为了深入了解复合材料固化过程的温度变化与微结构变化特征,设计了线热源加热的固化实验方法.采用SEM技术和3D温度采集系统考察了线加热条件下树脂体系的固化生长形态、微观结构的形成过程以及固化过程体系中的温度分布和变化规律.结果表明,线加热条件下形成的固化物表面微观形貌可以直观地反映均匀加热条件下树脂体系固化过程不同时刻体系微观形貌的形成历程.研究结果对理解复合材料热压成型过程中热传递方式、热应力与微观结构的形成机理具有一定的参考价值.
参考文献
[1] | Yarovsky E E. Computer simulation of structure and proper-ties of crosslinked polymers: Application to epoxy resins [J]. Polymer, 2002, 43: 963-969. |
[2] | Gu X,Raghavan D,Nguyen T,et al.Characterization of poly-ester degradation using tapping mode atomic force microscopy: Exposure to alkaline solution at room temperature [J]. Polymer Degradation and Stability, 2001, 74: 139-149. |
[3] | Chen J J, Zampini D, Walliser A. High-pressure epoxy-impr-egnated cementitious materials for microstructure characteri-zation [J]. Cement and Concrete Research, 2002, 32:1-7. |
[4] | Baillargeon Y,Vu-Khanh T.Prediction of fiber orientation and microstructure of woven fabric composites after forming [J]. Composites Structures, 2001, 52: 475-481. |
[5] | 隋刚, 张佐光, 李凤梅, 等. 增强纤维对环氧树脂基体电子束辐射固化过程及其固化度的影响研究 [J]. 复合材料学报, 2003, 20(2):1-6. |
[6] | Lazzaroni R, Leclere P, Couturiaux A, et al. Microstructure of block copolymers containing a conjugated segment as studied with atomic force microscopy [J]. Synthetic Metals, 1999, 102: 1279-1282. |
[7] | Kim Y B, Kim H K, Hong J W. Epoxy-acrylic microgels in electrodeposition coating films [J]. Surface and Coatings Technology, 2002, 153: 284-289. |
[8] | Hills B P, Mano J P, Destruel C. NMR Q-space microscopy of concentrated oil-in-water emulsions [J]. Magnetic Resonance Imaging, 2000, 18: 319-333. |
[9] | 金熹高, 朱世雄, 贾世军, 等. 多组分高聚物体系多层形态观察的新方法:激光共聚焦荧光显微技术 [J]. 化学通报, 1999(6): 34-39. |
[10] | 陈平,刘胜平. 环氧树脂 [M]. 北京:化学工业出版社,1999. 173-176. |
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