欢迎登录材料期刊网

材料期刊网

高级检索

以杨木粉、玉米淀粉和聚乳酸(PLA)为原料,甘油为相容剂,利用熔融挤出法制备了木粉-淀粉/PLA复合材料.研究了木粉含量对复合材料界面相容性、热性能、力学性能、流变性能以及吸水率的影响.结果表明:随着木粉含量的增加,PLA与木粉之间的界面相容性下降,木粉-淀粉/PLA复合材料的热稳定性下降,储能模量、损耗模量和复数黏度逐渐增加;随着木粉含量的增加,木粉-淀粉/PLA复合材料的拉伸强度和弯曲强度呈现先增大后减小的趋势,当木粉含量为18wt%时,复合材料的拉伸强度和弯曲强度均达到最大值,最大值分别为40.65 MPa和60.91 MPa;随木粉含量的增加,复合材料的断裂伸长率由9.64%减小到5.97%,而吸水率由5.38%增大到13.43%.

参考文献

[1] Kozlowski M;Masirek R;Piorkowska E;Gazicki-Lipman M.Biodegradable blends of poly(L-lactide) and starch[J].Journal of Applied Polymer Science,20071(1):269-277.
[2] Jian-Feng Zhang;Xiuzhi Sun.Mechanical Properties of Poly(lactic acid)/Starch Composites Compatibilized by Maleic Anhydride[J].Biomacromolecules,20044(4):1446-1451.
[3] O.Martin;L.Averous.Poly(lactic acid): plasticization and properties of biodegradable multiphase systems[J].Polymer: The International Journal for the Science and Technology of Polymers,200114(14):6209-6219.
[4] Li Chen;Xueyu Qiu;Mingxiao Deng;Zhongkui Hong;Rui Luo;Xuesi Chen;Xiabin Jing.The starch grafted poly(L-lactide)and the physical properties of its blending composites[J].Polymer: The International Journal for the Science and Technology of Polymers,200515(15):5723-5729.
[5] Michel A.Huneault;Hongbo Li.Morphology and properties of compatibilized polylactide/thermoplastic starch blends[J].Polymer: The International Journal for the Science and Technology of Polymers,200726(26):270-280.
[6] Li Chen;Xueyu Qiu;Zhigang Xie.Poly(L-lactide)/starch blends compatibilized with poly(L-lactide)-g-starch copolymer[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,20061(1):75-80.
[7] Ning Wang;Jiugao Yu;Peter R.Chang.Influence of formamide and water on the properties of thermoplastic starch/poly(lactic acid) blends[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,20081(1):109-118.
[8] Chanakorn Yokesahachart;Rangrong Yoksan.Effect of amphiphilic molecules on characteristics and tensile properties of thermoplastic starch and its blends with poly(lactic acid)[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,20111(1):22-31.
[9] Yanling Wang, Rongrong Qi;Cheng Xiong;Mark Huang.Effects of Coupling Agent and Interfacial Modifiers on Mechanical Properties of Poly(lactic acid) and Wood Flour Biocomposites[J].Iranian polymer journal,20114(4):281-294.
[10] Takatani Masahiro;Ikeda Kohei;Sakamoto Kei;Okamoto Tadashi.Cellulose esters as compatibilizers in wood/poly(lactic acid) composite[J].Journal of wood science,20081(1):54-61.
[11] Pilla S;Gong S;O'Neill E;Rowell RM;Krzysik AM.Polylactide-pine wood flour composites[J].Polymer engineering and science,20083(3):578-587.
[12] Ru Liu;Shupin Luo;Jinzhen Cao.Characterization of organo-montmorillonite (OMMT) modified wood flour and properties of its composites with poly(lactic acid)[J].Composites, Part A. Applied science and manufacturing,2013:33-42.
[13] A.A.S.Curvelo;A.J.F.de Carvalho;J.A.M.Agnelli.Thermoplastic starch-cellulosic fibers composites: preliminary results[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,20012(2):183-188.
[14] Cassagnau P.;Melis F..Non-linear viscoelastic behaviour and modulus recovery in silica filled polymers[J].Polymer: The International Journal for the Science and Technology of Polymers,200321(21):6607-6615.
[15] Kapnistos M.;Vlassopoulos D.;Anastasiadis SH.;Stammer A. Wolf BA.;Hinrichs A..RHEOLOGY OF A LOWER CRITICAL SOLUTION TEMPERATURE BINARY POLYMER BLEND IN THE HOMOGENEOUS, PHASE-SEPARATED, AND TRANSITIONAL REGIMES[J].Macromolecules,199622(22):7155-7163.
[16] Livia Danyadi;Janos Moczo;Bela Pukanszky.Effect of various surface modifications of wood flour on the properties of PP/wooc composites[J].Composites, Part A. Applied science and manufacturing,20102(2):199-206.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%