镀液流动对泡沫炭真空超声化学镀铜的影响

无机材料学报, 2016, 31(1): 69-74. doi: 10.15541/jim20150276

镀液流动对泡沫炭真空超声化学镀铜的影响

杨柳 ^1, , 刘秀军 ^2, , 李同起 ^3, , 韩瑞连 ^4, , 冯志海 ^5,

1.天津工业大学环境与化学工程学院,天津,300387

2.天津工业大学环境与化学工程学院,天津,300387

3.航天材料及工艺研究所先进功能复合材料技术国防科技重点实验室,北京,100076

4.天津工业大学环境与化学工程学院,天津,300387

5.航天材料及工艺研究所先进功能复合材料技术国防科技重点实验室,北京,100076

基金项目: National Natural Science Foundation of China(51102070) 国家重点实验室基金(9140C560109130C569199) 国家自然科学基金(51102070) State Key Laboratory Program(9140C560109130C569199)

关键词：流动镀 , 化学镀铜 , 泡沫炭 , 真空辅助

Effect of Plating Solution Flow Pattern on Preparation of Electroless Copper-Plated Carbon Foam under Vacuum and Ultrasonic Conditions

Keywords： plating solution flow , electroless copper plating , carbon foam , vacuum assisted

真空超声辅助化学镀铜,可以在大体积泡沫炭内部孔隙表面镀铜,但沉铜分布不均.在此基础上,本研究强制镀液在泡沫炭内部充分流动,并探究流动方式对镀层性能的影响.相比于镀液单向流动,镀液双向流动实现了铜增量的均匀分布,轴向切片铜的增重率超过7.10％,整块泡沫炭铜的增重率为7.68％;镀层均匀致密,平整光滑,厚度超过5 tm,各向分布差异很小;镀层无CuO、Cu2O杂质;机械性能、电学性能都得到均匀地提高,压缩强度从0.70 MPa增大至1.54 MPa,电导率从700 S/cm增加至1724 S/cm.

参考文献

[1]	李同起;王成扬.中间相沥青基泡沫炭的制备与结构表征[J].无机材料学报,2005(6):1438-1444.
[2]	James W.Klett;April D.McMillan;Nidia C.Gallego;Timothy D.Burchell;Claudia A.Walls.Effects of heat treatment conditions on the thermal properties of mesophase pitch-derived graphitic foams[J].Carbon: An International Journal Sponsored by the American Carbon Society,20048/9(8/9):1849-1852.
[3]	Klett J.;Romine E.;Walls C.;Burchell T.;Hardy R..High-thermal-conductivity, mesophase-pitch-derived carbon foams: effect of precursor on structure and properties[J].Carbon: An International Journal Sponsored by the American Carbon Society,20007(7):953-973.
[4]	王妹先 .中间相沥青基泡沫炭的制备及性能研究[D].天津大学,2008.
[5]	Sangwook Sihn;Ajit K. Roy.Modeling and prediction of bulk properties of open-cell carbon foam[J].Journal of the Mechanics and Physics of Solids,20041(1):167-191.
[6]	Mei-xian Wang;Cheng-Yang Wang;Tong-Qi Li.Preparation of mesophase-pitch-based carbon foams at low pressures[J].Carbon: An International Journal Sponsored by the American Carbon Society,20081(1):84-91.
[7]	Sizhong Li;Yongzhong Song;Yan Song.Carbon foams with high compressive strength derived from mixtures of mesocarbon microbeads and mesophase pitch[J].Carbon: An International Journal Sponsored by the American Carbon Society,200710(10):2092-2097.
[8]	Vignoles, GL;Gaborieau, C;Delettrez, S;Chollon, G;Langlais, F.Reinforced carbon foams prepared by chemical vapor infiltration: A process modeling approach[J].Surface & Coatings Technology,20085/7(5/7):510-515.
[9]	Khalid Lafdi;Mohammad Almajali;Omer Huzayyin.Thermal properties of copper-coated carbon foams[J].Carbon: An International Journal Sponsored by the American Carbon Society,200911(11):2620-2626.
[10]	M. Almajali;K. Lafdi;P.H. Prodhomme.Mechanical properties of copper-coated carbon foams[J].Carbon: An International Journal Sponsored by the American Carbon Society,20105(5):1604-1608.
[11]	M. Almajali;K. Lafdi.Assessment of carbon foam geometry during copper coating[J].Carbon: An International Journal Sponsored by the American Carbon Society,201015(15):4238-4247.
[12]	杨春光;肖尤明;陈楠;徐烈.真空下非金属材料放气模型与研究综述[J].真空,2006(3):48-50.
[13]	Zhai, Lili;Liu, Xiujun;Li, Tongqi;Feng, Zhihai;Fan, Zhen.Vacuum and ultrasonic co-assisted electroless copper plating on carbon foams[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,2015:21-25.
[14]	余刚;邹超;胡波年;黄兴华;叶立元.超声流动镀铜法制备铜包石墨粉[J].湖南大学学报（自然科学版）,2011(2):60-64.

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