保护渣中 Al2 O3质量分数变化是渣钢交互作用的结果,包括吸附钢液中 Al2 O3夹杂和渣金反应产物。氧化铝对保护渣成分与性能稳定性影响突出,进而影响铸坯质量。分析指出,影响保护渣吸附 Al2 O3夹杂的因素包括接触角、润湿速率和界面张力、熔渣成分和性能等。熔渣与夹杂物的交互作用行为决定了其对上浮夹杂的去除率。高铝钢连铸过程渣金反应尤为突出,保护渣的工作性能将发生明显改变。基于近年关于 Al2 O3夹杂的吸附溶解试验研究,以及高铝钢浇铸渣金反应及其保护渣性能变化的研究结果,探讨了通过合理设计保护渣成分或更换渣系等措施来实现该类钢种保护渣工作性能的相对稳定性。
The change in alumina content in mould flux is the result of slag-metal interactions,including adsorbing a-lumina inclusions in steel and slag-metal reaction product.Alumina content has a dramatical influence on the compo-sitions and performance stability of mould flux,and further affects the strand quality.The factors that impact on the adsorption of alumina are contact angle,wetting rate,interfacial tension,composition and performance of mould flux.The removal rate of floating alumina inclusions is determined by the interaction of mould flux and inclusions. The slag-metal reaction is more intensive in the casting process of high aluminium steel,which leads to the the chan-ges in performance of mould flux.To achieve the relative stability of mould flux performance,some measures such as rational design of mould flux compositions or selecting anther mould flux system are discussed ,based on the ex-periment researches on absorption and dissolution of alumina inclusion in recent years and the research results of slag-metal reaction and variations of mould flux performance in the casting process of high aluminium steel.
参考文献
[1] | Mills K C,Fox A B,Li Z,et al .Performance and properties of mould fluxes[J].Ironmaking and Steelmaking,2005,32(1):26.,2005. |
[2] | 林晏民,欧阳民,廖美华,姚铁梅.保护渣高温特性对板坯表面裂纹影响的研究[J].中国冶金,2011(08):26-29. |
[3] | WANG Q,QIU S,ZHAO P .Kinetic analysis of alumina change in mold slag for high aluminum steel during continu-ous casting[J].Metallurgical and Materials Transactions:B,2012,43(2):424.,2012. |
[4] | 闫威,陈伟庆,Carsten Lippold,郑宏光.无磁钢20Mn23AlV保护渣液渣和渣圈性能变化对连铸的影响[J].特殊钢,2013(01):45-48. |
[5] | Mukongo T,Pistorius P C,Garbers-Craig A M .Viscosity effect of titanium pickup by mould fluxes for stainless steel[J].Ironmaking and Steelmaking,2004,31(2):135.,2004. |
[6] | 王强,仇圣桃,赵沛,刘志宏,朱果灵,胡坤太.高铝钢连铸保护渣的研究现状[J].炼钢,2012(01):74-78. |
[7] | 铁生年,张芬娟,陈列,李昀珺,李星.连铸保护渣性能研究进展[J].中国冶金,2008(12):1-5. |
[8] | Park J H,Todoroki H .Control of MgO· Al2 O3 spinel in-clusions in stainless steels[J].ISIJ International,2010,50(10):1333.,2010. |
[9] | Fox A B,Valdez M E,Gisby J,et al .Dissolution of ZrO2, Al2 O3,MgO and MgAl2 O4 particles in a B2 O3 containing commercial fluoride-free mould slag[J].ISIJ International,2004,44(5):836.,2004. |
[10] | ZHANG L.Thomas B G.Inclusions in continuous casting of steel[C]//XXIV National Steelmaking Symposium,Morelia, Mich,Mexico:[s.n.],2003:138.,2003. |
[11] | Valdez M,Shannon G S,Sridhar S .The ability of slags to absorb solid oxide inclusions[J].ISIJ International,2006,46(3):450.,2006. |
