色谱 , 2001, 19(5): 385-389. doi: 10.3321/j.issn:1000-8713.2001.05.001
流动相组成、浓度和pH对蛋白质在金属螯合柱上的保留特性的影响
李蓉 1, , 邸泽梅 {"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"在较低的转速下(720 r/min),将磁力搅拌和超声方法结合,制备煤油-Span80-NaOH乳化液膜,在较温和条件下制备了稳定性较高的乳化液膜.将制备的乳化液膜应用于1-萘酚废水溶液的处理.系统考察了液膜制备过程的影响因素,如NaOH浓度、超声时间、油内比等;废水处理的操作条件:外水相pH、接触时间和乳水体积比等因素对1-萘酚的去除效果.结果表明,NaOH浓度为2％、超声时间为5 min、油内比为1∶2、无需调节pH、接触时间为15min、乳水比为1∶5时,1-萘酚去除率可高达94％.","authors":[{"authorName":"胡萌晓","id":"6a1fa7b6-fcbb-4206-87ab-52ebfad9a764","originalAuthorName":"胡萌晓"},{"authorName":"乔楠楠","id":"06bf80fb-a773-488a-81a2-bcd788cf9904","originalAuthorName":"乔楠楠"},{"authorName":"常嘉丽","id":"d917a16c-bc51-4b0c-901d-70ef71d2c67a","originalAuthorName":"常嘉丽"},{"authorName":"张朵朵","id":"3ecff011-8981-4133-9e9d-22d01498dfa1","originalAuthorName":"张朵朵"},{"authorName":"马红竹","id":"8ec14d1f-4bce-4482-8006-5ee8d6d9d8f0","originalAuthorName":"马红竹"}],"doi":"10.16159/j.cnki.issn1007-8924.2015.02.017","fpage":"93","id":"f7f8dc10-c4fa-4728-85b5-8d7d41880164","issue":"2","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术 "},"keywords":[{"id":"cc1abf96-c29b-4516-8c8d-5404f7eefa5f","keyword":"1-萘酚","originalKeyword":"1-萘酚"},{"id":"15f0ecb0-0b79-4d16-a6d8-7bde67bbfb29","keyword":"乳化液膜法","originalKeyword":"乳化液膜法"},{"id":"cf340772-ec01-411d-93d0-e458464831ad","keyword":"超声","originalKeyword":"超声"}],"language":"zh","publisherId":"mkxyjs201502017","title":"乳化液膜的制备及其在1-萘酚废水处理中的实验研究","volume":"35","year":"2015"},{"abstractinfo":"首先采用种子生长法合成了形状规整的金纳米棒(AuNRs),再采用3-丁烯酸对AuNRs表面进行改性,最后通过种子沉淀聚合法将聚(N-异丙基丙烯酰胺)(PNIPAM)包覆在AuNRs表面,制备了以AuNR为核、交联的PNIPAM为壳层的核壳结构型温度刺激响应性杂化微凝胶.以此杂化微凝胶作为表面增强拉曼光谱(SERS)的基底,升高温度使杂化微凝胶发生体积相转变,能检测到以常规纳米金属材料为基底难以检测的1-萘酚(1-NOH)水溶液的SERS信号.并且,随着温度从5℃升高到55℃,1-NOH的SERS信号逐渐增强.这是由于杂化微凝胶发生温度变化刺激的体积相转变过程中,可捕捉水溶液中溶解的微量1-NOH,使其富集在杂化微凝胶内部.","authors":[{"authorName":"刘晓云","id":"2e4bfda3-d602-4407-9392-d22442f3a98d","originalAuthorName":"刘晓云"},{"authorName":"邹先波","id":"37f87395-1e87-4227-9a46-394f3f12a257","originalAuthorName":"邹先波"},{"authorName":"董旭","id":"fb8b84bd-6dab-40f3-a0a4-b2194b4ffda5","originalAuthorName":"董旭"},{"authorName":"杨建茂","id":"386887e0-e702-4a68-844c-a3ecd00e993f","originalAuthorName":"杨建茂"},{"authorName":"张莉","id":"36e1ca48-3443-492c-b91c-08f12c74a1ea","originalAuthorName":"张莉"},{"authorName":"查刘生","id":"0cec4e5f-4850-40eb-8b37-9c8d6656f833","originalAuthorName":"查刘生"}],"doi":"","fpage":"163","id":"add3421d-9607-4813-bd35-737