针对钴矿石含有大量可溶性碱性脉石的特点,提出酸浸—摇床重选除可溶性碱性脉石的预处理方案,并通过对比试验来验证该方案.结果表明:经过酸浸—摇床重选预处理后,酸浸矿中钙的质量分数由8.61%降至2.87%,去除率达74.32%,而金属钴损失率仅为0.15%.经过酸浸—摇床重选预处理,避免了浸出体系酸度不稳定的情况发生,减少了铁矾沉淀的生成量,同时也避免了硫酸钙沉淀的生成.酸浸矿体系钴回收率为87.7%,较原矿体系提高35.2%,效果良好.经过酸浸—摇床重选预处理不但使该钴矿石适合采用微生物浸出技术回收钴,而且也缓解了该矿山大量硫酸无法消耗的情况.
参考文献
[1] | Behera, S. K.;Panda, P. P.;Singh, S.;Pradhan, N.;Sukla, L. B.;Mishra, B. K. . .Study on reaction mechanism of bioleaching of nickel and cobalt from lateritic chromite overburdens[J].International Biodeterioration & Biodegradation,2011(7):1035-1042. |
[2] | 温建康,阮仁满.高砷硫低镍钴硫化矿浸矿菌的选育与生物浸出研究[J].稀有金属,2007(04):537-542. |
[3] | Congren Yang;Wenqing Qin;Shaoshi Lai;Jun Wang;Yansheng Zhang;Fen Jiao;Liuyi Ren;Tian Zhuang;Ziyong Chang .Bioleaching of a low grade nickel–copper–cobalt sulfide ore[J].Hydrometallurgy,2011(1/2):32-37. |
[4] | 刘伟,杨洪英,刘媛媛,罗文杰.含钴矿石摇瓶生物浸出比较试验的研究[J].东北大学学报(自然科学版),2013(11):1606-1609,1614. |
[5] | Helmut Tributsch .Direct versus indirect bioleaching[J].Hydrometallurgy,2001(2/3):177-185. |
[6] | F.K. Crundwell .How do bacteria interact with minerals?[J].Hydrometallurgy,2003(1/2):75-81. |
[7] | G.S. Hansford;T. Vargas .Chemical and electrochemical basis of bioleaching processes[J].Hydrometallurgy,2001(2/3):135-145. |
[8] | L. J. Mason;N. M. Rice .The adaptation of Thiobacillus ferrooxidans for the treatment of nickel-iron sulphide concentrates[J].Minerals Engineering,2002(11):795-808. |
[9] | H. Deveci;A. Akcil;I. Alp .Bioleaching of complex zinc sulphides using mesophilic and thermophilic bacteria: comparative importance of pH and iron[J].Hydrometallurgy,2004(3/4):293-303. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%