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使用ASPEX PSEM explorer研究了帘线钢中氧化物夹杂的成分及形态在炼钢与轧制过程的变化。结果表明,连铸坯夹杂物中SiO2质量分数较中间包有增加趋势,并在铸坯中发现MnO-SiO2-Al2O3和SiO2构成的复合夹杂物,轧制盘条中出现未很好变形的SiO2夹杂物。热力学分析表明:由于连铸过程钢液和夹杂物间的传质作用,导致铸坯夹杂物中SiO2质量分数增加,MnO-SiO2-Al2O3系夹杂在浇铸过程较CaO-SiO2-MnO-Al2O3系夹杂物更易析出SiO2相,形成MnO-SiO2-Al2O3为基体的复合夹杂物。CaO-SiO2-Al2O3-MnO和MnO-SiO2-Al2O3夹杂物在盘条中呈长条状,MnO-SiO2-Al2O3和SiO2析出相构成的复合夹杂在轧制过程将发生相分离,形成“眼睛状”或单颗粒状夹杂。

Changes in composition and morphology of inclusions during steelmaking and rolling process of tire cord were studied by ASPEX PSEM explorer. The results showed the content of SiO2 in inclusions in as-cast bloom increased a little compared to that in the tundish and dual-phase structure of pure SiO2 in MnO-SiO2-Al2O3 matrix were also ob-served in as-cast bloom. Inadequate deformation SiO2-type inclusions were observed in rolling products. Thermodynam-ic analysis showed that mass transfer between liquid steel and inclusions resulted in the rise of SiO2 content in inclusions from tundish to as-cast bloom and accelerated the precipitation of pure SiO2 phase in the formed inclusions. SiO2 solid phase was highly likely to precipitate out from MnO-SiO2-Al2O3 inclusions to form dual phase inclusions,compared to precipitate from CaO-SiO2-MnO-Al2O3 inclusions. During hot rolling,the homogeneous CaO-SiO2-Al2O3-MnO and MnO-SiO2-Al2O3 can easily be elongated and presented long strip shape in rolled products. Phase separation in the dual phase inclusion of MnO-SiO2-Al2O3 and SiO2 may occur for its inhomogeneous composition during rolling accounting for the distribution of non-deformable SiO2 inclusions in the wire rods and some eye-shaped and single-particle inclusions were generated.

参考文献

[1] G. M. Faulring.Inclusion modification in semi-killed steels[J].Iron & Steelmaker,19997(7):29-36.
[2] Youn-Bae KANG;Hae-Geon LEE.Inclusions chemistry for Mn/Si deoxidized steels: Thermodynamic predictions and experimental confirmations[J].ISIJ International,20046(6):1006-1015.
[3] 王立峰;卓晓军;张炯明;王新华.冶金过程中帘线钢夹杂物成分控制[J].北京科技大学学报,2003(4):308-311.
[4] 王立峰;张炯明;王新华;王万军.低碱度顶渣控制帘线钢中CaO-SiO2-Al2O3-MgO类夹杂物成分的实验研究[J].北京科技大学学报,2004(1):26-29.
[5] Shu-hao Chen;Min Jiang;Xiao-fei He;Xin-hua Wang.Top slag refining for inclusion composition transform control in tire cord steel[J].矿物冶金与材料学报,2012(06):490-498.
[6] 王昆鹏;姜敏;赵昊乾;王新华;王郢.切割丝用盘条非金属夹杂物对比分析[J].钢铁,2016(1):33-38.
[7] Shin-ya KITAMURA.Preface to the Special Issue on "Fundamentals and Applications of ion-metallic Inclusions in Solid Steel"[J].ISIJ International,201112(12):1943-1943.
[8] Hiroyuki SHIBATA;Koichiro KIMURA;Tomoko TANAKA.Mechanism of Change in Chemical Composition of Oxide Inclusions in Fe-Cr Alloys Deoxidized with Mn and Si by Heat Treatment at 1 473 K[J].ISIJ International,201112(12):1944-1950.
[9] H. Shibata;T. Tanaka;K. Kimura.Composition change in oxide inclusions of stainless steel by heat treatment[J].Ironmaking & Steelmaking: Products and applications,20107(7):522-528.
[10] Kim, Kyung-Ho;Kim, Sun-Joong;Shibata, Hiroyuki;Kitamura, Shin-ya.Reaction between MnO-SiO2-FeO Oxide and Fe-Mn-Si Solid Alloy during Heat Treatment[J].ISIJ International,201410(10):2144-2153.
[11] Xinhua Wang;Xiugang Li;Qiang Li.Control of Stringer Shaped Non-Metallic Inclusions of CaO-Al_2O_3 System in API X80 Linepipe Steel Plates[J].Steel Research International,20142(2):155-163.
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