c42cea6a4","issue":"5","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"bad9778c-a7bb-40fa-913b-be3708d72ad8","keyword":"金纳米棒","originalKeyword":"金纳米棒"},{"id":"8a0a6002-b117-4d38-98c8-e945635cec04","keyword":"聚(N-异丙基丙烯酰胺)","originalKeyword":"聚(N-异丙基丙烯酰胺)"},{"id":"d5a17dfa-896c-4802-b28a-97711eca4e35","keyword":"温度刺激响应性","originalKeyword":"温度刺激响应性"},{"id":"e04c45fb-ff41-4c1d-a5fa-f97b783f2ef6","keyword":"表面增强拉曼光谱","originalKeyword":"表面增强拉曼光谱"},{"id":"cc6b797f-b59a-4528-b8aa-7271a84f25a8","keyword":"基底","originalKeyword":"基底"},{"id":"7cb30357-b9b4-4afc-a6fc-05b6fbea475f","keyword":"1-萘酚","originalKeyword":"1-萘酚"}],"language":"zh","publisherId":"gfzclkxygc201405035","title":"载金纳米棒温度刺激响应性杂化微凝胶的制备及在SERS基底中的应用","volume":"30","year":"2014"},{"abstractinfo":"研究了硫酸铵-1-(2-吡啶偶氮)-2-萘酚-磺酸-Tween 80体系萃取铁的行为.试验表明,当溶液pH 2.0～4.0,能使Fe(Ⅱ)与Zn(Ⅱ),Cd(Ⅱ),Mn(Ⅱ),Mg(Ⅱ),A(Ⅲ)定量分离.应用该法测定了铝合金中Fe的含量,结果满意.","authors":[{"authorName":"胡瑞定","id":"a3ff4f0e-1d95-44f8-89d0-8b997f9fda4c","originalAuthorName":"胡瑞定"},{"authorName":"林秋月","id":"74399c7b-ab4e-45ab-b855-15189a6a87de","originalAuthorName":"林秋月"},{"authorName":"陈建荣","id":"9585971f-d726-473f-ab63-bb4e8a9a86f1","originalAuthorName":"陈建荣"}],"doi":"10.3969/j.issn.1000-7571.2000.01.006","fpage":"17","id":"416a1e3a-6074-4816-86c0-2d2a290ea89e","issue":"1","journal":{"abbrevTitle":"YJFX","coverImgSrc":"journal/img/cover/YJFX.jpg","id":"71","issnPpub":"1000-7571","publisherId":"YJFX","title":"冶金分析 "},"keywords":[{"id":"62f09265-d304-4919-a894-321c5b49d0e8","keyword":"液固萃取","originalKeyword":"液固萃取"},{"id":"caf15ebf-6e4d-4b46-8a9c-2bc35157f182","keyword":"分离","originalKeyword":"分离"},{"id":"c3650b43-6924-40e9-8fd3-7564a453f2c8","keyword":"铁","originalKeyword":"铁"},{"id":"d74b4065-8b0f-41b7-8418-a9f65da9a116","keyword":"1-(2-吡啶偶氮)-2-萘酚-磺酸","originalKeyword":"1-(2-吡啶偶氮)-2-萘酚-磺酸"}],"language":"zh","publisherId":"yjfx200001006","title":"硫酸铵-1-(2-吡啶偶氮)-2-萘酚-磺酸-Tween 80体系萃取分离铁","volume":"20","year":"2000"},{"abstractinfo":"以1-亚硝基-2-萘酚为萃取剂, 以90℃熔融萘作稀释剂萃取痕量钯 (Ⅱ), 萘相中钯经氯仿溶解后用光度法测定其含量. 实验条件下络合物能从pH=0.8～11.0范围内定量萃入萘中, 络合物波长λmax=440 nm, 摩尔吸光系数ε440=2.41×104 L.mol-1.cm-1, 组成比Pd∶HR=1∶2, 萃取反应平衡常数Kex=6.31×1011. 钯量在0.48～34 μg/10 ml范围内符合朗伯-比耳定律, 检测限为0.044 μg/10 ml. 同时确定了光度法测定的最佳条件及常见阴阳离子的干扰允许量. 