为提高玻纤增强环氧树脂复合材料的力学性能,采用静电植绒法将多壁碳纳米管(MWCNTs)附着在玻纤织物表面,得到改性的玻纤织物.利用一种低黏度的环氧树脂和所制得的改性织物,采用真空辅助成型工艺(VARI)制备了MWCNTs改性格玻纤织物/环氧树脂复合材料层合板,表征了层合板的力学性能.对进行力学实验后的MWCNTs改性玻纤织物/环氧树脂复合材料试样断口进行了SEM和OPM观察.结果显示:与未添加MWCNTs的玻纤织物/环氧树脂复合材料层合板相比,添加了MWCNTs的层合板的拉伸强度降低了10.24%,弯曲强度降低了13.90%,压缩强度降低了17.33%,拉伸模量和弯曲模量分别提高了19.38%和16.04%,压缩模量提高了13%;MWCNTs与玻纤织物之间的结合较弱,在拉伸作用下,存在明显的脱粘和分层;将改性玻纤织物在200℃下热压处理2h后,制备的MWCNTs改性玻纤织物/环氧树脂复合材料层合板的力学性能均有所提高,热压处理后树脂与玻纤织物之间的界面结合得到改善.
参考文献
[1] | 黎小平;张小平;王红伟.碳纤维的发展及其应用现状[J].高科技纤维与应用,2005(5):24-30,40. |
[2] | 刘学慧.连续玄武岩纤维与碳纤维、芳纶、玻璃纤维的对比及其特性概述[J].山西科技,2014(01):87-90. |
[3] | 汪华锋;李振华;王新庆;王淼.纳米碳管/环氧树脂复合材料的制备及力学性能[J].复合材料学报,2004(5):48-51. |
[4] | Florian H. Gojny;Malte H.G. Wichmann;Bodo Fiedler.Influence of different carbon nanotubes on the mechanical properties of epoxy matrix composites - A comparative study[J].Composites science and technology,200515/16(15/16):2300-2313. |
[5] | Arash Montazeri.Mechanical properties of multi-walled carbon nanotube/epoxy composites[J].Materials & design,20109(9):P.4202. |
[6] | Salvetat JP.;Bonard JM.;Bacsa RR.;Kulik AJ.;Stockli T. Burnham NA.;Forro L.;Briggs GAD..Elastic and shear moduli of single-walled carbon nanotube ropes[J].Physical review letters,19995(5):944-947. |
[7] | 朱莉莉;顾轶卓;孙志杰;李敏;张佐光.分散方法对低含量碳纳米管玻纤/环氧层板性能的影响[J].复合材料学报,2012(5):11-17. |
[8] | F.H. GOJNY;M.H.G. WICHMANN;U. KOPKE.Carbon nanotube-reinforced epoxy-composites: enhanced stiffness and fracture toughness at low nanotube content[J].Composites science and technology,200415(15):2363-2371. |
[9] | S. Rahmanian;K.S. Thean;A.R. Suraya;M.A Shazed;M.A Mohd Salleh;H.M. Yusoff.Carbon and glass hierarchical fibers: Influence of carbon nanotubes on tensile, flexural and impact properties of short fiber reinforced composites[J].Materials & design,2013Jan.(Jan.):10-16. |
[10] | Fabrication and multifunctional properties of a hybrid laminate with aligned carbon nanotubes grown In Situ[J].Composites science and technology,20089(9):p.2034. |
[11] | Shafi Ullah Khan;Jayaram R. Pothnis;Jang-Kyo Kim.Effects of carbon nanotube alignment on electrical and mechanical properties of epoxy nanocomposites[J].Composites, Part A. Applied science and manufacturing,2013:26-34. |
[12] | C.A.Martin;J.K.W.Sandler;A.H.Windle;M.-K.Schwarz;W.Bauhofer;K.Schulte;M.S.P.Skhaffer.Electric field-induced aligned multi-wall carbon nanotube networks in epoxy composites[J].Polymer: The International Journal for the Science and Technology of Polymers,20053(3):877-886. |
[13] | Du CS;Yeh J;Pan N.Carbon nanotube thin films with ordered structures[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,20055(5):548-550. |
[14] | Aldo R. Boccaccini;Johann Cho;Judith A. Roether.Electrophoretic deposition of carbon nanotubes[J].Carbon: An International Journal Sponsored by the American Carbon Society,200615(15):3149-3160. |
[15] | Qi An;Andrew N. Bider;Erik T. Thostenson.Hierarchical Composite Structures Prepared by Electrophoretic Deposition of Carbon Nanotubes onto Glass Fibers[J].ACS applied materials & interfaces,20136(6):2022-2032. |
[16] | Erik T. Thostenson;Tsu-Wei Chou.Processing-structure-multi-functional property relationship in carbon nanotube/epoxy composites[J].Carbon: An International Journal Sponsored by the American Carbon Society,200614(14):3022-3029. |
[17] | 赵艳文;顾轶卓;李敏;张佐光.碳纳米管-玻璃纤维/环氧层板双真空灌注工艺及性能[J].复合材料学报,2011(3):13-19. |
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