在常压、110℃用浓LiOH水溶液和粉末TiO2(锐钛矿)反应的方法,合成了岩盐型LiTiO2,并采用TEM、XRD、XPS、TG/DTG等手段对岩盐型LiTiO2进行了表征.结果表明,采用该方法制得的岩盐型LiTiO2为纳米颗粒状的非化学计量物质,在≤500℃其晶型是稳定的,在室温下它有较强的吸水性.
参考文献
[1] | Tarascon J M,Armand M.Nature,2001,414:359-367. |
[2] | 李智敏,仇卫华,胡环宇,等(LI Zhi-Min,et al).无机材料学报(Journal of Inorganic Materials),2004,19(2):343-348. |
[3] | Natarajan C,Setoguchi K,Nogami G.Electrochim.Acta,1998,43:3371-3374. |
[4] | Duncan G R.New Scientist,London:New Science Publications,March 5,2005. |
[5] | Abrham K M.Electrochim.Acta,1993,38:1233-1248. |
[6] | Auborn J J,Barbero Y L.J.Electrochem.Soc.,1987,134:368-375. |
[7] | Huang S Y,Kavan L,Exnar I,et al.J.Electrochem.Soc.,1995,142:L142-L145. |
[8] | Bomino F,Busani L,Lazzani M,et al.J.Power Source,1981,6:261-270. |
[9] | 陈方,梁海潮,李仁贵,等(CEHN Fang,et al).无机材料学报(Journal of Inorganic Materials),2005,20(3):537-544. |
[10] | Ohzku T,Kodama T,Hirai T.J.Power Source,1985,14:153-166. |
[11] | Cava R J,Murphy D W,Zahurak S,et al.J.Solid State Chem.,1984,53:64-75. |
[12] | Kavan L,Grazel M,Gilbert S E,et al.J.Am.Chem.Soc.,1996,118:6716-6723. |
[13] | Luca V,Hanley T L,Roberts N K,et al.Chem.Mater.,1999,11:2089-2102. |
[14] | Wittingham M S,Dines M B.J.Electrochem.Soc.,1977,124:1387-1388. |
[15] | Zachau-Christiansen B,West K,Jacobsen T,et al.solid State Ionics,1988,28-30:1176-1182. |
[16] | Wagemaker M,Rvan de Krol,Kentgens A P M,et al.J.Am.Chem.Soc.,2001,123:11454-11461. |
[17] | Murphy D W,Cava R J,Zahurak S M,et al.Solid State Ionics,1983,9-10:413-418. |
[18] | Fattakhova D,Petrykin V,Brus J,et al.Solid State Ionics,2005,176:1877-1885. |
[19] | Fattakhova D,Krtil P.J.Electrochem.Soc.,2002,149:A1224-A1229. |
[20] | Li Junrong,Tang Zilong,Zhang Zongtai.Electrochem.Commun.,2005,7:894-899. |
[21] | Li Junrong,Tang Zilong,Zhang Zongtai.Electrochem.Commun.,2005,7:62-67. |
[22] | Zhou Yingke,Cao Lin,Zhang Feibao,et al.J.Electrochem.Soc.,2003,150:A1246-A1249. |
[23] | Lecerf A.Ann.Chim.[Paris],1962,7:513-535. |
[24] | Jiang K,Hu X,Sun H,et al.Chem.Mater.,2004,16:4324-4329. |
[25] | JCPDS No.72-1216. |
[26] | JCPDS No.16-0223. |
[27] | Wagner C D,Rigge W M,Davis L E,et al.Handbook of X-ray Photoelectron Spectroscopy,USA,1978. |
[28] | Sodergren S,Siegbahn H,Rensmo H,et al.J.Phys.Chem.B.,1997,101:3087-3090. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%