采用凝胶浇注成型工艺制备了纳米碳管/羟基磷灰石复合材料坯体.研究了pH值、分散剂、固相含量(纳米碳管和羟基磷灰石在料浆中的质量分数)、分散工艺等因素对料浆和复合材料坯体性能的影响,对坯体的力学性能进行了测试,借助扫描电镜分析了坯体的微观组织.实验发现,料浆的pH值应控制在10~12的范围内;聚甲基丙烯酸铵的浓度为0.6%时,羟基磷灰石悬浮体流动性最好;十二烷基磺酸钠的浓度在SDS/CNTs=1%~2%时,纳米碳管/羟基磷灰石复相料浆的粘度最低;采用球磨法制备的复相料浆固相含量达到55%,复合材料坯体的抗弯强度达到57.403MPa.
参考文献
[1] | 郭颖,李玉宝.骨修复材料的研究进展[J].世界科技研究与发展,2001,23(1):33-37.Guo Ying,Li Yubao.The progress in biomaterials for the replacement of hand tissue[J].World Sci-Tech R & D,2001,23(1):33-37. |
[2] | Burg K J L,Porter S,Kellam J F.Biomaterial developments for bone tissue engineering[J].Biomaterials,2000,21(23):2347-2359. |
[3] | Wojciech S,Masahiro Y.Processing and properties of hydroxyapatite-based biomaterials for use as hard tissue replacement implants[J].J Mater Res,1998,13(1):94-117. |
[4] | 龚树生,汪吉宝,师洪,等.羟基磷灰石人工听骨的临床应用[J].同济医科大学学报,1996,25(6):467-469.Gong Shusheng,Wang Jibao,Shi Hong,et al.Clinical study of hydroxyapatitic ossicle in middle ear surgery[J].Acta Univ Med Tongji,1996,25(6):467-469. |
[5] | 程玉华,赵广军,刘海俊,等.胶原复合羟基磷灰石修复下颌骨缺损的组织学观察[J].中国修复重建外科杂志,1998,12(2):74-76.Cheng Yuhua,Zhao Guangjun,Liu Haijun,et al.Histological evaluation of collagen hydroxyapatite composite as osseous implants in the repair of mandibular defect[J].Chinese J Reparative and Reconstructive Surgery,1998,12(2):74-76. |
[6] | 刘治,陈晓红,宋怀河.碳纳米管及其研究进展[J].化工新型材料,2002,30(4):1-4.Liu Zhi,Chen Xiaohong,Song Huaihe.Carbon nanotube and its development[J].New Chemical Materials,2002,30(4):1-4. |
[7] | Havashida T,Pan L,Nakayama Y.Mechanical and electrical properties of carbon tubule nanocoils[J].Physica B,2002,323 (1/4):352-353. |
[8] | 李爱民,孙康宁,董维芳,等.烧结工艺对碳纳米管/羟基磷灰石复合材料力学性能与微观结构的影响[J].人工晶体学报,2004,33(4):624-628.Li Aimin,Sun Kangning,Dong Weifang,et al.Influence of sintering technique on mechanical properties and microstructure of CNTs/HAp composite[J].Journal of Synthetic Crys tals,2004,33(4):624-628. |
[9] | Ogbemi O O,Mark A J,Richard A S.Gel-casting:A new ceramic forming process[J].Ceramic Bulletin,1991,70(10):1641-1849. |
[10] | 王浚,高濂,孙静.Y-TZP悬浮液的界面吸附特性[J].无机材料学报,1999,14(5):757-762.Wang Jun,Gao Lian,Sun Jing.Interface adsorption properties of Y-TZP aqueous suspensions[J].Journal of Inorganic Materials,1999,14(5):757-762. |
[11] | 刘阳桥,高濂,郭景坤.丙烯酸类共聚物在纳米Y-TZP上的等温吸附研究[J].无机材料学报,2001,16(4):635-640.Liu Yangqiao,Gao Lian,Guo Jingkun.Isotherm adsorption of acrylic acid/acrylate ester copolymers on nanosized Y-TZP powders[J].Journal of Inorganic Materials,2001,16 (4):635-640. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%