以二甲基亚砜为前驱体,通过二次插层取代,夹带入羧甲基淀粉,制备出高岭土/羧甲基淀粉剥离型插层复合微粒.羧甲基淀粉插层引起高岭土片层之间的剥离,高岭土片层在羧甲基淀粉中均匀分散.二次插层取代使插层复合物电流变液的介电常数和电导率显著改善.高岭土/羧甲基淀粉复合材料具有较好的协同效应,其电流变液的静态剪切应力值分别是纯高岭土的3.60倍和羧甲基淀粉的2.24倍.复合材料的电流变性能与复合物中羧甲基淀粉的含量有密切关系.复合材料电流变液的工作温区大幅扩展(20~90℃),抗沉降性明显提高.
参考文献
[1] | H.Tian, Electrorheological Fluids, Adv. Mater., 13(24), 1847(2001) |
[2] | YIN Jianbo(尹剑波),ZHAO Xiaopeng(赵晓鹏),Advance in Research on Preparation and Properties of Electrorheological Materials(电流变材料的设计与制备研究进展),Mater.Rev.(材料导报),14(9),10(2000) |
[3] | T.C.Halsay,Electrorheological Fluids,Science,258,761(1992) |
[4] | LU Jun(路军),ZHAO Xiaopeng(赵晓鹏),Temperature Effect and Antisedimentation of Polyaniline/Montmorillonite Electrorheological Fluid(聚苯胺/蒙脱土电流变液的稳定性),Chinese J.of Mater.Research(材料研究学报),16(6),638(2002) |
[5] | B.X.Wang, X.P. Zhao, Electrorheological Behavior of Kaolinite-Polar Liquid Intercalation Composites,J.Mater. Chem., 12, 1865(2002) |
[6] | J.Lu, X.P. Zhao Electrorheological properties of suspensions based on polyaniline-montmorillonite clay nanocomposite, J.Mater. Res., 17, 1513(2002) |
[7] | ZHAO Xiaopeng(赵晓鹏),YIN Jianbo(尹剑波),XIANG Liqun(向礼琴),Electrorheological Behavior of the Suspensions of Surfactant Coated TiO2(包覆表面活性剂的TiO2电流变液),Chinese J.of Mater.Research (材料研究学报),14(6),604(2000) |
[8] | R.L.Frost, J.Kristof, Raman spectroscopy of potassium acetate-intercalated kaolinites at liquid nitrogen temperature J. of Raman Spectroscopy (UK), 12(4), 271(2001) |
[9] | L.C.Davis, Polarization Forces and Conductivity Effects in ER Fluids, J.Appl. Phys., 72, 1334(1992) |
[10] | H.Block, P.Rattray, Recent development in electrorheology, in progress in Electrorheology, edited By Harelka,K.U.and Flicks, F.E.(New York, Plenum Press, 1995) p.19 |
[11] | K.O.Havelka, F.E.Filisko, Progress in Electrorheology [M] (New York, Plenum Press, 1995) p.19 |
[12] | Frost, R.L., Kristof, J., Horvath E. and Kloprogge, J.T. Modification of the kaolinite hydroxyl surfaces Part Ⅲ. Journal of Colloid and Interface Science, 214, 380(1999) |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%