for Dioxins and Dioxin-Like Compounds[J].Toxicological Sciences,2006,93(2):223.,2006.
[3] LIU Guo-rui,ZHENG Ming-hui,CAI Zong-wei,et al .Dioxin Analysis in China[J].TrAC Trends in Analytical Chemistry,2013,46(6):178.,2013.
[4] Philip J A.Reducing the Emissions of Dioxins From Sinter Plants Work Shop Proceedings[M].Bilbao:Steel Research and Development on Environmental Issues,1999.,1999.
[5] Cieplik M K,Carbonell J P,Munoz C,et al .On Dioxin Formation in Iron Ore Sintering[J].Environ Sci Technol,2003,37(15):3323.,2003.
[6] 环境保护部,国家质量监督检验检疫总局.GB 28662-2012[S].北京:中国环境科学出版社,2012.,2012.
[7] TIAN Bo,HUANG Jun,WANG Bin,et al .Emission Characterization of Unintentionally Produced Persistent Organic Pollutants From Iron Ore Sintering Process in China[J].Chemosphere,2012,89(4):409.,2012.
[8] 吴永宁,王绪卿,二唔英及其类似物环境与食品污染[J].,1999,11(5):30.,1999.
[9] Stanmore B R .The Formation of Dioxins in Combustion Systems[J].Combustion and Flame,2004,136(3):398.,2004.
[10] Weber R,Hagenmaier H .Mechanism of Formation of Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans From Chlomphenols in Gas Phase Reactions[J].Chemosphere,1999,38(3):529.,1999.
[11] P Born J G,Mulder P,Louw R .Fly Ash Mediated Reactions of Phenol and Monochlorophenols:Oxychlorination,Deep Oxidation,and Condensation[J].Environmental Science & Technology,2010,27(9):1849.,2010.
[12] Addink R, Olie K .Mechanisms of Formation and Destruction of Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans in Heterogeneous Systems[J].Environmental Science & Technology,2010,29(6):1425.,2010.
[13] Stieglitz L,Zwick G,Beck J,et al .Carbonaceous Particles in Fly Ash a Source for the De-Novo-Synthesis of Organochlorocompounds[J].Chemosphere,1989,19(1):283.,1989.
[14] Stieglitz L,Eichberger M,Schleihauf J,et al .The Oxidative Degradation of Carbon and Its Role in the De Novo Synthesis of Organohalogen Compounds in Fly Ash[J].Chemosphere,1993,27(1):343.,1993.
[15] Huang H,Buekens A .On the Mechanisms of Dioxin Formation in Combustion Processes[J].Chemosphere,1995,31(9):4099.,1995.
[16] Huang H,Biesemans M,Buekens A .Characterization of the Nature of De Novo Synthesis by 13C NMR[J].Organohalogen Compounds,1999,41(1):105.,1999.
[17] Kuzuhata S,Sato H,Kasai E,et al .Influence of Metallic Chlorides on the Formation of PCDD/Fs During Low-Temperature Oxidation of Carbon[J].Environmental Science & Technology,2003,37(11):2431.,2003.
[18] Xhrouet C,Pirard C,Pauw F D .De Novo Synthesis of Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans on Fly Ash From a Sintering Process[J].Environmental Science & Technology,2009,35(8):1616.,2009.
[19] Fisher R,Fray T,Anderson D R.Investigation of the Formation of Dioxins in the Sintering Process[C]//Ironmaking Conference Proceeding,2011:1183.,2011.
[20] David R,Anderson,Raymond F.Sources of Dioxins in the United Kingdom:the Steel Industry and Other Sources[J].Chemosphere,2002(46):371.,2002.
[21] 杨红博,李咸伟,俞勇梅,何晓蕾.热风烧结对二噁英生成的影响研究[J].烧结球团,2011(01):47-51.
[22] Kuo Yu-Chieh,Chen Yu-Cheng,Yang Chi-Wei,et al .Identification the Content of the Windbox Dust Related to the Formation of PCDD/Fs During the Iron Ore Sintering Process[J].Aerosol and Air Quality Research,2011,11(4):351.,2011.
[23] Tan P,Neuschutz D .Study on Polychlorinated Dibenzo-p-Dioxin/Furan Formation in Iron Ore Sintering Process[J].Metallurgical and Materials Transactions:B,2004,35(5):983.,2004.
[24] Altarawneh M,Dlugogorski B Z,Kennedy E M,et al .Mechanisms for Formation,Chlorination,Dechlorination and Destruction of Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans (PCDD/Fs)[J].Progress in Energy and Combustion Science,2009,35(3):245.,2009.
[25] Kasma S,Yamamura Y,Watanabe K .Investigation on the Dioxin Emission From a Commercial Sintering Plant[J].ISIJ International,2006,46(7):1014.,2006.
[26] 原丽军,李遇春.烧结烟气与垃圾焚烧二恶英的控制技术对比[J].中国冶金,2012(02):31-35.
