聚碳酸酯/TiO2超细纤维的制备与表征

无机材料学报, 2007, 22(3): 407-412. doi: 10.3321/j.issn:1000-324X.2007.03.006

聚碳酸酯/TiO2超细纤维的制备与表征

韩晓建 ^1, , 黄争鸣 ^2, , 何创龙 ^3, , 刘玲 ^4, , 董国华 ^5, , 吴庆生 ^6,

1.同济大学,航空航天与力学学院,上海,200092;安徽农业大学,轻纺工程与艺术学院,合肥,230036;同济大学,化学系,上海,200092

2.同济大学,航空航天与力学学院,上海,200092

3.东华大学,生物科学与技术研究所,上海,201620

4.同济大学,航空航天与力学学院,上海,200092

5.同济大学,航空航天与力学学院,上海,200092

6.同济大学,化学系,上海,200092

基金项目: 国家自然科学基金(10502038)

关键词：聚碳酸酯 , 复合超细纤维 , 抗菌性能

Preparation and Characterization of Polycarbonate/TiO2 Ultrafine Fibers

静电纺丝是一种有效制备超细纤维的重要方法.以钛酸丁酯作为TiO2前驱体实现了聚碳酸酯(PC)/TiO2的制备,采用TEM、SEM、红外光谱、X射线衍射等方法进行理化性能表征,并测试了材料的抗菌性能.结果表明:当PC与钛酸丁酯质量比为9∶1时电纺纤维尺寸较均匀,珠状物最少;7∶3时纤维膜对大肠杆菌的抗菌率达到87%左右,以期用于过滤膜、防护服及医疗纺织材料等领域.

参考文献

[1]	Huang Z M,Zhang Y Z,Kotaki M,et al.Composites Science and Technology,2003,63:2223-2253.
[2]	Loscertales I G,Barrero A,Guerrero I,et al.Science,2002,295:1695-1698.
[3]	覃小红,王善元.高科技纤维与应用,2004,29(2):28-32.
[4]	Gibson P W,Schreuder-Gibson H L,Riven D.AIChE J,1999,45 (1):190-195.
[5]	Gibson P W,Kendrick C,Rivin D,et al.J Coated Fabrics,1995,24:322-345.
[6]	Jeerapong Watthanaarun,Varong Pavarajarn,Pitt Supaphol.Science and Technology of Advanced Materials,2005,6:240-245.
[7]	Chong-Heng He,Jian Gong.Polymer Degradation and Stability,2003,81:117-124.
[8]	Viswanathamurthi P,Bhattarai N,Kim C K,et al.Inorganic Chemistry Communications,2004,7:679-682.
[9]	包定华,顾豪爽,黄桂玉,等(BAO Ding-Hua,et al).无机材料学报(Journal of Inorganic Materials),1996,11(3):453-458.
[10]	Schreuder-Gibson H,Gibson P,et al.Journal of Advanced Materials,2002,34:44-55.
[11]	Gibson P,Schreuder-Gibson H,et al.Colloids and Surface A:Physicochemical and Engineering Aspects,2001,187-188:469-481.
[12]	Zhang Y Z,Huang Z M,Xu X,et al.Chem Mater,2004,16 (18):3406-3409.
[13]	Loscertales I G,Barrero A,Guerrero I,et al.Science,2002,295:1695-1698.
[14]	Sun Z,Zussman E,Yarin A L,et al.Advanced Materials,2003,15 (22):1929-1932.
[15]	Li D,Xia Y.Nano Lett,2004,4 (5):933-938.
[16]	Loscertales I G,Barrero A,Marquez M,et al.J Am Chem Soc,2004,1265:5376 5377.
[17]	Lopez-Herrera J M,Barrero A,Lopez A,et al.J Areosol Sci,2003,34:535-552.
[18]	Xiao-Jian Han,Zheng-Ming Huang,Chuang-Long He,et al.Polym.Compos,2006,277:381-387.
[19]	Huang Z M,Zhang Y Z,Ramakrishna S,et al.Polymer,2004,45 (15):5361-5368.
[20]	Megelski S,Stephens J S,Chase D B,et al.Macromolecules,2002,35:8456-8466.
[21]	Jamila Shawon,Changmo Sung.Journa of Materials Science,2004,39:4605-4613.
[22]	Mit-uppatham C,Nithitanakul M,Supaphol P.Macromol.Chem.Physic,2004,205:2327-2338.
[23]	张嘉琪,郑嗣华,黄积淘(ZHANG Jia-Qi,et al).无机材料学报(Journal ofInorganic Materials),2006,21(3):719-724.
[24]	张峰,张歆(ZHANG Feng,et al).无机材料学报(Journal ofInorganic Materials),2006,21(5):1268-1272.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

聚碳酸酯/TiO2超细纤维的制备与表征

Preparation and Characterization of Polycarbonate/TiO2 Ultrafine Fibers

参考文献