欢迎登录材料期刊网

材料期刊网

高级检索

以偏氟乙烯-三氟乙烯(P(VDF-TrFE))共聚物为基体,锆钛酸铅(PZT)铁电颗粒为功能相,钽铌酸钾(KTN)颗粒为增强相,制备了0-3型(PZT,KTN)/P(VDF-TrFE)三相铁电复合材料.利用SEM及EDAX技术,分析了复合材料的显微结构及PZT和KTN相的分布.测试了具有不同KTN体积分数的复合材料的电性能.实验结果表明:PZT和KTN相的颗粒分布均匀,存在少量的团聚体;随KTN体积分数的增加,三相复合材料的极化漏电流Ⅰ、介电常数εr和介电损耗tan δ增加,压电系数d33降低,而热释电系数P3先增加后降低,但其d33和P3均高于具有相同PZT体积分数的PZT/P(VDF-TrFE)两相复合材料.

参考文献

[1] Dias C J,Igreja R,Marat-Mendes R,et al.Recent advances in ceramic-polymer composite electrets[J].IEEE Transactions on Dielectrics and Electrical Insulation,2004,11(1):35-40.
[2] 党智敏,王海燕,王岚.新型高温高介无机/有机功能复合材料[J].复合材料学报,2005,22(5):9-15.Dang Zhimin,Wang Haiyan,Wang Lan.New inorganic/organic functional composites with high temperature and high dielectric constant[J].Acta Materiae Compositae Sinica,2005,22(5):9-15.
[3] Waller D,lqbal T,Safari A.Poling of lead zirconate titanate ceramics and flexible piezoelectric composites by the corona discharge technique[J].J Am Ceram Sci,1989,72(3):322-324.
[4] 高峰,杨祖培,刘向春,田长生.铁电陶瓷/铁氧体复合材料的相结构与介电性能[J].复合材料学报,2004,21(5):22-27.Gao Feng,Yang Zupe,Liu Xiangchun,Tian Changsheng.Phase structure and dielectric properties of ferroelectfics and ferrite mixed composites[J].Acta Materiae Compositae Sinica,2004,21(5):22-27.
[5] Sakamoto W K,Marin-Franch P,Das-Gupta D K.Characterization and application of PZT/PU and graphite doped PzT/Pu composite[J].Sensors and Actuators A,2002,100(2/3):165-174.
[6] Lam K S,Wong Y W,Tai L S,et al.Dielectric and pyroelectric properties of lead zirconate titanate/polyurethane composites[J].J Appl Phys,2004,96(7):3896-3899.
[7] Wong C K,Shin F G.Electrical conductivity enhanced dielectric and piezoelectric properties of ferroelectric 0-3composites[J].J Appl Phys,2005,97(6):064111-1-9.
[8] Zhang Duanming,Nian Wei,Yang Fengxia,et al.A new comprehensive model for the pyroelectric property of 0-3 ferroelectric composites[J].J Phys D:Appl Phys,2006,39(9):1963-1969.
[9] Zhong Zhicheng,Zhang Duanming,Han Xiangyun,et al.Hydrothermal and solvothermal preparation of nanocyrstalline KTN power[J].Journal of Inorganic Materials,2007,22(1):45-48.
[10] Ng K L,Wa H L,Choy C L.Piezoelectric and pyroelectric properties of PZT/P(VDF-TrFE)composites with constituent phase poled in parallel or antiparallel directions[J].IEEE Trans Ultrason Ferroelectr Freq Control,2000,47(6):1308-1315.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%