利用二维Miedema坐标(△φ*和△n-1/3 W-S)以及加入尺寸因素△R/RA构成的三维化学坐标揭示了化学镀多元合金的非晶形成规律.对已有实验结果的60个化学镀多元合金系分析表明,非晶化条件为:二维坐标系中,二元和三元体系,|△φ*|＞6.9|△n-1/3 W-S|;二元、三元和四元体系,|△φ*|＞6.9|△n-1/3 W-S|+0.1.三维坐标系中,二元体系,|△R/RA|＞0.18[1-|△n-1/3 W-S|/(-0.01)-|△φ*|/0.08];二元和三元体系,|△R/RA|＞0.14[1-|△n-1/3 W-S|/(-0.01)-|△φ*|/0.08];二元、三元和四元体系,|△R/RA|＞0.26[1-|△n-1/3 W-S|/(-0.01)-|△φ*|/0.07].二元和三元合金系统的区分准确率高于84%;四元合金体系的区分准确率高于81%.
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