聚合物/层状硅酸盐(PLS)纳米复合材料是一新兴复合材料,具有优异的性能,是当前材料科学的研究热点之一.本文作者首先简要概述了层状硅酸盐的结构及其表面修饰,其中LS的离子交换容量和插层剂的种类是制备PLS纳米复合材料的关键因素之一;然后介绍了PLS纳米复合材料的制备方法、微观结构及其特点,其主要制备方法是插层复合法,包括插层聚合法和聚合物插层法两种;最后展望了PLS纳米复合材料的发展、特性及应用.
参考文献
| [1] | 吴人洁.下世纪复合材料发展趋势[J].工程塑料应用,1999,27(2):28. |
| [2] | 曾清华,王栋知,王淀佐.聚合物-粘土矿物纳米复合材料[J].化工进展,1998,17(2):1. |
| [3] | 王昕,孙康宁,尹衍升,等.纳米复合陶瓷材料研究进展[J].复合材料学报,1999,16(1):105. |
| [4] | 王新宇,漆宗能,王佛松.聚合物/层状硅酸盐纳米复合材料制备及应用[J].工程塑料应用,1999,27(2):1. |
| [5] | Wang M S, Pinnavaia T J. Clay-polymer nanocomposites formed acidic derivatives of montmorillonite and an epoxy resin [J].Chem Mater, 1994,6(4): 468. |
| [6] | 乔放,李强,漆宗能,等.聚酰胺/粘土纳米复合材料的制备、结构表征及性能研究[J].高分子通报,1997,(3):135. |
| [7] | Burnside S D, Giannels E P. Synthesis and properties of new poly (dimethylsiloxane) nanocomposites[J]. Chem Mater,1995,7(9):1597. |
| [8] | 漆宗能,李强,周砚珠,等.一种聚酰胺/粘土纳米复合材料及其制备方法[P].中国发明专利:ZL96105362.3. |
| [9] | Yano K, Usuki A, Okada A, et al. Synthesis and properties of polyimide-clay hybrid[J]. J Polym Sci,A: Polym Chem, 1993,31:2493. |
| [10] | Usuki A, Mizutani T, Fukushima Y. Composite material containing a layered silicate[P].美国专利:US4889885,1989. |
| [11] | Vaia R A, Vasudevan S, Krawiec W, et al. New polymer electrolyte nanocomposites. Melt intercalation of poly (ethylene oxide) in mica-type silicates[J]. Adv Mater, 1995,7(2): 154. |
| [12] | Lan T, Pinnavaia T J. Clay-reinforced epoxy nanocomposites[J]. Chem Mater, 1994,6(12):2216. |
| [13] | Giannelis E P. Polymer layered silicate nanocomposites[J]. Adv Mater, 1996,8(1) :29. |
| [14] | Lan T,Kaviratna P D, Pinnavaia T J. Mechanism of clay tactoid exfoliation in epoxy-clay nanocomposites [J]. Chem Mater,1995,7(11) :2144. |
| [15] | Okada A, Kawasui M. Synthesis and characterization of a nylon6-clay hybrid[J]. Polym Prepr,1987,28(2) :447. |
| [16] | Kato C,Kuroda K, Takahara H, et al. Preparation and electrical properties of quaternary ammonium montmorillonite-polystyrene complex[J]. Clays Clay Miner,1981,29(4) :294. |
| [17] | Greenland D J. Adsorption of poly(vinyl alcohols) by montmorillonite [J]. J Colloid Sci, 1963,18(7): 647. |
| [18] | Vaia R A,Ishii Hope, Giannelis E P. Synthesis and properties of two-dimensional nanostructures by direct intercalation of polymer melts in layered silicates[J]. Chem Mater, 1993, 5 (12):1694. |
| [19] | Vaia R A,Tse Olivek, Giannelis E P. Intercalation method for preparation of polymer composites with layered silicates or clays[P].世界专利:WO9514733,1995. |
| [20] | 章永化,龚克成.聚合物/层状无机物纳米复合材料的研究进展[J].材料导报,1998,12(2):61. |
| [21] | 赵竹第,李强,欧玉春,等.尼纶6/蒙脱土纳米复合材料的制备、结构与力学性能的研究[J].高分子学报,1997,(5):519. |
| [22] | 王胜杰,李强,漆宗能,等.硅橡胶/蒙脱土复合材料的制备、结构与性能[J].高分子学报,1998,(2):149. |
| [23] | 王胜杰,李强,王新宇,等.聚苯乙烯/蒙脱土熔融插层复合的研究[J].高分子学报,1998,(2):129. |
| [24] | 王立新,蹇锡高,袁金凤,等.环氧树脂-蒙脱石纳米复合材料的制备与形成机理[J].大连理工大学学报,2000,40(6):681. |
| [25] | 王立新,袁金凤,张楷亮,等.环氧树脂/粘土纳米复合材料的制备及其固化动力学的研究[J].河北工业大学学报,2000,29(2).22. |
| [26] | Messersmith P B, Giannelis E P. Polymer-layered silicate nanocomposites: in situ intercalative polymerization of ε-caprolactone in layered silicates[J]. Chem Mater, 1993,5 (8):1064. |
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