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为研究短切碳纤维含量和温度对导电复合材料渗流行为的影响,通过Landau相变理论导出了复合材料电导率与填料体积分数及温度的方程,并用该方程分析了短切碳纤维/乙烯基酯树脂复合材料的渗流和PTC行为.结果表明:复合材料的渗流阈值随温度升高而增加,PTC温度随碳纤维含量增加而上升.当温度由24.6℃上升到108.4℃时,其渗流阈值的理论值由1.06%增加到1.60%;当碳纤维体积分数由3.1%增加到4.6%时,其PTC温度的理论值由120℃上升到170℃.复合材料渗流阈值和PTC温度理论值与实验值符合得很好.

参考文献

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