对用混合合金法制备的Nd7.69Dy6.62Fe64.33Co14.83B6.53/Ga烧结磁体的磁性和微观结构进行了研究.结果表明:添加0.5%(质量分数)的Ga后,磁体的iHc由1232 kA/m升高到1819 kA/m,在200℃放置0.5 h后的磁通不可逆损失由33.3%下降到5%以下.当Ga的添加量达到1.0%左右时,Ga的作用达到最大值.微观结构分析表明,不添加Ga磁体的晶粒边界、尤其是晶界角隅处多呈现弯曲和凹凸不平的形状,添加Ga磁体的晶粒边界则呈现平滑和近似直线的形状.烧结过程中Ga原子置换Nd2Fel4B相中Fe原子形成Nd2Fel4-xGaxB相,与此同时,被置换的Fe原子进入液相与富Nd相、富B相反应形成新的Nd2Fel4B(或Nd2Fel4-xGaxB)相,这是导致磁体的磁性和微观结构发生变化的主要原因.
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