建立了气相色谱-质谱检测8种植物源性食品中联苯菊酯残留量的方法.粮谷类样品采用乙腈提取、凝胶渗透色谱(GPC)结合Florisil固相萃取柱净化;蔬菜类样品采用乙酸乙酯提取、Florisil固相萃取柱净化,然后采用气相色谱-质谱测定,选择离子监测模式检测.方法的检出限为5μg/kg(S/N=10);在0.005～0.5 mg/L范围内呈现良好的线性关系,相关系数为0.999 9;在0.005,0.04和0.1 mg/kg 3个添加水平下,联苯菊酯的添加回收率在74%～99%之间,相对标准偏差(RSD)小于13%.该方法灵敏度高,净化效果良好,能有效地消除复杂基质带来的干扰,可以作为日常样品中联苯菊酯残留量的检测和确证方法.
参考文献
| [1] | Wu Y N.Present knowledge in food safety.Beijing:Chemical Industry Press (吴永宁.现代食品安全科学.北京:化学工业出版社),2003 |
| [2] | Lin W X.The compilation of residue limit standards for pesticides and veterinary drugs in foodstuffs in the world.Dalian:Dalian Maritime University Press (林维宣.各国食品中农兽药残留限量规定.大连:大连海事大学业出版社),2002 |
| [3] | Zhu M Y,Li M Q,Zhao Q Y,et al.Chinese Journal of Zhengzhou Institute of Technology (祝美云,李梦琴,赵秋艳,等.郑州工程学院学报),2003,24(4):64 |
| [4] | Mai G Z,Lin X W,Zhai G S,et al.Chinese Journal of Agroenvironmental Protection (买光照,刘潇威,翟广书,等.农业环境保护),2002,21(3):260 |
| [5] | Pan Y X,Dong J,Zhu L P,et al.Chinese Journal of Analytical Science (潘玉香,董静,朱莉萍,等.分析科学学报),2007,23(5):575 |
| [6] | Sun J,Pan Y X,Zhu L P,et al.Chinese Journal of Analysis Laboratory (孙军,潘玉香,朱莉萍,等.分析试验室),2007,26 (8):56 |
| [7] | Colume A,Cardenas S,Gallego M,et al.Anal China Acta,2001,436(1):153 |
| [8] | Ramesh A,Ravi P E.J Chromatogr B,2004,802(2):371 |
| [9] | Zhu L P,Zhu T,Pan Y X,et al.Chinses Journal of Health Laboratory Technology (朱莉萍,朱涛,潘玉香,等.中国卫生检验杂志),2008,18(2):242 |
| [10] | Zheng X H.Chinese Journal of Analytical Chemistry (郑孝华.分析化学),2004,32(2):225 |
| [11] | Lou Z Y,Chen Z M,Luo F J,et al.Chinese Journal of Chromatography (楼正云,陈宗懋,罗逢健,等.色谱),2008,26 (5):568 |
| [12] | Hong W P,Chen Z H,Yang Z Q.Chinese Journal of Chromatography (洪蔚萍,陈枝华,杨忠强.色谱),2004,22 (3):289 |
| [13] | Li Y,Chu X G,Zhong W K,et al.Chinese Journal of Chromatography (李樱,储晓刚,仲维科,等.色谱),2004,22(5):551 |
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