以新型取代聚乙炔—聚[1-(4-三甲基硅基)苯基-2-苯乙炔](PTMSDPA)为膜材料,采用溶剂蒸发法制备均质膜,研究其对不同染料-乙醇溶液的纳滤性能.发现在所考察的压力、温度范围内,PTMSDPA均质膜的乙醇渗透性能稳定,耐压密性良好,且无老化现象.膜的分离性能不仅和染料的相对分子质量有关,也和染料所带电荷相关,膜和染料之间的相互作用是影响膜分离性能的重要因素.
参考文献
[1] | Patrizia Marchetti;Maria F. Jimenez Solomon;Gyorgy Szekely;Andrew G. Livingston.Molecular Separation with Organic Solvent Nanofiltration: A Critical Review[J].Chemical Reviews,201421(21):10735-10806. |
[2] | 李祥;张忠国;任晓晶;李继定.纳滤膜材料研究进展[J].化工进展,2014(5):1210-1218,1229. |
[3] | 王晓琳;涂丛慧;方彦彦;肖燕;周波.纳滤膜孔结构、荷电性质、分离机理及动电性质研究进展[J].膜科学与技术,2011(3):127-134. |
[4] | 王晓琳;张澄洪;赵杰.纳滤膜的分离机理及其在食品和医药行业中的应用[J].膜科学与技术,2000(1):29-36. |
[5] | 吴法东;周勇;高从堦.耐溶剂高分子纳滤膜研究进展[J].水处理技术,2010(12):1-5,14. |
[6] | Vandezande P;Gevers LEM;Vankelecom IFJ.Solvent resistant nanofiltration: separating on a molecular level[J].Chemical Society Reviews,20082(2):365-405. |
[7] | Kazukiyo Nagai;Toshio Masuda;Tsutomu Nakagawa;Benny D.Freeman;Ingo Pinnau.Poly[1-(trimethylsilyl)-1-propyne] and related polymers: synthesis, properties and functions[J].Progress in Polymer Science,20015(5):721-798. |
[8] | Volkov AV;Stamatialis DF;Khotimsky VS;Volkov VV;Wessling M;Plate NA.Poly[1-(trimethylsilyl)-1-propyne] as a solvent resistance nanofiltration membrane material[J].Journal of Membrane Science,20061/2(1/2):351-357. |
[9] | 胡雁鸣;高可可;张丛峥;李战胜;增田俊夫.物理老化对聚[1-(4-三甲基硅基)苯基-2-苯乙炔]膜气体渗透性能的影响[J].化学工业与工程,2014(1):53-56. |
[10] | Kai Fischer;Michael Wilken.Experimental determination of oxygen and nitrogen solubility in organic solvents up to 10 MPa at temperatures between 298 K and 298 K[J].The Journal of Chemical Thermodynamics,200110(10):1285-1308. |
[11] | Machado Darlo R;Hasson David.Effect of solvent properties on permeate flow through nanofiltration membranes. Part I: investigation of parameters affecting solvent flux[J].Journal of Membrane Science,19991(1):93-102. |
[12] | S. E. Tsar'kov;A. O. Malakhov;E. G. Iitvinova.Nanofiltration of Dye Solutions through Membranes Based on Pory(trimethylsilylpropyne)[J].Petroleum Chemistry,20137(7):537-545. |
[13] | Bhanushali D.;Kloos S.;Bhattacharyya D..Solute transport in solvent-resistant nanofiltration membranes for non-aqueous systems: experimental results and the role of solute-solvent coupling[J].Journal of Membrane Science,20021/2(1/2):343-359. |
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