添加NH4Cl的洗液对负载有机相中Zn2+洗涤率的影响

稀土, 2016, 37(4): 74-80. doi: 10.16533/J.CNKI.15-1099/TF.201604012

添加NH4Cl的洗液对负载有机相中Zn2+洗涤率的影响

王军 ^1, , 郝先库 ^2, , 李向阳 ^3, , 赵永志 ^4, , 马显东 ^5, , 张瑞祥 ^6,

1.内蒙古科技大学材料与冶金学院,内蒙古包头,014010

2.包头稀土研究院,内蒙古包头014030;包头市京瑞新材料有限公司,内蒙古包头014015

3.内蒙古科技大学材料与冶金学院,内蒙古包头,014010

4.包头稀土研究院,内蒙古包头014030;包头市京瑞新材料有限公司,内蒙古包头014015

5.包头市京瑞新材料有限公司,内蒙古包头,014015

6.包头稀土研究院,内蒙古包头014030;包头市京瑞新材料有限公司,内蒙古包头014015

关键词：锌 , 钐 , NH4Cl , 洗涤率

Effect of the Washing with NH4Cl on the Washing Rate of Zn2+ in the Loaded Organic Phase

Keywords： zinc , samarium , NH4Cl , washing rate

以盐酸和SmCl3溶液作为洗液,对负载Sm3+和Zn2+的有机相进行洗涤,分别研究了添加和未添加NH4Cl的洗液对负载有机相中Zn2洗涤率的影响.结果表明,在相比O/A为2:1时,用1.5 mol/L盐酸添加3 mol/L NH4Cl洗液,可以将Zn2+完全洗涤,而未添加NH4Cl的洗液酸度大于等于2 mol/L时,才能将Zn2完全洗涤;以0.5 mol/L SmCl3溶液添加NH4Cl作为洗液,Zn2完全被洗涤,未添加NH4Cl的SmCl3洗液,Zn2+洗涤率为92.35％.

The organic phase loading Sm3+ and Zn2+ was washed by hydrochloric acid and SmCl3 solution in the experiment.The washing with and without NH4Cl had an influence on the washing rate of Zn2 + in the loaded organic phase.The results show that Zn2+ can be completely washed with 1.5 mol/L HCl adding 3 mol/L NH4Cl or with ≥2 mol/L HCl and without NH4Cl.Zn2+ can also be completely washed with 0.5 mol/L SmCl3 solution adding NH4Cl,but the washing rate was 92.35％ with 0.5 mol/L SmCl3 solution without NH4Cl.

参考文献

上一张下一张

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%