利用该法进行合成样与实际样中钯含量的测定, 结果满意.","authors":[{"authorName":"王碧","id":"6c7cf210-e969-472c-9ad2-23bee16582fa","originalAuthorName":"王碧"},{"authorName":"范海燕","id":"d8e0b904-34d7-46cc-bfae-a36c34d3e9d1","originalAuthorName":"范海燕"},{"authorName":"高锦章","id":"05ebbd29-b038-4e4c-bd8b-dc1767461772","originalAuthorName":"高锦章"},{"authorName":"杨武","id":"d89c8a46-1ad2-4bdd-a137-e923c3b0c1fc","originalAuthorName":"杨武"},{"authorName":"郭效军","id":"742bd2ed-701a-46c6-a849-0e13a6f43dfa","originalAuthorName":"郭效军"},{"authorName":"康敬万","id":"f8e09c8c-b5cf-48ac-8b5c-629184592b41","originalAuthorName":"康敬万"}],"doi":"10.3969/j.issn.0258-7076.1998.05.007","fpage":"350","id":"7a0ae964-0a42-4701-8349-fe795fd65bd6","issue":"5","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"c726877e-0a5e-4234-b221-8c3248c2e54f","keyword":"固-液萃取光度法","originalKeyword":"固-液萃取光度法"},{"id":"dcfe064d-0e2f-4ffe-87c7-d766c2d35acc","keyword":"钯","originalKeyword":"钯"},{"id":"308f7974-e740-4ee1-b002-5fe8c0304295","keyword":"1-亚硝基-2-萘酚","originalKeyword":"1-亚硝基-2-萘酚"}],"language":"zh","publisherId":"xyjs199805007","title":"1-亚硝基-2-萘酚固-液萃取光度法测定贵金属钯","volume":"22","year":"1998"},{"abstractinfo":"合成了新显色剂1-[(4,6-二甲基-2-嘧啶)偶氮]-2- 萘酚(DMPAN),并研究了该试剂的性质及其与钴显色反应的条件.结果表明:试剂的离解常数pka＝7.4,λmax＝374.0nm,在pH 6.22的磷酸盐缓冲介质中,试剂与钴形成红色1∶1络合物,其最大吸收波长λmax＝426nm,络合比Co2+∶R＝1∶1,摩尔吸光系数ε＝2.66×104,钴量在0～1.2μg/mL范围内遵守比尔定律,在掩蔽剂作用下,可不经分离直接用于含钴样品的分析,结果满意.","authors":[{"authorName":"蒋华江","id":"af28c5f0-e057-45fe-bb89-44824c54cc42","originalAuthorName":"蒋华江"},{"authorName":"叶巧云","id":"68cfcfa7-6696-419a-9722-12d4195af3b0","originalAuthorName":"叶巧云"},{"authorName":"孙芳","id":"9a682235-c183-4ba2-9013-95b4fbb982e4","originalAuthorName":"孙芳"}],"doi":"10.3969/j.issn.1000-7571.2000.03.007","fpage":"20","id":"cca1599d-7670-4e36-96ae-9b688d0b0d08","issue":"3","journal":{"abbrevTitle":"YJFX","coverImgSrc":"journal/img/cover/YJFX.jpg","id":"71","issnPpub":"1000-7571","publisherId":"YJFX","title":"冶金分析 "},"keywords":[{"id":"cdf41b7c-bbf9-4c5c-84ed-e232218b14f1","keyword":"钴","originalKeyword":"钴"},{"id":"ae5fe848-3a1b-43a9-bd31-42aaa4991315","keyword":"分光光度法","originalKeyword":"分光光度法"},{"id":"0dab4237-a204-4a7e-8ca5-f4d2e18d151c","keyword":"1-[4,6-二甲基-2-嘧啶)偶氮]-2- 萘酚","originalKeyword":"1-[4,6-二甲基-2-嘧啶)偶氮]-2- 萘酚"}],"language":"zh","publisherId":"yjfx200003007","title":"1-[(4,6-二甲基-2-嘧啶)偶氮]-2-萘酚的合成及其与钴(II)的显色反应","volume":"20","year":"2000"},{"abstractinfo":"运用循环伏安法(CV)和紫外可见光谱法(UV)研究了N,N-(2-羟基-1-萘酚醛)-2,6-二亚胺吡啶合Co(Ⅱ)配合物([Co(BHNP)]2+)及其与DNA相互作用. 结果表明,随DNA浓度增大,配合物的氧化峰电位Ep正移,氧化峰电流Ip降低;最大吸收波长红移,吸光度值降低. 结果表明,配合物与DNA发生较强的相互作用. 