借助于几何概率中的一些相关理论,从理论分析的角度,对表面为凸形曲线或曲面的二维和三维任意形状粒子建立了表观界面过渡区厚度统计平均值和实际界面过渡区厚度之间的定量关系.结果表明,对于二维凸形粒子,截面分析法所得的表观界面过渡区厚度的统计平均值与实际界面过渡区厚度之间的比值小于π/2.精确比值与粒子的形状有关.如果实际界面过渡区厚度与粒子的尺寸相比可以忽略的话,截面分析法所得的表观界面过渡区厚度的统计平均值与实际界面过渡区厚度之间的比值约等于π/2.对于三维凸形粒子,截面分析法所得的表观界面过渡区厚度的统计平均值与实际界面过渡区厚度之间的比值小于2,比值的精确解与粒子的形状有关.如果实际界面过渡区厚度与粒子的尺寸相比可以忽略的话,截面分析法所得的表观界面过渡区厚度的统计平均值与实际界面过渡区厚度之间的比值约等于2.
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