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通过两步法熔融共混工艺制备了具有核壳特征凹凸棒土(AT)/聚丙烯(PP)/聚碳酸酯(PC)三元复合材料.利用TEM观察复合体系的亚微相态.使用万能材料拉力机、冲击实验仪等手段测试了复合材料的力学性能,并对三元复合体系的增韧机理进行了探讨.结果表明,PC连续相中形成了以AT为核、PP为壳的分散相.这种核-壳结构特征相包容粒子对PC具有良好的增韧效果,且强度较PP/PC二元共混体系有所提高.结合冲击断面形貌的SEM分析,认为AT/PP/PC三元复合体系中的增韧机制主要是界面脱粘、空化作用和AT对分散相的增强作用.

参考文献

[1] Wu Souheng. Phase structure and adhesion in polymer blends:A criterion for rubber toughening [J]. Polym, 1985, 26(11): 1855-1863.
[2] Favis B D, Therriem D. Factors influencing structure formation and phase size in an immiscible polymer blend of polycarbonate and polypropylene prepared by twin-screw extrusion[J]. Polym, 1991, 32(8): 1474.
[3] LeBaron Peter C, Wang Zhen, Pinnavaia Thomas J. Polymer-layered silicate nanocomposites: An overview [J]. Applied ClayScience, 1999, 15(1): 11-29.
[4] 吕建坤,柯毓才,漆宗能,等.环氧树脂/粘土纳米复合材料的制备与性能研究[J].复合材料学报,2002,19(1):117-120.Lu Jiankun, Ke Yucai, Qi Zongneng, et al. Synthesis and mechanical properties of epoxy/clay nanocomposites [J]. Acta Materiae Compositae Sinica , 2002, 19(1) : 117-120.
[5] 周杰,刘宁,李云,等.凹凸棒石粘土的显微结构特征[J].硅酸盐通报,1999(6):50.Zhou Jie, Liu Ning, Li Yun, et al. Microscopic structure characteristics of attapugite [J]. Silicate Bulletin, 1999(6):50.
[6] Tian Ming, Qu Chengdong, Zhang Liqun, et al. Structure and properties of fibrillar silicate/SBR composites by direct blend process [J]. J Mater Sci, 2003, 38: 4917-4924.
[7] Du Zhongjie, Rong Junfeng, Li Hangquan, et al. Polyethylene/palygorskite nanocomposites with macromolecular comb structure via in situ polymerization [J]. J Mater Sci, 2003,38:4863-4868.
[8] Yoon P J, Humter D L, Paul D R. Polycarbonate nanocomposites Ⅱ : Degradation and color formation [J]. Polymer,2003, 44: 5341-5354.
[9] 戴兰宏,吴国璋.凹凸棒土增强增韧聚丙烯复合材料断裂韧性和断面分维的相关性[J].复合材料学报,1996,13(4):70-75.Dai Lanhong, Wu Guozhang. Relation between fracture toughness and fractal dimension of fracture surface for PP/AT composites [ J ]. Acta Materiae Compositae Sinica,1996, 13(4): 70-75.
[10] 王丽华,段丽斌,盛京.聚丙烯/凹凸棒土纳米复合材料结晶形态和形貌研究[J].高分子学报,2004,3:424427.Wang Lihua, Duan Libin, Sheng Jing. Study on crystallization and morphology of polypropylene/attaplugite nanocomposites [J]. Acta Polymer Sinica, 2004, 3: 424-427.
[11] 高翔,毛立新,金日光,等.凹凸棒土表面改性及其对聚丙烯力学性能的影响[J].塑料,2004,33(3):34-39.Gao Xiang, Mao Lixin, Jin Riguang, et al. Surface organic modification of attapugite and its effect on mechanical properties of polypropylene [J]. Plastics, 2004, 33(3): 34-39.
[12] 容敏智,章明秋,郑永祥,等.纳米SiO2增强增韧聚丙烯的界面效应与逾渗行为[J].复合材料学报,2002,19(1):1-4.Rong Minzhi, Zhang Mingqiu, Zheng Yongxiang, et al. Interfacial effects and percolation behavior in silica nanoparticles filled polypropylene composites [J]. Acta Materiae Compositae Sinica, 2002, 19(1): 1-4.
[13] Kayano K, Keskkula H , Paul D R. Fracture behaviour of some rubber toughened nylon6 blends [J]. Polymer, 1998,39(13): 2835-2845.
[14] Azimi H R, Pearson R A, Hertzberg R W. Fatigue of the hybrid epoxy composites: epoxies containing rubber and hollow glass spheres [J]. Polym Eng Sci, 1996, 36(18): 2352-2365.
[15] Li Zhong Ming, Yang Mingbo, Huang Rui, et al. Fibre formation based toughening in polycarbonate/polyethelene alloy compatibilized with diallyl bispbenol A ether grafted polyethylene [J]. J MaterSci, 2001, 36: 2013-2018.
[16] 冯威,毛立新,金日光,等.PPO/SEBS-g-MAH共混体系的"瞬间原位大取向"增韧模型[J].材料研究学报,2000,14(2):127-132.Feng Wei, Mao Lixin, Jin Riguang, et al. Impact fracture surface and microstructural deformation process of PPO/elastomeric styrene-based block copolymers blends [J]. Chin J Mater Res, 2000, 14(2): 127-132.
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