锆合金已被广泛用于核反应堆的堆芯结构材料,但其耐腐蚀性能和耐磨性能制约着使用寿命,采用合适的表面处理技术可以改善其表面完整性.通过对近几年核用锆合金表面处理的研究进行归纳总结,简单介绍了锆合金的研发进展,并着重对能提高锆合金耐腐蚀性能和耐磨性能的表面处理技术进行了综述,如喷丸处理、超声冲击强化、冷轧、渗氮和渗铝等.总结了各种表面处理技术对锆合金的微观结构和性能的影响,并介绍了结构和性能之间的联系.最后对锆合金表面处理技术进行了讨论和展望.
Zirconium alloy has been widely used in nuclear reactor core structure materials, but the service life is restricted by its corrosion resistance and wear resistance. The surface integrity can be improved by adopting appropriate surface modification technique. In this paper, the literatures on the surface treatment of nuclear zirconium alloys in recent years were summarized. The development progress of zirconium alloys was briefly introduced and the surface treatment techniques that can improve the corrosion resistance and wear resistance of zirconium alloys were reviewed, such as shot peening, ultrasonic impact peening, cold rolling, ni-trogen implantation and aluminum implantation. The effects of various surface treatment techniques on the microstructure and prop-erties of zirconium alloys were summarized and the relationship between the structure and properties was introduced. Ultimately the surface modification techniques of zirconium alloy were discussed and prospected.
参考文献
[1] | de Gabory, Benoit;Motta, Arthur T.;Wang, Ke.Transmission electron microscopy characterization of Zircaloy-4 and ZIRLO (TM) oxide layers[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2015:272-280. |
[2] | Steinbrück, M.;B?ttcher, M..Air oxidation of Zircaloy-4, M5? and ZIRLO? cladding alloys at high temperatures[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,20112(2):276-285. |
[3] | Hengstler-Eger, R.M.;Baldo, P.;Beck, L.;Dorner, J.;Ertl, K.;Hoffmann, P.B.;Hugenschmidt, C.;Kirk, M.A.;Petry, W.;Pikart, P.;Rempel, A..Heavy ion irradiation induced dislocation loops in AREVA's M5? alloy[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,20121/3(1/3):170-182. |
[4] | M. Rautenberg;D. Poquillon;P. Pilvin;C. Grosjean;J.M. Cloue;X. Feaugas.Thermal isocreep curves obtained during multi-axial creep tests on recrystallized Zircaloy-4 and M5? alloy[J].Nuclear engineering and design,2014Apr.(Apr.):33-37. |
[5] | Rui Tang;Xiaoxue Yang.Dissolution and precipitation behaviors of hydrides in N18, Zry-4 and M5 alloys[J].International journal of hydrogen energy,200917(17):7269-7274. |
[6] | I. I. Petrova;B. N. Samsonov;V. E. Peletskii.The Experimental Determination of the Melting Heat for E635 Zirconium Alloy[J].High Temperature,20036(6):751-754. |
[7] | 李中奎;刘建章;薛祥义.与我国核电发展相关的堆芯关键材料--锆合金国产化问题[J].稀有金属快报,2007(1):6-9. |
[8] | Kim HG;Park JY;Jeong YH.Phase boundary of the Zr-rich region in commercial grade Zr-Nb alloys[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,20051/2(1/2):140-150. |
[9] | Sh. Fujimoto;H. Hayashida.Extremely high corrosion resistance of thin film stainless steels deposited by ion beam sputtering[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,19992(2):314-318. |
[10] | 张强;张喜燕;李聪;邱绍宇.Zr-4合金的表面晶粒细化研究[J].核动力工程,2009(1):64-67. |
[11] | R. Raghavan;R. Ayer;H.W. Jin.Effect of shot peening on the fatigue life of a Zr-based bulk metallic glass[J].Scripta materialia,20082(2):167-170. |
[12] | 石明华;张喜燕;李中奎;李聪;张建军;王文生;周军;田锋.喷丸处理Zr-4合金氧化膜组织和氧化动力学研究[J].稀有金属材料与工程,2009(7):1288-1291. |
[13] | A. Gebert;A. Concustell;A.L. Greer.Effect of shot-peening on the corrosion resistance of a Zr-based bulk metallic glass[J].Scripta materialia,20109(9):635-638. |
[14] | Zhao, Chunmei;Gao, Yukui;Guo, Jing;Wang, Qiang;Fu, Lichao;Yang, Qingxiang.Investigation on Residual Stress Induced by Shot Peening[J].Journal of Materials Engineering and Performance,20153(3):1340-1346. |