[27] 吴铿,窦力威,刘万山,王欣.钢铁工业中的二恶英和预防措施[J].钢铁,2000(08):62-66,74.
[28] Xhrouet C,Pauw E D .Formation of PCDD/Fs in the Sintering Process:Influence of Raw Materials[J].Environ Sci Technol,2004,38(15):4222.,2004.
[29] Masanori N,Kazuyuki M,Takehiko S .Factors Accelerating Dioxin Emission From Iron Ore Sintering Machines[J].ISIJ International,2009,49(5):729.,2009.
[30] Fisher R,Fray A T T,Anderson D R.Investigation of the Formation of Dioxins in the Sintering Process[C]//ICSTI/Ironmaking Conference Proceedings,1998:1183.,1998.
[31] Kim K,Koh D J,Kim B,et al .Dioxin Emissions in the Sintering Process[J].Organohalogen Compounds,2001,50(1):328.,2001.
[32] Kasai E,Aono T,Tomita Y,et al .Macroscopic Behaviours of Dioxins in the Iron Ore Sintering Plants[J].ISIJ Int,2001,41(1):86.,2001.
[33] Xhrouet C,Pauw E D .Formation of PCDD/Fs in the Sintering Process:Influence of Raw Materials[J].Environ Sci Technol,2004,38(15):4222.,2004.
[34] Ooi T C,Thompson D,Anderson D R,et al .The Effectof Charcoal Combustion on Iron-Ore Sintering Performance and Emission of Persistent Organic Pollutants[J].Combust Flame,2011,158(5):979.,2011.
[35] Ooi T C,Aries E,Thompson D,et al .The Study of Sunflower Seed Husks as a Fuel in the Iron Ore Sintering Process[J].Miner Eng,2008,21(2):167.,2008.
[36] Kawaguchi T,Matsumura M .Method of Sinter Pot Test Evaluation Fordioxins Formation on Iron Ore Sintering[J].Tetsu to Hagane,2002,88(1):16.,2002.
[37] 龙红明,李家新,王平,高岗,张健.尿素对减少铁矿烧结过程二恶英排放的作用机理[J].过程工程学报,2010(05):944-949.
[38] LONG Hong-ming,LI Jia-xin,WANG Ping.Influence of dioxin reduction on chemical composition of sintering exhaust gas with adding urea[J].中南大学学报(英文版),2012(05):1359-1363.
[39] 戴帆,谈琰,李咸伟,俞勇梅,何晓蕾,陈德珍.两种抑制剂对铁矿石烧结过程二(口恶)(口英)减排研究[J].中国环境科学,2012(05):822-828.
[40] Tupperainen K,Halonen I,Ruokojarvi P,et al .Formation of PCDDs and PCDFs in Municipal Waste Incineration and Itsinhibition Mechanism:A Review[J].Chemosphere,1998,36(7):1493.,1998.
[41] LIU Wen-bin,ZHENG Ming-hui,ZHANG Bing,et al .Inhibition of PCDD/Fs Formation From Dioxin Precursprs by Calcium Oxide[J].Chemosphere,2005,60(6):785.,2005.
[42] Chen Y C,Tsa i P J,Mou J L,et al .A Pilot Study for Determining the Optimal Operation Condition for Simultaneously Controlling the Emissions of PCDD/Fs and PAHs From the Iron Ore Sintering Process[J].Chemosphere,2012,88(11):1324.,2012.
[43] Yongmei Yu,Minghui Zheng,Xianwei Li,Xiaolei He.Operating condition influences on PCDD/Fs emissions from sinter pot tests with hot flue gas recycling[J].环境科学学报(英文版),2012(05):875-881.
[44] 张春霞,王海风,齐渊洪.烧结烟气污染物脱除的进展[J].钢铁,2010(12):1-11.
[45] Hofstadler K,Gebert W,Lanzerstorfer Ch,等 .去除烧结和电炉废气中的二英的方案[J].钢铁,2001,36(10):69.,2001.
[46] 王玮,肖成龙,姜思朋,李大涛,胡道庆.火化过程中二噁英类污染物减排技术研究[J].环境污染与防治,2006(10):786-787,795.
[47] 林立恒.用活性褐煤HOK去除烧结及电炉炼钢PCDD/F及重金属[N].世界金属导报,2012-12-4(B10).,2012.
[48] Hung P C,Lo W C,Chi K H,et al .Reduction of Dioxin Emission by a Multi-Layer Reactor With Bead-Shaped Activated Carbon in Simulated Gas Stream and Real Flue Gas of a Sinter Plant[J].Chemosphere,2011,82(1):72.,2011.
[49] 孟庆立,李昭祥,杨其伟,宋由仁.台湾中钢SCR触媒在烧结场脱硝与脱二噁英中的应用[J].武汉大学学报:工学版,2012(06):751-756.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%