研究了溶液配比和降温速率对K2Al2B2O7(KABO)晶体生长的影响,发现NaF与KABO的适宜比例为2:1,晶体生长的合适降温速率为(0.1~5)℃/d,NaF为合适助熔剂.籽晶的取向也影响晶体的质量,[110]方向是KABO晶体生长的最佳生长方向;采用顶部籽晶技术,以NaF为助熔剂可生长出尺寸为50 mm×20 mm×17mm、重30 g的高光学质量KABO透明单晶.晶体对波长2500nm以上的光表现出各向异性吸收,紫外截止边为180 nm.用V型棱镜法测出的KABO晶体折射率拟合出了Sellmeier方程,计算了SHG相位匹配范围,一类相位匹配最短倍频波长为225.5 nm.KABO晶体的266 nm SHG相位匹配角为58.1°.长度为3.6 mm的晶体Nd:YAG激光器四倍频输出能量转换效率为12.3%.
参考文献
[1] | Chen C; Xu Z; Deng D; Zhang J; Tang D; The vacuum ultraviolet phase-matching characteristics of nonlinear optical KBe2BO3F2 crystal, Appl. Phys.Lett., 68(21), 2930(1996) |
[2] | Chen C; Wang Y; Wu B; Design and synthesis of an ultraviolet-transparent nonlinear optical crystal Sr2Be2B2O7, Nature, 373, 332(1995) |
[3] | Chen C; Ye N; Wu B, Design and synthesis of new nonlinear optical crystals, in Proceedings of International Symposium on Laser and Nonlinear Optical Materials, edited by Takatomo Sasaki (Singapore, No. 161committee of Japan Society for Promotion of Science and Data Storage Institute, 1997) p.103 |
[4] | Ye N; Zeng W; Wu B ; Chen C, Two new nonlinear optical crystals: BaAl2B2O7 and K2Al2B2O7, in Proceedings of SPIE, edited by Chuangtian Chen (Washington, SPIE-The International Society for Optical Engineering, 1998) p.21 |
[5] | Chen C; Ye N; Lin J; Jiang J; Zeng W and Wu B, C, Computer assisted search for nonlinear optical crystals; Adv. Mater., 11(13), 1071(1999) |
[6] | Ning Ye; Wenrong Zeng; Jie Jiang; Baichang Wu and Chuangtian Chen; New nonlinear optical crystal K2Al2B2O7; J.Opt.Soc.Am.B, 17(5), 764(2000) |
[7] | Zhang Chengqian, Research on the growth and properties of the new deep ultra-violet nonlinear optical crystals: KBe2BO3F2 and K2Al2B2O7; Ph.D Dissertation; Shandong University (2002) |
[8] | Zhang Chengqian, Wang Jiyang Hu Xiaobo, Jiang Huaidong, Li jing, Liu yaogang, Qi Ha, Wu Yicheng, Chen Chuangtian, Synthesis and Growth of A Novel NLO Crystal K2Al2B2O7, Journal of Synthetic Crystals,30(4), 325(2001) |
[9] | Zhang C., Wang J., Hu X., Liu H., Wei J., Liu Y., Wu Y., Chen C., Top-seeded growth of K2Al2B2O7,Journal of Crystal Growth, 231,439(2001) |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%