分析了难混溶合金凝固过程中作用在凝固界面前沿液滴上的力,建立了液滴与凝固界面相互作用行为的动力学判据.结合实验,探讨了固/液界面与液滴间相互作用对Al-Bi基难混溶合金凝固组织演变的影响.结果表明,在界面排斥和Marangoni力共同作用下,较小尺寸的富Bi液滴被凝固界面排斥并富积在凝固界面前沿.当凝固界面为枝晶/胞状晶时,临界尺寸的富Bi液滴与界面发生部分捕获,凝固后形成"蝌蚪"型的富Bi粒子;尺寸较小的富Bi液滴被捕获在枝晶/胞状晶间,凝固后富Bi粒子分布于晶界和三叉交角处.
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