采用浸渍-焙烧法制备了具有可见光响应活性的硅藻土/g-C3N4复合光催化材料.利用TG、XRD、FE-SEM、HR-TEM、FT-IR、XPS、UV-Vis-DRS和PL谱等手段对其物相组成、形貌和光吸收特性进行表征.以RhB的光催化降解为探针反应评价催化剂的活性.光催化结果表明,2.32wt%硅藻土/g-C3N4复合材料对RhB有较高的催化活性,光催化降解的速率常数是纯g-C3N4的1.9倍.自由基捕获实验表明,·O2-是RhB在硅藻土/g-C3N4复合材料上光催化降解的主要活性物种.光催化活性提高的主要原因在于硅藻土和g-C3N4之间静电作用有利于光生电子-空穴在g-C3N4表面的迁移,进而提高g-C3N4的光催化活性.
参考文献
[1] | Walter, M.G.;Warren, E.L.;McKone, J.R.;Boettcher, S.W.;Mi, Q.;Santori, E.A.;Lewis, N.S..Solar water splitting cells[J].Chemical Reviews,201011(11):6446-6473. |
[2] | Xinchen Wang;Kazuhiko Maeda;Arne Thomas.A metal-free polymeric photocatalyst for hydrogen production frorrr water under visible light[J].Nature materials,20091(1):76-80. |
[3] | Yan, S. C.;Li, Z. S.;Zou, Z. G..Photodegradation Performance of g-C3N4 Fabricated by Directly Heating Melamine[J].Langmuir,200917(17):10397-10401. |
[4] | Zhang, X.;Xie, X.;Wang, H.;Zhang, J.;Pan, B.;Xie, Y..Enhanced photoresponsive ultrathin graphitic-phase C_3N _4 nanosheets for bioimaging[J].Journal of the American Chemical Society,20131(1):18-21. |
[5] | Zhang, Y.;Mori, T.;Ye, J.;Antonietti, M..Phosphorus-doped carbon nitride solid: Enhanced electrical conductivity and photocurrent generation[J].Journal of the American Chemical Society,201018(18):6294-6295. |
[6] | Xinguo Ma;anhui Lv;Jing Xu.A Strategy of Enhancing the Photoactivity of g-C3N4 via Doping of Nonmetal Elements: A First-Principles Study[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201244(44):23485-23493. |
[7] | Yan, SC;Li, ZS;Zou, ZG.Photodegradation of Rhodamine B and Methyl Orange over Boron-Doped g-C3N4 under Visible Light Irradiation[J].Langmuir: The ACS Journal of Surfaces and Colloids,20106(6):3894-3901. |
[8] | Chen, Xiufang;Zhang, Jinshui;Fu, Xianzhi;Antonietti, Markus;Wang, Xinchen.Fe-g-C3N4-Catalyzed Oxidation of Benzene to Phenol Using Hydrogen Peroxide and Visible Light[J].Journal of the American Chemical Society,200933(33):11658-11659. |
[9] | Lei Ge;Fan Zuo;Jikai Liu.Synthesis and Efficient Visible Light Photocatalytic Hydrogen Evolution of Polymeric g-C3N4 Coupled with CdS Quantum Dots[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201225(25):13708-13714. |
[10] | Xiaojing Wang;Wen-yan Yang;Fa-tang Li.In Situ Microwave-Assisted Synthesis of Porous N-TiO2/g-C3N4 Heterojunctions with Enhanced Visible-Light Photocatalytic Properties[J].Industrial & Engineering Chemistry Research,201348(48):17140-17150. |
[11] | Hideyuki Ratsumata;Tsubasa Sakai;Tohru Suzuki.Highly Efficient Photocatalytic Activity of g-C3N4/Ag3PO4 Hybrid Photocatalysts through Z-Scheme Photocatalytic Mechanism under Visible Light[J].Industrial & Engineering Chemistry Research,201419(19):8018-8025. |
[12] | Yiming He;Jun Cai;Tingting Li.Synthesis, Characterization, and Activity Evaluation of DyVO4/g-C3N4 Composites under Visible-Light Irradiation[J].Industrial & Engineering Chemistry Research,201245(45):14729-14737. |
[13] | Dong, Fan;Ni, Zilin;Li, Peidong;Wu, Zhongbiao.A general method for type I and type II g-C3N4/g-C3N4 metal-free isotype heterostructures with enhanced visible light photocatalysis[J].New Journal of Chemistry,20156(6):4737-4744. |
[14] | Kyung-Won Jung;Duksoo Jang;Kyu-Hong Ahn.A novel approach for improvement of purity and porosity in diatomite (diatomaceous earth) by applying an electric field[J].International Journal of Mineral Processing,2014:7-11. |
