在晶界面上用萃取碳复型技术研究了镍基合金GH4049(Ni-15Co-10Cr-5.5W-5Mo-4.2Al-1.5Ti)中与B和C的晶界偏聚效应密切相关的二次析出相特征.B含量低于0.008%时,因固溶B/C(原子比)很低,晶界析出大尺寸MC薄膜和M6C枝晶片以及薄膜状M23C6,不利于高温塑性和持久寿命.B含量为0.011%和0.018%时,固溶B/C(原子比)虽仅为0.667和0.941,已可减少和全部抑制上述碳化物的析出,代之以弥散M3B2颗粒,高温性能大幅度上升.但B含量过高,M3B2密集析出,高温性能下降.降低固溶冷却速度而使B和C原子向晶界长程偏聚,可促进M3B2析出,改善MC的形貌并抑制M6C和M23C6析出.
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