采用电化学方法得到配合物与DNA形成结合物的结合位点m=0.966,结合常数β=3.05×104 L/mol. 进一步运用紫外可见光谱法计算得出的值与电化学法所得结果基本相吻合. 同时利用DNA与配合物作用形成结合物导致Ip降低,且峰电流降低值在2.0×10-5 ~1.0×10-3 mol/L范围内与DNA浓度呈线性关系,其中线性方程为ΔIp(μA)=5.516 1×103cDNA(mol/L)+0.253 1,R=0.996 0. 是一种简单、快速的DNA电化学测定方法. 对模拟样品进行测定,结果满意.","authors":[{"authorName":"王梅","id":"ebaf61ae-718d-456b-ae18-b09335797ff4","originalAuthorName":"王梅"},{"authorName":"侯林荣","id":"74e42cdd-f38e-4f6d-8e50-a38e094fa092","originalAuthorName":"侯林荣"},{"authorName":"高作宁","id":"329a36c0-1527-44af-a4c1-183d4ef782d6","originalAuthorName":"高作宁"},{"authorName":"杨天林","id":"f23282ad-1e60-4843-a959-39c0c8666e92","originalAuthorName":"杨天林"}],"doi":"10.3969/j.issn.1000-0518.2008.10.014","fpage":"1186","id":"d31b7164-fc48-46af-918c-63354d124a9a","issue":"10","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"3e89dc3c-2352-4106-acf2-27b549f7aa08","keyword":"N","originalKeyword":"N"},{"id":"934f580a-d76e-4265-a771-a904d59b3369","keyword":"N-(羟基萘酚醛)二亚胺吡啶合Co(Ⅱ)配合物","originalKeyword":"N-(羟基萘酚醛)二亚胺吡啶合Co(Ⅱ)配合物"},{"id":"7a4a0d01-87c4-49f6-9fa8-f33f9e7eb5cb","keyword":"DNA","originalKeyword":"DNA"},{"id":"dc92e580-5180-4f98-81a1-26f301e7d4cb","keyword":"电化学","originalKeyword":"电化学"},{"id":"ab5e480a-f343-457d-9db3-dfc795abf61d","keyword":"紫外可见吸收光谱","originalKeyword":"紫外可见吸收光谱"}],"language":"zh","publisherId":"yyhx200810014","title":"N,N-(2-羟基-1-萘酚醛)-2,6-二亚胺吡啶合Co(Ⅱ)配合物与DNA相互作用的电化学和紫外可见光谱","volume":"25","year":"2008"},{"abstractinfo":"以(R)-(+)-1,1′-联-2-萘酚为模板分子,4-乙烯基吡啶为功能单体合成了分子印迹聚合物,将其作为高效液相色谱的固定相,研究其手性识别特性.对该固定相的手性拆分的色谱条件进行了优化.实验结果表明,合成的印迹聚合物对(R)-(+)-1,1′-联-2-萘酚具有较强的亲和力和特定的选择性,能有效拆分1,1′-联-2-萘酚对映体,分离因子最高达到12.25.通过优化色谱条件,该分子印迹聚合物还能对与1,1′-联-2-萘酚结构相似的衍生物5,6,7,8,5′,6′,7′,8′-八氢-1,1′-联-2-萘酚和1,1′-联萘-2-氨基-2′-酚进行手性拆分,分离因子分别达到1.51和2.40.","authors":[{"authorName":"李丽虹","id":"c0c3a419-1da2-4712-ad78-a70d47355e08","originalAuthorName":"李丽虹"},{"authorName":"刘岚","id":"055b811b-1650-474e-a286-7c9de550e224","originalAuthorName":"刘岚"},{"authorName":"罗勇","id":"c4c5ddcb-fdd5-4f2f-9232-74cbe5c7d617","originalAuthorName":"罗勇"},{"authorName":"邓芹英","id":"c87f5d79-ccf7-49bc-a3df-0160157584e7","originalAuthorName":"邓芹英"}],"doi":"10.3321/j.issn:1000-8713.2006.06.008","fpage":"574","id":"8bb977b6-9f0b-4bce-8235-c12bc7bc1cf5","issue":"6","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"f4efd9cc-672e-46c3-ad04-8b71aedf2800","keyword":"分子印迹聚合物","originalKeyword":"分子印迹聚合物"},{"id":"4eedefa6-0df0-456e-a8d7-75284a3e063a","keyword