洋葱碳独特的结构,使其具有优异的物理化学性能。本文首先介绍了洋葱碳的分类和结构,对几种传统的制备方法(包括电弧放电法、等离子体、电子束辐射、化学气相沉积、纳米金刚石真空退火、热解法)的优缺点进行归纳、总结。其次,介绍了近年来发展起来的制备方法。随后,对近年来洋葱碳在锂离子二次电池负极、染料敏化太阳能电池对电极、电化学储氢电极、超级电容器电极、摩擦和磨损、催化领域的应用做一概述。最后,指出了目前洋葱碳在制备和应用方面的不足,对今后的研究做了展望。
Due to unique structure, onion-like carbon has excellent physical and chemical properties that brodens the application in carbon and carbon-based composite materials. The classification and the structure of onion-like carbon were firstly introduced. Its advantages and disadvantages of traditional preparation methods, including arc discharge, plasma, electron-beam radiation, chemical vapor deposition, nanodiamond annealing in vacuum, thermolysis, were summarized. Then, some new synthetic methods developed in recent years were also presented. Subsequently, the ap-plication of onion-like carbon on anode materials of lithium ion secondary battery, counter electrode materials of dye-sensitized solar cell, electrodes materials of electrochemical hydrogen storage and super capacitor, friction and wear, and catalyst fields was summarized. Finally, deficiencies of preparation and application on onion-like carbon were pointed out and future research were put forward.
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