[12] | Sridhar S,Cramb A W.Kinetics of Al2 O3 dissolution in CaO-MgO-SiO2-Al2 O3 slags:in situ observations and analysis [J]. Metallurgical and Materials Transactions:B,2000(31):406.,2000. |
[13] | Nakashima K,Mori K .Interfacial properties of liquid iron al-loys and liquid slags relating to iron-and steel-making proces-ses[J].ISIJ International,1992,32(1):11.,1992. |
[14] | Pitak N V,P'yanykh N L .Wetting of refractories by molten steel and slag[J].Refractories and Industrial Ceramics,1965,6(5):243.,1965. |
[15] | Choi J Y,Lee H G .Wetting of solid Al2 O3 with molten CaO-Al2 O3-SiO2[J].ISIJ International,2003,43(9):1348.,2003. |
[16] | Yu X,Pomfret R J,Coley K S .Dissolution of alumina in mold fluxes[J].Metallurgical and Materials Transactions:B,1997,28(2):275.,1997. |
[17] | Park J H,Jung I H,Lee H G .Dissolution behavior of Al2 O3 and MgO inclusions in the CaO-Al2 O3-SiO2 slags:Formation of ring-like structure of MgAl2 O4 and Ca2 SiO4 around MgO inclusions[J].ISIJ international,2006,46(11):1626.,2006. |
[18] | Valdez M,Prapakorn K,Cramb A W,et al .Dissolution of alumina particles in CaO-Al2 O3-SiO2-MgO slags[J].Iron-making and Steelmaking,2002,29(1):47.,2002. |
[19] | Choi J Y,Lee H G,Kim J S.Dissolution rate of Al2 O3 into molten CaO-SiO2-Al2 O3 slags[J].ISIJ International,2002, 42(8):852.,2002. |
[20] | Bui A H,Ha H M,Chung I S,et al .Dissolution kinetics of alumina into mold fluxes for continuous steel casting[J].ISIJ International,2005,45(12):1856.,2005. |
[21] | Taira S,Nakashima K,Mori K .Kinetic behavior of dissolu-tion of sintered alumina into CaO-SiO2-Al2 O3 slags[J].ISIJ International,1993,33(1):116.,1993. |
[22] | 刘承军,王云盛,朱英雄,姜茂发.连铸保护渣的夹杂物吸收速率[J].钢铁研究学报,2000(Z1):46-50. |
[23] | 王强,仇圣桃,赵沛,朱果灵,徐李军.连铸保护渣吸收Al_2O_3的计算[J].钢铁研究学报,2011(09):5-7. |
[24] | Wang W,Blazek K,Cramb A .A study of the crystallization behavior of a new mold flux used in the casting of transforma-tion-induced-plasticity steels[J].Metallurgical and Materials Transactions:B,2008,39(1):66.,2008. |
[25] | Kim D J,Park J H .Interfacial reaction between CaO-SiO2-MgO-Al2 O3 flux and Fe-xMn-yAl (x=10 and 20 mass pct, y=1,3,and 6 mass pct)steel at 1 873 K (1 600°C)[J].Metallurgical and Materials Transactions:B,2012,43(4):875.,2012. |
[26] | Rhamdhani M A,Coley K S,Brooks G A .Analysis of the source of dynamic interfacial phenomena during reaction be-tween metal droplets and slag[J].Metallurgical and Materi-als Transactions:B,2005,36(5):591.,2005. |
[27] | 周鉴,王强,仇圣桃,干勇.高铝钢连铸保护渣结晶矿相的研究[J].钢铁研究学报,2013(04):15-19,24. |
[28] | 何生平,王谦,曾建华,张敏,谢兵.高铝钢连铸保护渣性能的控制[J].钢铁研究学报,2009(12):59-62. |
[29] | 王强.Al2 O3-BaO-B2 O3 系新型高铝钢连铸保护渣的应用基础研究[D].北京:钢铁研究总院,2012.,2012. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%