在不加任何引发剂和金属还原剂的条件下,超声辐射双原位引发乳液聚合制备纳米银镓合金/聚甲基丙烯酸甲酯(Ag-Ga/PMMA)复合粒子.利用HREM、EDS、XRD等对复合粒子进行了分析,表明所制得的乳胶粒子具有典型的核壳结构,粒径为80～200 nm,分布均匀,单分散性好,基本没有出现团聚.乳胶粒子中成壳部分的聚合物产生了一层层有序组装的现象.XRD证明,有纳米合金Ag0.72Ga0.28存在;此外还出现了2个新的衍射峰,推断可能是新的银镓合金物质.
参考文献
| [1] | 徐国财,张立德.纳米复合材料[M].北京:化学工业出版社,2002:249-310.Xu Guocai,Zhang Lide.Nanocomposite materials[M].Beijing:Chemical Industry Press,2002:249-310. |
| [2] | 张立德,牟季美.纳米材料和纳米结构[M].北京:科学出版社,2001:345-355.Zhang Lide,Mou Jimei.Nanomaterial and nanostructure[M].Beijing:Science Press,2001:345-355. |
| [3] | Nicolais Luigi,Carotenuto Gianfranco.Metal-polymer nanocomposite[M].New York:John Wiley & Sons,Inc,2005:155-185. |
| [4] | Shingu P H,Huang B,Nishitani S R,et al.Nano-meter order cystalline structures Al-Fe alloys produced by mechanical alloyings[J].Suppl Trans Japan Inst Metals,1988,29(3):3-10. |
| [5] | Jung Choong-Hwan,Lee Hee-Gyoun,Kim Chan-Joong,et al.Synthesis of Cu-Ni alloy powder directly from metal salts solution[J].Journal of Nanoparticle Research,2003,5(3/4):383-388. |
| [6] | Kobayashi Yoshio,Horie Mitsuru,Nagao Daisuke,et al.Preparation of silica-coated Co-Pt alloy nanoparticles[J].Materials Letters,2006,60(16):2046-2049. |
| [7] | Matsumura Hideo,Shimoe Saiji,Nagano Kiyoshi,et al.Effect of noble metal conditioners on bonding between prosthetic composite material and silver-palladium-copper-gold alloy[J].The Journal of Prosthetic Dentistry,1999,81 (6):710-714. |
| [8] | Rao J C,Song M,Furuya K,et al.TEM study of Mg-Zn precipitates in Mg-Zn Y alloys[J].Journal of Materials Science,2006,41(9):2573-2576. |
| [9] | Mandal Madhuri,Kundu Subrata,Sau Tapan K,et al.Synthesis and characterization of superparamagnetic Ni-Pt nanoalloy[J].Chem Mater,2003,15(19):3710-3715. |
| [10] | Huang Shengyang,Chang Shumin,Yeh Chuin-Tih.Characterization of surface composition of platinum and ruthenium nanoalloys dispersed on active carbon[J].J Phys Chem B,2006,110(1):234-239. |
| [11] | Teng Xiaowei,Yang Hong.Synthesis of face-centered tetragonal FePt nanoparticles and granular films from Pt@ Fe2O3 core-shell nanoparticles[J].J Am Chem Soc,2003,125(47):14559-14563. |
| [12] | 廖勇勤,王琪,王良文.超声辐照引发MMA微乳液聚合[J].高等学校化学学报,2001,22(7):1237-1240.Liao Yongqin,Wang Qi,Wang Liangwen.Ultrasonic induced microemulsion polymerization of MMA[J].Chemical Journal of Chinese Universities,2001,22(7):1237-1240. |
| [13] | 熊金钰,徐国财,吉小利,等.纳米银的超声合成及分形研究[J].安徽理工大学学报:自然科学版,2004,24(3):69-72.Xiong Jinyu,Xu Guocai,Ji Xiaoli,et al.Synthesis of nanosilver and its fractal by ultrasound[J].Journal of Anhui University of Science and Technology:Natural Science,2004,24(3):69-72. |
| [14] | 徐国财,王贞平,熊金钰,等.纳米镓/聚甲基丙烯酸甲酯复合材料的原位超声合成与表征[J].现代化工,2006,26(2):37-40.Xu Guocai,Wang Zhenpin,Xiong Jinyu,et al.In-situ ultrasonic preparation of nano-Ga/PMMA composites and characterization of it[J].Modern Chemical Industry,2006,26(2):37-40. |
| [15] | 杨强,王立,向卫东,等.金属纳米粒子/聚合物体系的稳定性及其机理[J].化学进展,2006,18(2/3):290-297.Yang Qiang,Wang Li,Xiang Weidong,et al.Stabilization and its mechanism of the metal nanoparticles/polymer systems[J].Progress in Chemistry,2006,18(2/3):290-297. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%