[15] | Mordyuk, B.N.;Karasevskaya, O.P.;Prokopenko, G.I..Structurally induced enhancement in corrosion resistance of Zr-2.5%Nb alloy in saline solution by applying ultrasonic impact peening[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2013:453-461. |
[16] | Tewari, R;Srivastava, D;Dey, GK;Chakravarty, JK;Banerjee, S.Microstructural evolution in zirconium based alloys[J].Journal of Nuclear Materials,20081/2(1/2):153-171. |
[17] | S.K. Sahoo;V.D. Hiwarkar;L. Jain;I. Samajdar;P. Pant;G.K. Dey;D. Srivastav;R. Tewari;S. Banerjee.Deformed microstructures of two-phase Zr-2.5Nb alloy: Effects of the second phase hardness[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,20103(3):222-230. |
[18] | Yuan, C.;Fu, R.;Zhang, F.;Zhang, X.;Liu, F..Microstructure evolution and mechanical properties of nanocrystalline zirconium processed by surface circulation rolling treatment[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2013:27-32. |
[19] | M.A. Meyers;A. Mishra;D.J. Benson.Mechanical properties of nanocrystalline materials[J].Progress in materials science,20064(4):427-556. |
[20] | M. Dao;L. Lu;R.J. Asaro.Toward a quantitative understanding of mechanical behavior of nanocrystalline metals[J].Acta materialia,200712(12):4041-4065. |
[21] | W.L. Li;N.R. Tao;K. Lu.Fabrication of a gradient nano-micro-structured surface layer on bulk copper by means of a surface mechanical grinding treatment[J].Scripta materialia,20085(5):546-549. |
[22] | Jiang P;Wei Q;Hong YS;Lu J;Wu XL.In situ synthesis of nanocrystalline intermetallic layer during surface plastic deformation of zirconium[J].Surface & Coatings Technology,20073(3):583-589. |
[23] | Shen TD.;Tsui TY.;Pharr GM.;Koch CC..ON THE ELASTIC MODULI OF NANOCRYSTALLINE FE, CU, NI, AND CU-NI ALLOYS PREPARED BY MECHANICAL MILLING/ALLOYING[J].Journal of Materials Research,199511(11):2892-2896. |
[24] | Leon L. Shaw;Angel L. Ortiz;Juan C. Villegas.Hall-Petch relationship in a nanotwinned nickel alloy[J].Scripta materialia,200811(11):951-954. |
[25] | K. S. Kumar;H. Van Swygenhoven;S. Suresh.Mechanical behavior of nanocrystalline metals and alloys[J].Acta materialia,200319(19):5743-5774. |
[26] | C.S. Pande;K.P. Cooper.Nanomechanics of Hall-Petch relationship in nanocrystalline materials[J].Progress in materials science,20096(6):663. |
[27] | Huang, Lu;Zhu, Chao;Muntele, Claudiu I.;Zhang, Tao;Liaw, Peter K.;He, Wei.Surface engineering of a Zr-based bulk metallic glass with low energy Ar- or Ca-ion implantation[J].Materials science & engineering, C. Materials for Biogical applications,2015:248-255. |
[28] | K.P. Purushotham;L.P. Ward;N. Brack;P.J. Pigram;P. Evans;H. Noorman;R.R. Manorv.The effect of MEVVA ion implantation of Zr on the corrosion behaviour of PVD TiN coatings[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,20081(1):8-14. |
[29] | Liu YZ;Zu XT;Qiu SY;Wang L;Ma WG;Wei CF.Surface characterization and corrosion resistance of Ti-Al-Zr alloy by niobium ion implantation[J].Nuclear Instruments and Methods in Physics Research, Section B. Beam Interactions with Materials and Atoms,20062(2):397-402. |
[30] | Kwon HS;Kim W;Choi BH;Lee SJ.Effects of compositional and structural change on the corrosion behaviour of nitrogen implanted Zircaloy-4[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,19991(1):23-31. |
[31] | D.Q. Peng;X.D. Bai;F. Pan;H. Sun;B.S. Chen.Influence of aluminum ions implanted on corrosion behavior of zirconium in 1 M H_2SO_4[J].Materials Letters,200519/20(19/20):2496-2503. |
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