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详细分析了热轧奥氏体不锈钢带钢的表面氧化皮形成机理、退火对氧化皮特性的影响机理、酸洗工艺机理。结论是:热轧奥氏体不锈钢带钢表面氧化皮外层主要以铁氧化物为主,内层主要以交替分布的Cr2O3和FeCr2O4层为主;退火后,氧化皮结构变得疏松多孔,且易脱落,贫铬层厚度增加,带钢更加容易酸洗;酸洗时,带钢表面的氧化皮主要通过机械剥离作用去除。分析结果对热轧奥氏体不锈钢带钢酸洗技术的改进具有一定的理论指导意义。

The formation mechanism of surface oxide scale, the mechanism of the effect of annealing on surface oxide scale, and the pickling process mechanism of hot-rolled austenitic stainless steel strip were analyzed in details, respective-ly. The results shows that the outer layer of oxide scale is mainly composed of iron oxide and the inner layer is alternative-ly distributed Cr2O3 and FeCr2O4. After annealing, the oxide scale becomes loose and porous and is easy to fall off. Mean-while, the chromium depleted layer becomes thicker. All these make the pickling of strip much more easily. In addition, the surface oxide scale is primarily removed by mechanical stripping during pickling. The analysis of the results has cer-tain theoretical significance for the improvement of hot-rolled austenitic stainless steel strip pickling technology.

参考文献

[1] Takamasa Yamamura;Seiji Mori;Koichi Asada .Process for Pro-duction of Coil of Hot Rolled Strip of Austenitic Stainless Steel[P].United States,US4360391,2014-03-31.
[2] 侯欣荣.酒钢不锈钢厂热轧层流冷却控制系统研究与应用[J].山西冶金,2008(06):23-25,49.
[3] 彭建国,骆素珍,袁敏.304奥氏体不锈钢高温氧化行为研究[J].宝钢技术,2007(04):29-32.
[4] 乔秉诚.热轧带钢氧化铁皮控制技术的发展[J].河北冶金,2012(12):40-42,12.
[5] 袁敏 .304不锈钢热轧生产工艺特性的研究[D].东北大学,2009.
[6] Habib K A;Damra M S;Saura J J.Breakdown and Evolu-tion of the Protective Oxide Scales of AISI304 and AISI316 Stainless Steels Under High-Temperature Oxidation[J].Interna-tional Journal of Corrosion,2011:5.
[7] Asteman H;Svensson J E;Johansson L G et al.Indication of Chromium Oxide Hydroxide Evaporation During Oxidation of 304L at 873 K in the Presence of 10% Water Vapor[J].Oxida-tion of Metals,1999,52(1-2):95.
[8] Yamauchi A;Kurokawa K;Takah Ashi H .Evaporation of Cr2O3 in Atmospheres Containing H2O[J].Oxidation of Metals,2003,59(5-6):517.
[9] 陈伟刚,陈永清,潘红良.304不锈钢Na2SO4电解酸洗工艺的研究[J].中国冶金,2009(01):16-19,23.
[10] Liu F;Tang J E;Asteman H et al.Investigation of the Evolution of the Oxide Scale Formed on 310 Stainless Steel Oxidized at 600℃in Oxygen With 40%Water Vapour Using FIB and TEM[J].Oxidation of Metals,2009,71(1-2):77.
[11] Karimi N;Riffard F;Rabaste F et al.Characterization of the Ox-ides Formed at 1 000℃on the AISI 304 Stainless Steel by X-ray Diffraction and Infrared Spectrosco-py[J].Applied Surface Science,2008,254(08):2297.
[12] 尚竹亚 .几种不锈钢材料高温氧化行为研究[D].太原:太原理工大学,2012.
[13] 苏婷婷 .多道次热轧过程中奥氏体不锈钢的氧化铁皮演变机制及影响因素[D].兰州:兰州理工大学,2012.
[14] 福田国父;宇城工;佐藤进.退火条件对SUS304冷轧板氧化铁皮结构和除鳞性的影响[J].浙江冶金,1999(04):24.
[15] S.J. COBO;E.J. PALMIERE;W.M. RAINFORTH .Mechanism of Oxidation of Austenitic Stainless Steels under Conditions of Hot Rolling in Steckel Mills[J].Metallurgical and materials transactions. A, physical metallurgy and materials science,2008(10):2477-2485.
[16] 刘振宇;于洋;郭晓波 .板带热连轧氧化铁皮的控制技术[J].轧钢,2009,26(01):6.
[17] G.Hubmer,A.Osterkom,K.Rendl,R.Puntigam,R.Sestak,W.R.Thiele.带钢酸洗终点的准确判定[J].钢铁,2003(09):39-42.
[18] 李登超.不锈钢板带材生产技术[M].北京:化学工业出版社,2008
[19] 崔卫中.热轧带钢表面氧化铁皮成因及去除方法[J].山西冶金,2010(03):25-26,35.
[20] 任建斌 .254SMO相析出规律及其性能的研究[D].云南大学,2012.
[21] 周永昌 .T122钢的氧化行为研究[D].东北大学,2010.
[22] 崔忠圻.金属学与热处理[M].北京:机械工业出版社,2000
[23] Lindell D;Pettersson R .Pickling of Process-Oxidised Austentic Stainless Steel in HNO3-HF Mixed Acid[J].Materials Technolo-gy,2010,81(07):547.
[24] 李旭初.不同抛丸介质在不锈钢热轧板除鳞工艺中的应用比较[J].山西冶金,2012(02):13-16,26.
[25] 单芳.不锈带钢酸洗工艺及其质量控制[J].太钢科技,2005(02):40.
[26] 臧震,胡俊辉.304不锈钢盘条酸洗技术的试验研究[J].山西冶金,2010(06):11-15.
[27] 朱立.钢材酸洗技术[M].北京:化学工业出版社,2007
[28] 刘福生;扈国军;王晟 .无酸雾污染的硫酸酸洗技术[J].化工时刊,1996,10(11):21.
[29] 廖建军.不锈钢线材表面处理技术及应用[J].金属制品,2008(05):9-14.
[30] 李正仁;朱文生.不锈钢管酸洗工艺的研究与应用[J].特殊钢,1985(05):49.
[31] 王海林.冷轧不锈钢带钢酸洗的工艺与废气、废酸处理[J].中国冶金,2009(06):40-43.
[32] 李丽娟.不锈钢混酸酸洗工艺浅析[J].钢铁技术,2005(05):46-48.
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