":"高效液相色谱","originalKeyword":"高效液相色谱"},{"id":"4f8926f8-a37e-4eb3-bdd1-f733feae5a9d","keyword":"联萘酚","originalKeyword":"联萘酚"},{"id":"6a57fbef-ffb5-4b23-9748-daa0e6e0c2a5","keyword":"手性拆分","originalKeyword":"手性拆分"}],"language":"zh","publisherId":"sp200606008","title":"以分子印迹聚合物为固定相手性拆分1,1′-联-2-萘酚及其衍生物","volume":"24","year":"2006"},{"abstractinfo":"以铁卟啉为催化剂在碱性甲醇溶液中,可用H2O2将α-或β-萘酚高选择性氧化为2-羟基-1，4-萘醌（HNQ),最高产率达57%.产物用IR,UV-Vis,MS,NMR,熔点测定和元素分析等方法表征.采用气相色谱法对催化体系监测,证明产物纯度为95%.在碱性水溶液中,利用HNQ在452nm的特征吸收,建立了UV-Vis定量分析产物的方法,探讨了NaOH浓度对HNQ吸收值的影响,测定了共存物的干扰量.","authors":[{"authorName":"阎雁","id":"0266ce75-e961-43a3-bca0-0b4dff794c35","originalAuthorName":"阎雁"},{"authorName":"郑国栋","id":"793863ad-9305-4ac7-8496-3b3dc7226992","originalAuthorName":"郑国栋"},{"authorName":"陈玉琴","id":"87d59772-07d9-4bf9-9182-eb29f717d951","originalAuthorName":"陈玉琴"},{"authorName":"甄开吉","id":"5633bc8b-b03a-49ae-93ce-762e8cc1cfa6","originalAuthorName":"甄开吉"},{"authorName":"方赤光","id":"00d194d2-46f0-47dd-ba96-d3500464742f","originalAuthorName":"方赤光"},{"authorName":"王岙","id":"0cacc7df-9a82-493f-82c7-3f5f9f0e1edf","originalAuthorName":"王岙"},{"authorName":"李青","id":"faa64231-5d1c-45e3-82c0-5f81e3d4b7b9","originalAuthorName":"李青"},{"authorName":"常新","id":"49bdb08a-8537-4869-853f-d01f3a5a6dfa","originalAuthorName":"常新"}],"doi":"10.3969/j.issn.1000-0518.2001.01.008","fpage":"29","id":"e0190ae2-4b9d-4bf1-a67b-0025a5844646","issue":"1","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"5b99bb3b-3669-4eeb-a93d-9d657f90a9a0","keyword":"萘酚","originalKeyword":"萘酚"},{"id":"d17053a2-4a12-41e5-83ef-70b4751bd7d1","keyword":"催化氧化","originalKeyword":"催化氧化"},{"id":"ad15f7a2-21ae-46be-b1fa-b79da82c473f","keyword":"铁卟啉","originalKeyword":"铁卟啉"},{"id":"86e64735-a5e7-488d-9598-d3dd9f1ccebd","keyword":"羟基萘醌","originalKeyword":"羟基萘醌"}],"language":"zh","publisherId":"yyhx200101008","title":"铁卟啉催化氧化萘酚合成2-羟基-1,4-萘醌","volume":"18","year":"2001"},{"abstractinfo":"乙酸(1-二茂铁基乙基)酯(记为配体2)与1-异丙基咪唑经过季铵化反应,制备出具有大空间位阻和富电子的配体1-(1二茂铁基乙基)-3-异丙基-1-咪唑碘盐(记为配体1),收率为88％.利用1H NMR、13C NMR对其结构进行了表征,并进一步考察了体系Pd (OAc)2/配体1催化4-甲氧基溴苯与苯硼酸的Suzuki-Miyaura偶联反应活性.