采用水溶液离子交换法制备了锂离子和其它多价阳离子混合交换的13X分子筛,并测定了这些二元离子交换分子筛在25.C下的氮和氩的吸附等温线.研究发现,经二元离子交换的MgLiX、ZnLiX、NiLiX和LaLiX分子筛对氮的吸附能力和对氮氩的吸附分离能力都低于LiX分子筛,且随着多价离子在分子筛中的含量增加,分子筛的氮氩分离性能变差.说明在LiX和实验所制得的各种二元离子交换的分子筛中,LiX分子筛仍是最好的氮氩分离吸附剂.
参考文献
[1] | 刘秀喜,林明喜,薛成山.高纯气体的性质、制造和应用.北京:电子工业出版社,1997.129-139. |
[2] | Yang R T, Chen Y D, Peck J D, et al. Ind. Eng. Chem. Res., 1996, 35: 3093-3099. |
[3] | Rege S U, Yang R T. Ind. Eng. Chem. Res., 1997, 36: 5358-5365. |
[4] | Huston N D, Rege S U, Yang R T. AIChE J., 1999, 45(4): 724-734. |
[5] | Chao C C. Process for Separation Nitrogen from Mixtures thereof with Less Polar Substances. EP 0 297 542,1989. |
[6] | Charles G C. Nitrogen Adsorption with a Ca and/or Sr Exchanged Lithium X-Zeolite. US 5 152 813, 1992. |
[7] | Charles G C. Nitrogen Adsorption with a Divalent Cation Exchanged Lithium X-Zeolite. US 5 258 058, 1993. |
[8] | Sircar S, Conrad R R, Ambs W J. Binary Ion Exchange Type X Zeolite Adsorbent. US 4557736, 1985. |
[9] | Chao C C, Sherman J D, Mullhaupt J T, et al. Mixed ion Exchanged Zeolites and Processes for the Use thereof in Gas Separations. US 5174979, 1989. |
[10] | 关莉莉,蒋化,段连运,等.化学学报,2002,60(7):1235-1241. |
[11] | Satoshi Y, Shigeru H, Atsushi H, et al. Microporous and Mesoporous Materials, 2001, 46: 203-209. |
[12] | Yang R T, Kikkinides E S. AIChE J., 1995, 41(3): 509-517. |
[13] | Chen J P, Yang R T. Langmuir, 1995, 11(9): 3450-3456. |
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