FeS2黄铁矿具有较高的光吸收系数和合适的禁带宽度,与太阳光谱匹配性较好,是一种具有极大潜力的光电材料,其相纯度对光伏电池的效率有显著影响.本文基于溶剂热法,采用油胺-油酸双配体体系,实现纯相FeS2黄铁矿的快速合成.通过反应温度和反应时间的考察,可知该工艺路线具有合成温度宽和反应时间短等优点.通过反应溶剂、添加剂及含量等参数的进一步考察,获得了更小颗粒尺寸的纯相FeS2黄铁矿,并对应分析了其变化机理.
参考文献
| [1] | Qian XF.;Wang C.;Tang KB.;Xie Y.;Qian YT.;Zhang XM. .Solvent-thermal preparation of nanocrystalline pyrite cobalt disulfide[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):110-112. |
| [2] | 冯旭,何向明,蒲薇华,万春荣,姜长印.锂电池正极材料FeS2[J].化学进展,2008(02):396-404. |
| [3] | CYRUS WADIA;A. PAUL ALIVISATOS;DANIEL M. KAMMEN .Materials Availability Expands the Opportunity for Large-Scale Photovoltaics Deployment[J].Environmental Science & Technology: ES&T,2009(6):2072-2077. |
| [4] | Yue GH;Yan PX;Liu JZ;Fan XY;Zhuo RF .Fabrication, structure, magnetic properties of highly ordered cobalt disulfide nanowire arrays[J].Applied physics letters,2005(26):62505-1-62505-3-0. |
| [5] | N.Arul Dhas;Kenneth S.Suslick .Sonochemical Preparation of Hollow Nanospheres and Hollow Nanocrystals[J].Journal of the American Chemical Society,2005(8):2368-2369. |
| [6] | 张懿强,张辉,于敬学,杨德仁,阙端麟.单分散硫化铜纳米晶的生长及调控[J].材料科学与工程学报,2008(02):208-212. |
| [7] | Wang W;Wang SY;Gao YL;Wang KY;Liu M .Nickel sulfide nanotubes formed by a directional infiltration self-assembly route in AAO templates[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2006(1/3):167-171. |
| [8] | 郑国源,龙飞,马浩,吴一,邹正光.表面活性剂对合成黄铁矿型FeS2的影响研究[J].人工晶体学报,2013(01):149-154. |
| [9] | P.P. Chin;J. Ding;J.B. Yi .Synthesis of FeS2 and FeS nanoparticles by high-energy mechanical milling and mechanochemical processing[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2005(1/2):255-260. |
| [10] | 于志伟,苗鸿雁,谈国强,殷立雄.自组装单层膜技术制备纳米晶态薄膜[J].材料科学与工程学报,2008(02):316-320. |
| [11] | Cyrus Wadia;Yue Wu;Sheraz Gul .Surfactant-Assisted Hydrothermal Synthesis of Single phase Pyrite FeS2 Nanocrystals[J].Chemistry of Materials: A Publication of the American Chemistry Society,2009(13):2568-2570. |
| [12] | Yuan, B.;Luan, W.;Tu, S.-T. .One-step synthesis of cubic FeS _2 and flower-like FeSe _2 particles by a solvothermal reduction process[J].Dalton transactions: An international journal of inorganic chemistry,2012(3):772-776. |
| [13] | Yongan Yang;Ou Chen;Alexander Angerhofer .Radial-Position-Controlled Doping in CdS/ZnS Core/Shell Nanocrystals[J].Journal of the American Chemical Society,2006(38):12428-12429. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%