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目的:改善铝合金的综合性能,尤其是耐磨性。方法采用微弧氧化技术,在铝合金表面制备具有自润滑效果的微弧氧化陶瓷膜层。通过分析电解参数(电流密度、频级和能级)对微弧氧化陶瓷膜耐磨性的影响,以及添加剂石墨对陶瓷膜厚度、表面形貌、相组成、耐磨性和耐蚀性的影响,探索可以提高铝合金表面微弧氧化陶瓷膜综合性能的电解参数,研究石墨在铝合金微弧氧化中所起的作用。结果确定了最佳电解参数。添加剂石墨不仅降低了铝合金陶瓷膜的摩擦系数,同时也提高了铝合金的耐蚀性。结论在铝合金微弧氧化中,石墨的自润滑特性和超高的导电性促进了铝合金在微弧氧化过程中成膜反应的进行,增加了陶瓷膜层的厚度,同时对试样表面有光滑、整平的作用。

ABSTRACT:Objective To improve the comprehensive performance of aluminum alloy, especially the wear resistance. Methods Self-lubricating ceramic layers were prepared by the micro-arc oxidation technology on the surface of aluminum alloy. The electro-lytic parameters for improving the comprehensive performance of the micro-arc oxidized ceramic membrane on the aluminum alloy and the role of graphite in the micro-arc oxidation of aluminum alloy were explored by analyzing the effects of electrolytic parameters ( current density, frequency ratio, energy level ratio) on the wear resistance of the micro-arc oxidized ceramic membrane and the influences of graphite addition on the thickness of ceramic membrane, surface morphology, phase composition, wear resistance and corrosion resistance. Results The optimal electrolytic parameters were determined. Graphite addition could not only decrease the friction coefficient of the micro-arc oxidized ceramic membrane on the aluminum alloy, but also improve the corrosion resistance of aluminum alloy. Conclusion With self-lubricating property and ultrahigh electric conductivity, graphite could promote the mem- brane forming reaction during the micro-arc oxidation of aluminum alloy, increase the thickness of the ceramic layer and smooth the surface morphology of the as-obtained aluminum alloy.

参考文献

[1] Donglei He;Guolong Li;Dejiu Shen;Changhong Guo;Haojie Ma;Jingrui Cai.Effect mechanism of ultrasound on growth of micro-arc oxidation coatings on A96061 aluminum alloy[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,2014:99-102.
[2] Laís T. Duarte;Claudemiro Bolfarini;Sonia R. Biaggio;Romeu C. Rocha-Filho;Pedro A.P. Nascente.Growth of aluminum-free porous oxide layers on titanium and its alloys Ti-6Al-4V and Ti-6Al-7Nb by micro-arc oxidation[J].Materials science & engineering, C. Materials for Biogical applications,2014:343-348.
[3] 钱建才,许斌,邹洪庆,吴厚昌,吕基成,方敏.2A12铝合金硬质阳极氧化及膜层性能研究[J].表面技术,2014(05):37-41.
[4] BOSTA M M S Al;MA K-J .Suggested Mechanism for the MAO Ceramic on Aluminium Substrate Using Bipolar Current Mode in the Alkaline Silicate Electrolytes[J].Applied Surface Science,2014,308:121-138.
[5] 杨巍,蒋百灵,时惠英.LY12铝合金微弧氧化膜层的形成与生长机制[J].中国有色金属学报,2010(10):1949-1954.
[6] WANG Ping;GUO Xiao-yang;MAO Xian-li .Influences of Vanadium Doping on Structure and Performance of Aluminum Alloy Micro-arc Oxidation Coating[J].RARE METAL MATERIALS AND ENGINEERING,2014,43:1759-1763.
[7] MOHAMMADREZA D;MAT Y A;YUSOF N M .Microstructural Characterization and Corrosion Resistance Evaluation of Nanostructured Al and Al/AlCr Coated Mg-Zn-Ce- La Alloy[J].Journal of Alloys and Compounds,2014,615:657-671.
[8] TENG Fu-yuan;TAI I-Chun;WANG Min-wen .The Structures Electrochemical and Cell Performance of Titania Films Formed on Titanium by Micro-arc Oxidation[J].Journal of the Taiwan Institute of Chemical Engineers,2014,45:1331-1337.
[9] 郭小燕,张津,张叶成,孙智富.表面技术在模具修复中的应用进展[J].表面技术,2007(06):70-73,76.
[10] VENUGOPAL A;PANDA R;MANWATKAR S et al.Effect of Micro Arc Oxidation Treatment on Localized Corrosion Behaviour of AA7075 Aluminum Alloy in 3. 5% NaCl Solu-tion[J].Transactions of Nonferrous Metals Society of Chi-na,2012,22:700-710.
[11] ZHONG Ye-sheng;SHI Li-ping;LI Ming-wei et al.Charac-terization and Thermal Shock Behavior of Composite Cera-mic Coating Doped with ZrO2 Particles on TC4 by Micro-arc Oxidation[J].Applied Surface Science,2014,311:158-163.
[12] 刘鹏,杨伏良.氧化锆陶瓷中温化学镀镍三元络合剂的研究[J].表面技术,2014(05):66-70.
[13] LIU Xing-hua;ZHU Li-qun;LIU Hui-cong .Investigation of MAO Coating Growth Mechanism on Aluminum Alloy by Two-step Oxidation Method[J].Applied Surface Science,2014,293:12-17.
[14] KAAN Y S;MUHAFFEL F;MURAT B .Effect of Incorpora-ting Carbon Nanotubes into Electrolyte on Surface Morpho-logy of Micro Arc Oxidation Cp-Ti[J].Applied Surface Sci-ence,2014,318:10-14.
[15] ZHAO QING LIN;HUI JUN YU;SI YU HE;YI NING HE;CHUAN ZHONG CHEN .EFFECT OF KOH ON MICRO-ARC OXIDATION COATINGS OF 2A12 ALUMINUM ALLOYS IN CH_3COONa-Na_2WO_4 ELECTROLYTE[J].Surface review and letters,2014(2):1450026-1-1450026-6.
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