欢迎登录材料期刊网

材料期刊网

高级检索

应用CoO、Zn粉对镍电极进行固相掺杂,电极经若干次充放电循环,Co、Zn元素在Ni(OH)2颗粒表层以固溶体的形式富集,可优化活性物质表面的组成和结构,提高活性物质表层的快速反应能力,从而使镍电极更适用于C/Ni(OH)2非对称电容器体系.实验结果表叨:在高倍率充放电条件下,掺杂10%CoO的镍电极,其容量为未掺杂电极的2倍;用5%的Zn粉替代部分导电剂Ni粉,镍电极大电流条件下的循环性能和容量性质将明显改善.

参考文献

[1] Andrew Burke. J. Power Sources, 2000, 91: 3-7-50.
[2] Arbizzani C, Mastragostino M, Soavi F. J. Power Sources, 2001, 100: 164-170.
[3] Liu K C, Anderson M A. J. Electrochem Soc., 1996, 143(1): 124-129 .
[4] 王晓峰,孔祥华(WANG Xiao-Feng,et al).无机材料学报(Journal of Inorganic Materials),2001,16(5):815-820.
[5] 王晓峰,王大志,梁吉(WANG Xiao-Feng,et al).无机材料学报(Journal ofInorganic Materials),2003,18:331-336.
[6] KStz R, Carbon M. Electrochimica Acta, 2000, 45: 2483-2498.
[7] 陈腾飞,贺万宁(CHEN Teng-Fei,et al).矿冶工程(Mining and Metallurgical Engineer),2001,21:43-45.
[8] Provazi K, Giz M J, Dall'Antonia L H, et al. J. Power Sources, 2001, 102: 224-232.
[9] Delia Maria Constantin, Eleonora Maria Rus, Oniciu L, et al. J. Power Sources, 1998, 74: 188-197.
[10] Kim Jong H, Jin Chang S, Shin Kyung H. Electrochemical Society Proceeding, 2002, 7: 172-181.
[11] Srinivasan V, Weidner J W. J. Power Sources, 2002, 108: 15-20.
[12] Singh D. J. Electrochem. Soc., 1998, 145: 116-120.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%