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综述了近半个世纪来M5Si3型硅化物研究的主要成果,从物理冶金的角度讨论了这一类化合物的共性和个性,阐述它们的相图与热力学性质、晶体结构、物理化学性质,还讨论了它们的制备、合金化与韧性化等方面的问题;最后,展望了M5Si3型硅化物研究的发展趋势和它们的工程应用前景.

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