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目的:选择恰当、高效防腐对策以提高气田开发经济效益,保证气井安全生产。方法对陕北某气田的水质进行全面分析,并以通入饱和CO2的气田气井产出水作为腐蚀介质,通过静态失重法探讨温度、矿化度、体系酸碱度、水介质中CO2含量、H2 S含量、溶解氧含量、HCO3含量、Cl-含量对设备管道腐蚀性的影响及其腐蚀规律。结果陕北某气田的气井产出水矿化度约为50000 mg/L,且Cl-、HCO3-含量偏高,水样呈弱酸性,pH值约6.5;腐蚀速率随水介质中CO2含量、H2S含量、溶解氧含量、HCO3-含量、Cl-含量增加均呈增加趋势,在50℃时最大达到0.352 mm/a,pH值为7时最小为0.250 mm/a。结论陕北某气田设备管道的腐蚀主要表现为O2腐蚀和CO2腐蚀。

Objective To choose appropriate and efficient anti-corrosion measures so as to improve economic benefit and ensure safety of oilfield production. Methods In the paper, water quality of Shanbei gasfield was analyzed and the gas field water from gas well replenished with saturated CO2 was taken as corrosive medium. The influences of temperature, salinity, systematic pH, CO2 content and H2 S content in the water, dissolved oxygen content, HCO3- content and Cl- content on the equipment pipeline corro-sion and the corrosion pattern were discussed by static weight-loss method. Results The water from Shanbei gasfield had the salinity reaching about 50 000 mg/L, Cl-and HCO3-contents were relatively high, the water sample was weak acidic, the pH value was a-round 6. 5. The corrosion rate increased with the increasing in contents of CO2 , H2 S, dissolved oxygen, HCO3-and Cl-in the wa-ter medium, the corrosion rate reached the maximum 0. 352 mm/a at 50℃ and the lowest 0. 250 mm/a when the pH value was 7. Conclusion Corrosion of equipment pipelines of Shanbei gasfield is mainly O2 corrsion and CO2 corrsion.

参考文献

[1] 宋伟;李娅;冯小波;谷坛.重庆气矿气井腐蚀现状及防腐对策[J].石油与天然气化工,2004(6):437-439,443.
[2] S.D. Zhu;A.Q. Fu;J. Miao;Z.F. Yin;G.S. Zhou;J.F. Wei.Corrosion of N80 carbon steel in oil field formation water containing CO_2in the absence and presence of acetic acid[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,201110(10):3156-3165.
[3] O. Yevtushenko;D. Bettge;S. Bohraus.Corrosion behavior of steels for CO2 injection[J].Transactions of The Institution of Chemical Engineers. Process Safety and Environmental Protection, Part B,20141(1):108-118.
[4] R. Cabrera-Sierra;I. Garcia;E. Sosa;T. Oropeza;I. Gonzalez.Electrochemical behavior of carbon steel in alkaline sour environments measured by electrochemical impedance spectroscopy[J].Electrochimica Acta,20004(4):487-497.
[5] 李国敏;李爱魁;郭兴蓬;郑家燊.油气田开发中的CO2腐蚀及防护技术[J].材料保护,2003(6):1-5.
[6] 鲍云波.CO2驱油气井的腐蚀预测与防护[J].油气田地面工程,2013(06):97-98.
[7] 张星;李兆敏;马新忠;张志宏;董斌.深井油管H2S应力腐蚀实验研究[J].石油勘探与开发,2004(6):95-97.
[8] 艾志久;范钰伟;赵乾坤.H2 S对油气管材的腐蚀及防护研究综述[J].表面技术,2015(9):108-115.
[9] 赵国仙;吕祥鸿.温度对油套管用钢腐蚀速率的影响[J].西安石油大学学报(自然科学版),2008(4):74-78.
[10] 朱世东;白真权;刘会;林冠发.Ca2+、Mg2+对N80钢腐蚀速率的影响[J].腐蚀与防护,2008(12):724-726.
[11] 李春福;王斌;张颖;罗平亚.油气田开发中CO2腐蚀研究进展[J].西南石油学院学报,2004(2):42-46.
[12] 李建平;赵国仙;郝士明.几种因素对油套管钢CO2腐蚀行为影响[J].中国腐蚀与防护学报,2005(4):241-244.
[13] 刘雨薇;王振尧;吕旺燕;苏伟.模拟酸雨大气环境中Cl-浓度对镀锌钢腐蚀行为的影响[J].装备环境工程,2015(4):22-26,43.
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