实验发现:配体1在催化反应过程中可以有效地稳定Pd,在二氧六环反应介质中,碳酸铯为碱,1％Pd用量的条件下可以有效催化Suzuki Miyaura偶联反应,加热回流3h,收率达93％.","authors":[{"authorName":"段书德","id":"3d744794-64d4-4765-875d-2a32be87522b","originalAuthorName":"段书德"},{"authorName":"于宏伟","id":"359e3cc7-05c3-4e17-8b8a-c9367543d2be","originalAuthorName":"于宏伟"},{"authorName":"韩卫荣","id":"e0f1a44e-9139-4b20-99e1-4115b8adc4ba","originalAuthorName":"韩卫荣"},{"authorName":"郧海丽","id":"fea14419-8fc0-4c58-8ec4-955d95a0a8f9","originalAuthorName":"郧海丽"},{"authorName":"高岩磊","id":"014c2ba6-df7a-438c-a63e-dece7d6823eb","originalAuthorName":"高岩磊"},{"authorName":"牟微","id":"35b2eea5-b901-4b64-957f-0171298cddab","originalAuthorName":"牟微"}],"doi":"","fpage":"38","id":"04401998-f7a3-4746-ae4f-ddca27cf3f62","issue":"20","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"e77587bb-86a0-4f31-8f50-ce0811bce234","keyword":"乙酸(1-二茂铁基乙基)酯","originalKeyword":"乙酸(1-二茂铁基乙基)酯"},{"id":"c8768e83-dcfc-4781-a9d9-740b58f693b4","keyword":"咪唑盐","originalKeyword":"咪唑盐"},{"id":"5af321fe-fe34-4baf-9f96-eb6416169c3d","keyword":"催化","originalKeyword":"催化"},{"id":"8643f81c-85d2-4af7-a04e-7d68c166f0ba","keyword":"Suzuki-Miyaura","originalKeyword":"Suzuki-Miyaura"},{"id":"c7f5001a-f824-4876-8f68-ffd56bf52275","keyword":"偶联反应","originalKeyword":"偶联反应"}],"language":"zh","publisherId":"cldb201220010","title":"1-(1-二茂铁基乙基)-3-异丙基-1-咪唑碘盐的制备及其性能研究","volume":"26","year":"2012"},{"abstractinfo":"用磺酸型离子液体1-甲基-3-磺酸丙基咪唑硫酸氢盐([MIMPS][HSO4])催化β-萘酚、芳香醛和酰胺(或脲)3组分\"一锅法\" 类Ritter反应合成了酰胺烷基萘酚. 投料比为n(β-萘酚):n(芳香醛):n(酰胺或脲):n([MIMPS][HSO4])=1:1:1.3:0.1,无需溶剂,恒温125 ℃反应5～40 min,通过简单水洗抽滤即可分离产物,酰胺烷基萘酚产率为85%～97%. 离子液体[MIMPS][HSO4]可回收重复使用4次,其催化活性无明显降低. 探讨了醛、酰胺或脲结构对反应的影响及可能的反应机理.","authors":[{"authorName":"佘婷婷","id":"bb3b5103-5e05-4adf-bee4-1431ae6a005e","originalAuthorName":"佘婷婷"},{"authorName":"刘祖亮","id":"ae95f6bd-f341-4acd-b086-2495714f26af","originalAuthorName":"刘祖亮"},{"authorName":"巩凯","id":"34619330-f546-4058-a263-3e8412773101","originalAuthorName":"巩凯"}],"doi":"10.3724/SP.J.1095.2010.90549","fpage":"778","id":"611f60c5-7f31-4d2c-a989-770bb8d4c099","issue":"7","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"d22c9940-429f-4942-9c85-bdea032de15d","keyword":"磺酸型离子液体","originalKeyword":"磺酸型离子液体"},{"id":"3ebd99fd-76bf-41f4-9eb0-489a5e850e50","keyword":"类Ritter反应","originalKeyword":"类Ritter反应"},{"id":"4eaeb817-97b6-411b-a330-747f18522654","keyword":"芳香醛","originalKeyword":"芳香醛"},{"id":"27242e13-56fc-48cb-acf3-66b67bd307cc","keyword":"酰胺","originalKeyword":"酰胺"},{"id":"53edc866-07f5-4b29-84ad-5314d1613e83","keyword":"酰胺烷基萘酚","originalKeyword":"酰胺烷基萘酚"}],"language":"zh","publisherId":"yyhx201007007","title":"磺酸型离子液体催化\"一锅法\"合成酰胺烷基萘酚","volume":"27","year":"2010"}],"totalpage":4276,"totalrecord":42754}