采用氧氮分析仪、扫描电镜、金相显微镜等分析手段,系统研究 LF精炼渣系对304系不锈钢全氧质量分数wT[O]、夹杂物数量、尺寸及成分的影响.研究结果表明,当 LF精炼渣碱度由1.5升高至2.6时,LF出站溶解氧质量分数w[O]由11.6×10-6降低至4.8×10-6,铸坯wT[O]由47×10-6降低至24×10-6,铸坯夹杂物总数量降低,但当量直径不大于10μm的夹杂物所占比率由77.7%增加至95.1%.热力学计算结果表明:在钢液中各元素达到平衡状态时,渣系碱度越高,低熔点夹杂物2MgO?2Al2 O3?5SiO2生成区域越小,MgO?Al2 O3尖晶石类夹杂物生成区域越大,与生产试验结果一致.随着 LF炉渣碱度升高,铸坯夹杂物成分中 MgO 和 Al2 O3的质量分数分别升高了14.4%和9.1%,当碱度不大于1.9时,铸坯中不会存在镁铝尖晶石.
The effect of LF refining slag on number,size,composition of inclusions and T[O]content in 304 stain-less steel were analyzed by oxygen-nitrogen analyzer,scanning electronic microscopy and metallographic microsco-py.The results indicate that mass fraction of dissolved oxygen in 304 stainless steel at LF tapping moment decrea-ses from 11.6×10-6 to 4.8×10-6 with slag basicity in LF refining process increasing from 1.5 to 2.6,and mass fraction of T[O]in 304 stainless steel continuous casting slab decreases from 47×10-6 to 24×10-6 .The number of inclusions in slab decreases,but the proportion of inclusions which diameter less than 10μm increases from 77.7% to 95.1%.The thermodynamical calculation results show that under the condition of equilibrium state, with increasing slag basicity in LF refining process,the formation areas of 2MgO?2Al2 O3?5SiO2 inclusions be-come smaller and the formation areas of MgO?Al2 O3 become bigger,which have the same tendency with produc-tion test.The MgO and Al2 O3 content of inclusions in slab increase 14.4% and 9.1% respectively with slag basic-ity in LF refining process increasing.There are no MgO?Al2 O3 spinel inclusions in continuous casting slab when slag basicity in LF refining process is less than 1.9.
参考文献
[1] | 徐匡迪;肖丽俊.关于不锈钢精炼的过程模型与质量控制[J].钢铁,2011(1):1-13. |
[2] | Joo Hyun PARK;Hidekazu TODOROKI.Control of MgO·Al_2O_3 Spinel Inclusions in Stainless Steels[J].ISIJ International,201010(10):1333-1346. |
[3] | 任英;张立峰;杨文.不锈钢中夹杂物控制综述[J].炼钢,2014(1):71-78. |
[4] | 茅卫东.SUS304不锈钢表面抛光缺陷原因分析及改进措施[J].上海金属,2011(02):58-62. |
[5] | Woo-Yeol CHA;Dong-Sik KIM;Yong-Deuk LEE.A Thermodynamic Study on the Inclusion Formation In Ferritic Stainless Steel Melt[J].ISIJ International,20047(7):1134-1139. |
[6] | H. MATSUNO;Y. KIKUCHI.Shape control of inclusions in high nickel content steel[J].ISIJ International,199511(11):1368-1373. |
[7] | JOO HYUN PARK;YOUN-BAE KANG.Effect of Ferrosilicon Addition on the Composition of Inclusions in 16Cr-14Ni-Si Stainless Steel Melts[J].Metallurgical and Materials Transactions, B. Process metallurgy and materials processing science,20065(5):791-797. |
[8] | YoungJo Kang;Fan Li;Kazuki Morita.Mechanism Study on the Formation of Liquid Calcium Aluminate Inclusion from MgO centre dot Al_2O_3 Spinel[J].Steel Research International,200611(11):785-792. |
[9] | Hideaki SUITO;Ryo INOUE.Thermodynamics on Control of Inclusions Composition in Ultraclean Steels[J].ISIJ International,19965(5):528-536. |
[10] | Kanae uzuki;Shiro Ban-Ya;Mitsutaka Hino.Deoxidation Equilibrium of Chromium Stainless Steel with Si at the Temperatures from 1 823 to 1 923 K[J].ISIJ International,20018(8):813-817. |
[11] | Kanae SUZUKI;Shiro BAN-YA;Mitsutaka HINO.Deoxidation Equilibrium of Cr-Ni Stainless Steel with Si at the Temperatures from 1823 to 1923 K[J].ISIJ International,20022(2):146-149. |
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