为深入研究复合材料界面特性,分析复合材料界面改性机理,采用原子力显微镜以力调制模式研究了单向碳纤维/聚芳基乙炔(CF/PAA)复合材料横截面的表面形貌和硬度,得到了材料中各相的形态、分布和相对硬度等信息.通过对硬度图像进行统计学分析得到材料表面硬度分布直方图,对不同方法改性后的复合材料界面相特性进行了分析和比较.研究表明,CF未经表面改性处理时,复合材料中无明显的界面相出现,氧化处理后界面上出现硬度变化区域,界面相结构变得复杂,氧化结合高碳酚醛涂层处理后可以获得更为完善的界面相,在纤维与基体间形成一个模量适中的过渡区域,使材料的界面力学性能显著提高.
参考文献
[1] | Katzman H A. Polyarylacetylene-matrix composites for solid rocket motor components [J]. J Advanced Materials, 1995(4): 21-27. |
[2] | 闫联生,姚冬梅,闫桂沈,等.碳布增强聚芳基乙炔新型防热材料[J].玻璃钢/复合材料,1999(5):20-23.Yan Liansheng, Yao Dongmei, Yan Guishen, et al. A new ablative material--Carbon cloth reinforced polyarylacetylene [J]. Fiber Reinforced Plastic/Composites, 1999 (5) :20-23. |
[3] | 张德雄,张衍.高温复合材料基体树脂聚芳基乙炔综述[J].固体火箭技术,2001,24(1):53-59.Zhang Dexiong, Zhang Yan. An overview of polyarylacetylene as the resin matrix for high temperature composites [J].Journal of Solid Rocket Technology, 2001, 24 (1): 53 -59. |
[4] | 焦扬声,庄元其.防热材料的新进展-芳基乙炔共聚物的碳纤维增强材料[J].玻璃钢/复合材料,1997(1):41-43.Jiao Yangsheng, Zhuang Yuanqi. New advance of heating resistance materials [J]. Fiber Reinforced Plastic/Composites, 1997(1): 41-43. |
[5] | 闫联生.酚醛改性聚芳基乙炔复合材料探索[J].玻璃钢/复合材料,2001(2):22-24.Yan Liansheng. Property improvement of polyarylacetylene matrix composites by phenolic resins [J]. Fiber Reinforced Plastic/Composites, 2001(2): 22-24. |
[6] | Fu H J, Huang Y D, Liu L. Influence of fibre surface oxidation treatment on mechanical interfacial properties of carbon fiber/polyarylacetylene composites [ J ]. Material Science and Technology, 2002, 20(11): 1654-1660. |
[7] | 刘丽,傅宏俊,黄玉东.碳纤维表面处理及其对碳纤维/聚芳基乙炔复合材料力学性能的影响[J].航空材料学报,2005,25(2):59-62.Liu Li, Fu Hongjun, Huang Yudong. Surficial modification for carbon fiber and its effect on the mechanical property of CF/PAA [J]. Journal of Aeronautical Materials, 2005,25(2): 59-62. |
[8] | 白春礼,田芳,罗克.扫描力显微术[M].北京:科学出版社,2000.Bai Chunli, Tian Fang, Luo Ke. Scanning force microscopy[M]. Beijing: Science Press, 2000. |
[9] | Munza M, Sturma H, Schulza E, et al. The scanning force microscope as a tool for the detection of local mechanical properties within the interphase of fibre reinforced polymers[J]. Composites Part A, 1998: 1251-1259. |
[10] | Radmacher Tillmann R W, et al. Imaging viscoelasticity by force modulation with the atomic force microscope [J]. Biophysical Journal, 1993, 64: 735-742. |
[11] | VanLandingham M R, Dagastine R R, Eduljee R F, et al.Characterization of nanoscale property variations in polymer composite system. Ⅰ : Experimental results [J]. Composites PartA, 1999, 30: 75-83. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%