[15] | Wang, Bin;Zhang, Guangxin;Leng, Xue;Sun, Zhiming;Zheng, Shuilin.Characterization and improved solar light activity of vanadium doped TiO2/diatomite hybrid catalysts[J].Journal of hazardous materials,2015Mar.21(Mar.21):212-220. |
[16] | Zhiming Sun;Xiaoping Yang;Guangxin Zhang.A novel method for purification of low grade diatomite powders in centrifugal fields[J].International Journal of Mineral Processing,2013:18-26. |
[17] | Dusan Losic;James G. Mitchell;Nicolas H. Voelcker.Diatomaceous Lessons in Nanotechnology and Advanced Materials[J].Advanced Materials,200929(29):2947-2958. |
[18] | Myroslav Sprynskyy;Iryna Kovalchuk;Boguslaw Buszewski.The separation of uranium ions by natural and modified diatomite from aqueous solution[J].Journal of hazardous materials,20101/3(1/3):700-707. |
[19] | Yu, Wenbin;Yuan, Peng;Liu, Dong;Deng, Liangliang;Yuan, Weiwei;Tao, Bo;Cheng, Hefa;Chen, Fanrong.Facile preparation of hierarchically porous diatomite/MFI-type zeolite composites and their performance of benzene adsorption: The effects of NaOH etching pretreatment[J].Journal of hazardous materials,2015Mar.21(Mar.21):173-181. |
[20] | Yucheng Du;Haiguang Fan;Liping Wang.α-Fe2O3 nanowires deposited diatomite: highly efficient absorbents for the removal of arsenic[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201326(26):7729-7737. |
[21] | Su-Gwang Jeong;Jisoo Jeon;Jeong-Hun Lee;Sumin Kim.Optimal preparation of PCM/diatomite composites for enhancing thermal properties[J].International Journal of Heat and Mass Transfer,2013:711-717. |
[22] | Shaofei Guo;Li Shi.Synthesis of succinic anhydride from maleic anhydride on Ni/diatomite catalysts[J].Catalysis Today,2013:137-141. |
[23] | Ping Niu;Gang Liu;Hui-Ming Cheng.Nitrogen Vacancy-Promoted Photocatalytic Activity of Graphitic Carbon Nitride[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201220(20):11013-11018. |
[24] | Majeda A.M.Khraisheh;Yahya S.Al-degs;Wendy A.M.Mcminn.Remediation of wastewater containing heavy metals using raw and modified diatomite[J].Chemical Engineering Journal,20042(2):177-184. |
[25] | Fan Dong;Liwen Wu;Yanjuan Sun.Efficient synthesis of polymeric g-C3N4 layered materials as novel efficient visible light driven photocatalysts[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201139(39):15171-15174. |
[26] | Yajun Wang;Xiaojuan Bai;Chengsi Pan.Enhancement of photocatalytic activity of Bi2WO6 hybridized with graphite-like C3N4[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201223(23):11568-11573. |
[27] | Zhang, YJ;Thomas, A;Antonietti, M;Wang, XC.Activation of Carbon Nitride Solids by Protonation: Morphology Changes, Enhanced Ionic Conductivity, and Photoconduction Experiments[J].Journal of the American Chemical Society,20091(1):50-51. |
[28] | Quanjun Xiang;Jiaguo Yu;Mietek Jaroniec.Preparation and Enhanced Visible-Light Photocatalytic H2-Production Activity of Graphene/C3N4 Composites[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201115(15):7355-7363. |
[29] | MINGCAI YIN;ZHAOSHENG LI;JIAHUI KOU.Mechanism Investigation of Visible Light-Induced Degradation in a Heterogeneous TiO2/Eosin Y/Rhodamine B System[J].Environmental Science & Technology: ES&T,200921(21):8361-8366. |
[30] | Li, Baoying;Huang, Hongwei;Guo, Yuxi;Zhang, Yihe.Diatomite-immobilized BiOI hybrid photocatalyst: Facile deposition synthesis and enhanced photocatalytic activity[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2015Oct.30(Oct.30):1179-1185. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%